Publications - van Eldik

All Publications

1969-1974

Publications of 1969
1)	Contradiction in the photolysis of dioxalatozinc(II) in excess oxalate R. van Eldik and J.A. van den Berg J. S.A. Chem. Inst., 22, 24 (1969)
2)	A kinetic study of the photochemical decomposition of the oxalate ion in aqueous solution R. van Eldik and J.A. van den Berg J. S.A. Chem. Inst., 22, 19 (1969)
3)	A kinetic study of the thermal and photochemical decomposition of the trismalonatocobalt(III) ion R. van Eldik and J.A. van den Berg J. S.A. Chem. Inst., 22, 175 (1969)
Publications of 1970
4)	A kinetic study of the thermal and photochemical decomposition of the bismalonatodiaquomanganese(III) ion R. van Eldik and J.A. van den Berg J. S.A. Chem. Inst., 23, 85 (1970)
5)	A kinetic study of the photochemical decomposition of the trismalonatoiron(III) ion R. van Eldik and J.A. van den Berg J. S.A. Chem. Inst., 23, 96 (1970)
Publications of 1971
6)	A kinetic study of the sensitized photochemical decomposition of some copper malonate complexes R. van Eldik J. S.A. Chem. Inst., 24, 13 (1971)
Publications of 1972
7)	A radiochemical tracer technique for studying the decomposition mechanisms of transition-metal malonate complexes in solution R. van Eldik and R. Alberts J. S.A. Chem. Inst., 25, 17 (1972)
Publications of 1973

Publications of 1974
8)	The photolysis of trisoxalatogermanate(IV) in aqueous solution. I. Photochemical behaviour E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 9, 177 (1974)
9)	The photolysis of trisoxalatogermanate(IV) in aqueous solution. II. Kinetics and mechanism E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 9, 183 (1974)

1975-1979

Publications of 1975
10)	Substitution reactions of oxalato complex ions. XI. Kinetics of the anation of aquopentaamminecobalt(III) ion by oxalate in aqueous acidic solution R. van Eldik and G.M. Harris Inorg. Chem., 14, 10 (1975)
11)	The kinetics of the anation reaction of aquopentaamminecobalt(III) by acetate in aqueous acidic solution P.R. Joubert and R. van Eldik Inorg. Chim. Acta, 12, 205 (1975)
12)	Kinetic reactivity of a variety of protonated and deprotonated carboxylic acids during the anation reactions of aquopentaamminecobalt(III) ion P.R. Joubert and R. van Eldik React. Kinet. Catal. Lett., 3, 23 (1975)
13)	The kinetics of the anation reaction of aquopentaamminecobalt(III) by propionate in aqueous acidic solution P.R. Joubert and R. van Eldik J. Inorg. Nucl. Chem., 37, 1817 (1975)
14)	The kinetics of the anation reaction of aquopentaamminerhodium(III) ion by oxalate in aqueous acidic solution R. van Eldik Z. Anorg. Allg. Chem., 416, 88 (1975)
15)	I_a(Sn2) and I_d(Snl) anation reactions of aquopentaamminerhodium(III) ion R. van Eldik React. Kinet. Catal. Lett., 2, 251 (1975)
16)	The kinetics of the anation reaction of aquopentaamminecobalt(III) by formate in aqueous acidic solution P.R. Joubert and R. van Eldik Inorg. Chim. Acta, 14, 259 (1975)
17)	Kinetics and mechanism of the photolysis of the tetrachloroaurate(III) oxalate system in acidic solution B.S. Maritz, R. van Eldik and J.A. van den Berg J. S.A. Chem. Inst., 28, 14 (1975)
18)	The recovery of Fe, Mn and Al from a mine water effluent S.R. van der Walt, R. van Eldik and H.G.J. Potgieter Water Research, 9, 865 (1975)
19)	Kinetics and mechanism of aquation and formation reactions of carbonato complexes. IX. The aquation of - and -cis-carbonato(ethylenediaminediacetato)cobaltate(III) ion in strongly acidic solution R. van Eldik, T.P. Dasgupta and G.M. Harris Inorg. Chem., 14, 2573 (1975)
20)	A mechanistic study of an industrial cementation process of copper O.G. van Schalkwyk and R. van Eldik CHEMSA, 1, 286 (1975)
Publications of 1976
21)	Equilibrium studies of the uranyl oxalate system in acidic aqueous solution A.G. Brits, R. van Eldik and J.A. van den Berg Z. Phys. Chem. N.F., 99, 107 (1976)
22)	Kinetics and mechanism of the reduction of tetrachloroaurate(III) by oxalate in acidic aqueous solution B.S. Maritz and R. van Eldik Inorg. Chim. Acta, 17, 21 (1976)
23)	Recalculatd rate parameters for the anation reaction of aquopentaamminecobalt(III) by some carboxylic acids in aqueous acidic solution R. van Eldik J. Inorg. Nucl. Chem., 38, 884 (1976)
24)	The kinetics of the anation reaction of aquopentaamminecobalt(III) by malonate in acidic aqueous solution P.R. Joubert and R. van Eldik Int. J. Chem. Kinet., 8, 411 (1976)
25)	The photolysis of the uranyl oxalate system. I. Photochemical behaviour in strongly acidic aqueous solution A.G. Brits, R. van Eldik and J.A. van den Berg Z. Phys. Chem. N.F., 102, 203 (1976)
26)	The photolysis of the uranyl oxalate system. II. Kinetics and mechanism in strongly acidic aqueous solution A.G. Brits, R. van Eldik and J.A. van den Berg Z. Phys. Chem. N.F., 102, 213 (1976)
27)	Kinetics and mechanism of the reduction of tetrachloroaurate(III) by formate in acidic aqueous solution B.S. Maritz and R. van Eldik J. Inorg. Nucl. Chem., 38, 1545 (1976)
28)	Rate data for the reaction between tetrachloroaurate(III) and a series of carboxylic acids in aqueous acidic solution B.S. Maritz and R. van Eldik J. Inorg. Nucl. Chem., 38, 1749 (1976)
29)	The synthesis and crystal structure of potassium- -oxalato- di[trisoxalatostannate(IV)] tetrahydrate G.J. Krüger, E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 19, 151 (1976)
30)	Kinetic data for the photolysis of a series of tetra-chloroaurate(III) carboxylate systems in acidic aqueous solution B.S. Maritz and R. van Eldik J. Inorg. Nucl. Chem., 38, 2124 (1976)
31)	The dissolution process of potassium- -oxalato- di[tris-oxalatostannate(IV)] tetrahydrate in water E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 20, 99 (1976)
32)	Kinetics and mechanism of the reduction of tetrachloroaurate(III) by malonate in acidic aqueous solution B.S. Maritz and R. van Eldik Inorg. Chim. Acta, 20, 43 (1976)
Publications of 1977
33)	The photolysis of potassium- -oxalato-di[trisoxalatostannate(IV)] tetrahydrate in aqueous acidic solution I. Photochemical behaviour E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 21, 89 (1977)
34)	The photolysis of potassium- -oxalato-di[trisoxalatostannate(IV)] tetrahydrate in aqueous acidic solution II. Kinetics and mechanism E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 21, 95 (1977)
35)	Kinetics and mechanism of the reduction of tetrachloroaurate(III) by substituted malonates in acidic aqueous solution B.S. Maritz and R. van Eldik J. Inorg. Nucl. Chem., 39, 1035 (1977)
36)	The photolysis of the uranyl oxalate system. III. Photochemical behaviour, kinetics and mechanism in aqueous solution A.G. Brits, J.A. van den Berg and R. van Eldik J. Inorg. Nucl. Chem., 39, 1195 (1977)
Publications of 1978
37)	The photolysis of the uranyl formic acid/formate system in acidic aqueous solution A.G. Brits, R. van Eldik and J.A. van den Berg Inorg. Chim. Acta, 30, 17 (1978)
38)	Temperature and pressure dependencies of the anation of Pd(MeEt₄dien)OH₂²⁺ by chloride ion in acidic aqueous solution. A mixing system for studying the kinetics of moderately fast reactions under pressure D.A. Palmer, R. Schmidt, R. van Eldik and H. Kelm Inorg. Chim. Acta, 29, 261 (1978)
39)	Mechanistic information from the effects of pressure on the kinetics of the reduction of Co(NH₃)₅F²⁺, Co(NH₃)₅Cl²⁺ and Co(NH₃)₅Br²⁺ by iron(II) in dimethylsulph-oxide R. van Eldik, D.A. Palmer and H. Kelm Inorg. Chim. Acta, 29, 253 (1978)
40)	Volumes of activation for the linkage isomerization reaction of thiocyanatopentaamminecobalt(III) in aqueous solution and in dimethylsulphoxide D.A. Palmer, R. van Eldik and H. Kelm Inorg. Chim. Acta, 30, 83 (1978)
Publications of 1979
41)	Substitution reactions of cis- and trans-bis(triethylphosphine)mesityl(bromo)platinum(II) with iodide and thiourea in methanol. Evidence for an associative mechanism R. van Eldik, D.A. Palmer and H. Kelm Inorg. Chem., 18, 572 (1979)
42)	Mechanistic information from the effect of pressure on the kinetics of some anation reactions of aquopentaamminecobalt(III), -rhodium(III) and -chromium(III) ions in acidic aqueous solution R. van Eldik, D.A. Palmer and H. Kelm Inorg. Chem., 18, 1520 (1979)
43)	Volumes of activation for the mercury(II) induced aquation reactions of halopentaamminecobalt(III), -rhodium(III) and -chromium(III) ions in acidic aqueous solution D.A. Palmer, R. van Eldik, T.P. Dasgupta and H. Kelm Inorg. Chim. Acta, 34, 91 (1979)
44)	Substitution reactions of oxalato complex ions. XII. Kinetics of the anation of diaquobis(ethylenediamine)cobalt(III) ion by oxalate in aqueous acidic solution. Nitrate ion catalysis of a cobalt(III) substitution reaction R. van Eldik and G.M. Harris Inorg. Chem., 18, 1997 (1979)
45)	Kinetics and mechanism of aquation and formation reactions of carbonato complexes. 15. The acid-catalyzed aquation of trans-carbonatocyanotetraamminecobalt(III) ion and carbon dioxide uptake by trans-aquocyanotetraamminecobalt(III) ion C.R. Krishnamoorthy, D.A. Palmer, R. van Eldik and G.M. Harris Inorg. Chim. Acta, 35, L361 (1979)

1980-1984

Publications of 1980
46)	Kinetics and mechanism of the formation, acid-catalyzed decomposition and intramolecular redox reactions of oxygen-bonded sulfitopentaamminecobalt(III) ions in aqueous solution R. van Eldik and G.M. Harris Inorg. Chem., 19, 880 (1980)
47)	The photolysis of the uranyl malonic acid/bimalonate system in acidic aqueous solution A.G. Brits, R. van Eldik and J.A. van den Berg Inorg. Chim. Acta, 39, 47 (1980)
48)	The kinetics and mechanism of the hydrolysis of the trisoxalatogermanate(IV) ion in aqueous acidic solution E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 40, 153 (1980)
49)	The chemistry lecturer as researcher at South African Universities R. van Eldik Scientific Contributions from the Potchefstroom University, Series H, Inaugural address No. 59, 1980
50)	Kinetics and mechanism of aquation and formation reactions of carbonato complexes. 17. Carbon dioxide uptake by and decarboxylation of the cis-bis(ethylenediamine)rhodium(III) system in aqueous solution D.A. Palmer, R. van Eldik, H. Kelm and G.M. Harris Inorg. Chem., 19, 1009 (1980)
51)	A study of the interaction of Cr(III) and Co(III) complex ions with nucleosides and their bases in aqueous solution C.R. Krishnamoorthy, R. van Eldik and G.M. Harris J. Coord. Chem., 10, 195 (1980)
52)	Nitrate ion catalysis of Co(III) substitution reactions R. van Eldik Inorg. Chim. Acta, 44, L197 (1980)
53)	Substitution reactions of cis- and/or trans-bromomesitylbis(triethylphosphine)platinum(II) with thiourea in ethanol, dimethylsulphoxide and acetone D.A. Palmer, R. van Eldik and H. Kelm Z. Anorg. Allg. Chem., 468, 77 (1980)
54)	Raikes memorial lecture: High pressure kinetics - a powerful tool in the study of reaction mechanisms R. van Eldik CHEMSA, 46 (1980)
55)	Synthesis and kinetics of the decarboxylation of two carbonate bridged complexes of chromium(III) and rhodium(III). The crystal structure of μ-carbonato-di-μ-hydroxo-bis[(1,4,7-triazacyclononane)chromium(III)]diiodide-hydrate. K. Wieghardt, W. Schmidt, R. van Eldik, B. Nuber and J. Weiss Inorg. Chem., 19, 2922 (1980)
56)	Kinetic data for SO₂ uptake by Rh(III) and Cr(III) hydroxo complexes in aqueous solution R. van Eldik Inorg. Chim. Acta, 42, 49 (1980)
57)	Concerning uncatalyzed isomerization and substitution reactions of sterically crowded Pt(II) complexes R. van Eldik, D.A. Palmer, H. Kelm and W.J. Louw Inorg. Chem., 19, 3551 (1980)
58)	The uncatalyzed cis to trans isomerization of PtX(C₆H₅)(PEt₃)₂ complexes in methanol. Further evidence for an initial solvolysis step W.J. Louw, R. van Eldik and H. Kelm Inorg. Chem., 19, 2878 (1980)
59)	Kinetics and mechanism of aquation and formation reactions of carbonato complexes. 18. Carbon dioxide uptake by and decarboxylation of the trans-bis(ehtylenediamine)rhodium(III) system in aqueous solution R. van Eldik, D.A. Palmer and G.M. Harris Inorg. Chem., 19, 3673 (1980)
60)	Kinetics and mechanism of aquation and formation reactions of carbonato complexes. 20. Carbon dioxide uptake by and decarboxylation of trans-halogenobis(ethylenediamine)rhodium(III) complexes in aqueous solution R. van Eldik, D.A. Palmer, H. Kelm and G.M. Harris Inorg. Chem., 19, 3679 (1980)
61)	Kinetics and mechanism of aquation and formation reactions of carbonato complexes. 21. Anation of dihydroxo(,',"-triaminotriethylamine)cobalt(III) by carbonate ion in basic solution R. van Eldik and G.M. Harris Inorg. Chem., 19, 3684 (1980)
62)	Interpretation of the volume of activation of inorganic reactions in solution R. van Eldik and H. Kelm Rev. Phys. Chem. Japan, 50, 185 (1980)
Publications of 1981
63)	Autocatalysis - yet another mechanism for spontaneous cis-trans isomerization of square planar complexes W.J. Louw and R. van Eldik Inorg. Chem., 20, 1939 (1981)
64)	High pressure mechanistic studies of photochemical reactions of transition metal complexes. I. Ligand field photolysis of some cationic Cr(III) amine complexes in aqueous solution K. Angermann, R. van Eldik, H. Kelm and F. Wasgestian Inorg. Chem., 20, 955 (1981)
65)	High pressure mechanistic studies of photochemical reactions of transition metal complexes. II: Ligand field photolysis of Cr(NCS)₆^3-, Cr(CN)₆^3- and Co(CN)₆^3- in aqueous solution K. Angermann, R. van Eldik, H. Kelm and F. Wasgestian Inorg. Chim. Acta, 49, 247 (1981)
66)	Volumes of activation for the anation of Pd(II) substituted dien complexes by chloride ion in aqueous solution. A high pressure stopped-flow instrument for studying the kinetics of fast reactions under pressure R. van Eldik, D.A. Palmer, R. Schmidt and H. Kelm Inorg. Chim. Acta, 50, 131 (1981)
67)	Kinetics of the anation of diaquobis(ethylenediamine)cobalt(III) by oxalic acid in aqueous acidic solution. Pressure and medium effects. R. van Eldik Inorg. Chim. Acta, 49, 5 (1981)
68)	Research activities of chemistry lecturers at South African Universities - a recent survey R. van Eldik CHEMSA, 71 (1981)
69)	Volumes of activation for the formation and aquation reactions of Co(III) sulfito complexes in aqueous solution U. Spitzer and R. van Eldik "High Pressure in Research and Industry", C.-M. Backman, T. Johannisson and L. TegnÃ©r (Eds.), 672 (1981)
70)	The interpretation of volumes of activation of photochemical reactions in solution R. van Eldik, R. Schmidt, B. Hammerich, H.-D. Brauer and H. Kelm "High Pressure in Research and Industry", C.-M. Backman, T. Johannisson and L. TegnÃ©r (Eds.), 651 (1981)
Publications of 1982
71)	High pressure mechanistic studies of the photochemical reactions of transition metal complexes. III. Medium effects on the photo-aquation of some Co(III) and Cr(III) complexes in solution K. Angermann, R. Schmidt, R. van Eldik, H. Kelm and F. Wasgestian Inorg. Chem., 21, 1175 (1982)
72)	Mechanistic information from ¹⁷O NMR measurements. Evidence for the existence of oxygen bonded (sulfito)pentaamminecobalt(III) in weakly acidic aqueous solution R. van Eldik, J. von Jouanne and H. Kelm Inorg. Chem., 21, 2818 (1982)
73)	Effects of pressure on the reduction of Co(NH₃)₅N₃²⁺ by Iron(II) in dimethylsulphoxide R. van Eldik Inorg. Chem., 21, 2501 (1982)
74)	Kinetics and mechanisms of the formation, substitution and aquation reactions of sulfur-bonded (sulfito)amminecobalt(III) complexes in aqueous solution U. Spitzer and R. van Eldik Inorg. Chem., 21, 4008 (1982)
75)	Concerning the pressure dependence of inner-sphere electron-transfer reactions: the reduction of cis-Co(en)₂Cl₂⁺ by iron(II) in dimethylsulphoxide R. van Eldik and H. Kelm Inorg. Chim. Acta, 60, 177 (1982)
76)	Kinetics and mechanism of the formation of nitritopentaamminecobalt(III) in aqueous acidic solution H. Ghazi-Bajat, R. van Eldik and H. Kelm Inorg. Chim. Acta, 60, 81 (1982)
77)	Comments on the synthesis and aquation of cis- and trans-Co(en)₂(NO₂)Cl⁺ in aqueous solution W. Rindermann and R. van Eldik Inorg. Chim. Acta, 64, L203 (1982)
78)	Kinetics and mechanism of the dioxygen uptake of the four-(X= Cl) and five- (X= I, SCN, PPh₃) coordinate complexes of Ir(cod)(phen)X D.J.A. de Waal, T.I.A. Gerber, W.J. Louw and R. van Eldik Inorg. Chem., 21, 2002 (1982)
79)	Mechanistic information from the effect of pressure on the formation and acid-catalyzed aquation reactions of carbonatopentaamminecobalt(III), -rhodium(III) and -iridium(III) ion in aqueous solution U. Spitzer, R. van Eldik and H. Kelm Inorg. Chem., 21, 2821 (1982)
80)	The construction and testing of a high-pressure joule-heating temperature-jump apparatus R. Doss, R. van Eldik and H. Kelm Rev. Sci. Instrum., 53, 1592 (1982)
81)	Mechanistic information from the effect of pressure on the linkage isomerization reactions of cis- and trans-dinitritobis(ethylenediamine)cobalt(III) in aqueous acidic solution W. Rindermann, R. van Eldik and H. Kelm Inorg. Chim. Acta, 61, 173 (1982)
82)	Concerning the formation and acid-catalyzed aquation reactions of carbonato-, O-bonded sulfito- and nitritopentaamminecobalt(III) ions R. van Eldik and G.M. Harris Inorg. Chim. Acta, 65, L125 (1982)
83)	The effect of pressure on the kinetics of the dehydration of carbonic acid and the hydrolysis of CO₂ in aqueous solution R. van Eldik and D.A. Palmer J. Sol. Chem., 11, 339 (1982)
84)	A reinvestigation of the effect of pressure on the reaction of Fe(III) with thiocyanate ions in aqueous solution R. Doss, R. van Eldik and H. Kelm Ber. Bunsenges. Phys. Chem., 86, 925 (1982)
85)	Kinetics and mechanisms of the formation and aquation reactions of transition metal carbonato and sulfito complexes in aqueous solution R. van Eldik Habilitation thesis, University of Frankfurt, 1982
86)	High-pressure temperature-jump evidence for an I_a mechanism for substitution reactions of manganese(II) in aqueous solution R. Doss and R. van Eldik Inorg. Chem., 21, 4108 (1982)
Publications of 1983
87)	Mechanistic information on the acid-catalyzed decarboxylation of the carbonatobis(ethylenediamine)cobalt(III) ion in aqueous solution using rapid scan spectrophotometry R. van Eldik and G.M. Harris Inorg. Chim. Acta, 70, 147 (1983)
88)	Mechanistic information from the effect of pressure on the intramolecular electron-transfer reaction of O-bonded (sulfito)pentaamminecobalt(III) in aqueous solution R. van Eldik Inorg. Chem., 22, 353 (1983)
89)	Base catalyzed isomerization reactions of nitro- and nitritobis(ethylenediamine)cobalt(III) complexes in aqueous solution W. Rindermann and R. van Eldik Inorg. Chim. Acta, 68, 35 (1983)
90)	Pressure effects on the photochemical and photophysical properties of the rho- dium(III) complexes Rh(NH₃)₅Cl²⁺ and Rh(NH₃)₅Br²⁺ in aqueous solution W. Weber, R. van Eldik, H. Kelm, J. DiBenedetto, Y. Ducommun, H. Offen and P.C. Ford Inorg. Chem., 22, 623 (1983)
91)	Pressure effects on photoisomerization/photosubstitution reactions of the rho- dium(III) complexes cis- and trans-Rh(NH₃)₄XYⁿ⁺ (X= Cl or Br, Y= X or H₂O) L.H. Skibsted, W. Weber, R. van Eldik, H. Kelm and P.C. Ford Inorg. Chem., 22, 541 (1983)
92)	Concerning the pressure dependence of outer-sphere electron-transfer reactions: the reduction of Co(NH₃)₅OH₂³⁺ by Fe(CN)₆^4- in aqueous acidic solution R. van Eldik and H. Kelm Inorg. Chim. Acta, 73, 91 (1983)
93)	The isolation and identification of an unusual palladium(II) substituted dien complex E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 76, L301 (1983)
94)	Mechanistic information on fast reactions of transition metal complexes using rapid scan spectrophotometry. II. The base hydrolysis of (;;S)-(salicylato)(tetraethylenepentamine)cobalt(III) in aqueous solution R. van Eldik, A.C. Dash and G.M. Harris Inorg. Chim. Acta, 77, L143 (1983)
95)	Kinetics and mechanism of some fast anation reactions of a series of substituted dien complexes of palladium(II). Temperature and pressure dependencies in weakly acidic aqueous solution E.L.J. Breet, R. van Eldik and H. Kelm Polyhedron, 2, 1181 (1983)
96)	Mechanistic information from temperature and pressure parameters for some substitution reactions of dien and a series of ethyl substituted dien complexes of palladium(II) in aqueous solution R. van Eldik, E.L.J. Breet, M. Kotowski, D.A. Palmer and H. Kelm Ber. Bunsenges. Phys. Chem., 87, 904 (1983)
97)	Mechanistic information on fast reactions of transition metal complexes using rapid scan spectrophotometry. III. The acid-catalyzed aquation of a series of Co(III) carbonato complexes in aqueous solution R. van Eldik, U. Spitzer and H. Kelm Inorg. Chim. Acta, 74, 149 (1983)
98)	The chemistry of metal carbonato and carbon dioxide complexes D.A. Palmer and R. van Eldik Chem. Rev., 83, 651 (1983)
99)	Effect of pressure on the aquation reactions of a series of bidentate carbonato complexes of Co(III) in aqueous solution R. van Eldik and U. Spitzer Trans. Met. Chem., 8, 351 (1983)
100)	High pressure kinetic evidence for dissociative activation during substitution reactions of some Co(III), Rh(III) and Cr(III) porphyrin complexes in aqueous solution J.G. Leipoldt, R. van Eldik and H. Kelm Inorg. Chem., 22, 4146 (1983)
Publications of 1984
101)	Kinetics and mechanism of some fast anation reactions of a series of substituted dien complexes of palladium(II). pH dependency in neutral and basic aqueous solution E.L.J. Breet, R. van Eldik and H. Kelm Inorg. Chim. Acta, 85, 151 (1984)
102)	Kinetics and mechanism of some fast substitution reactions of a series of methyl substituted dien complexes of palladium(II) in aqueous solution E.L.J. Breet and R. van Eldik Inorg. Chem., 23, 1865 (1984)
103)	Mechanistic information from the effect of pressure on fast substitution reactions of inorganic complexes in aqueous solution R. van Eldik, E.L.J. Breet, R. Doss, R. Mohr and H. Kelm Mat. Res. Soc. Symp. Proc., 22, Part 3, 61 (1984)
104)	Effect of pressure on the photosolvolysis reactions of a series of pentaamminerhodium(III) complexes in solution W. Weber, U. Kuester, R. van Eldik and H. Kelm Mat. Res. Soc. Symp. Proc., 22, Part 3, 65 (1984)
105)	Dilatometrically determined volumes of neutralization for a series of differently charged octahedral aquo and ammine complexes in aqueous solution Y. Kitamura and R. van Eldik Ber. Bunsenges. Phys. Chem., 88, 418 (1984)
106)	Pressure effects on the photophysical and photochemical properties of the rho- dium(III) ion Rh(NH₃)₅Cl²⁺ in nonaqueous solvents W. Weber, J. DiBenedetto, H. Offen, R. van Eldik and P.C. Ford Inorg. Chem., 23, 2033 (1984)
107)	Reactions involving coordinated ligands R. van Eldik "Adv. Inorganic and Bioinorganic Mechanisms", Vol. 3, A.G. Sykes (Ed.), Academic Press, 275 (1984)
108)	Volume profiles for the base hydrolysis of a series of pentaamminecobalt(III) complex ions in aqueous solution Y. Kitamura, R. van Eldik and H. Kelm Inorg. Chem., 23, 2038 (1984)
109)	Pressure dependence of the photoaquation quantum yields of some rhodium(III) ammine complexes in solution W. Weber and R. van Eldik Inorg. Chim. Acta, 85, 147 (1984)
110)	Kinetics and mechanism of an unique hydrolysis reaction of (hexafluoroacetylacetonato)bis(ethylenediamine)cobalt(III) in aqueous solution Y. Kitamura and R. van Eldik Transition Met. Chem., 9, 257 (1984)
111)	Spontaneous solvolysis reactions of some Pd(II) dien complexes in aqueous solution: equilibrium and kinetic data M. Kotowski and R. van Eldik Inorg. Chem., 23, 3310 (1984)
112)	Pressure and temperature effects on the rates of concurrent homolytic and heterolytic decomposition pathways of aqueous 2-propyl- and 2-hydroxy-2-propylchromium(III) ions M.J. Sisley, W. Rindermann, R. van Eldik and T.W. Swaddle J. Am. Chem. Soc., 106, 7432 (1984)
113)	Aquation of chloropentaammine and chloropentakis(methylamine) complexes of cobalt(III) and chromium(III): comparative activation volumes and mechanistic implications G.A. Lawrance, K. Schneider and R. van Eldik Inorg. Chem., 23, 3922 (1984)

1985-1989

Publications of 1985
114)	Synthesis and identification of a series of hexafluoroacetylacetonato complexes of Co(III). Spectroscopic analyses of the reversible addition of hydroxide to the coordinated ligand in aqueous solution S. Aygen, Y. Kitamura, K. Kuroda, R. Kume, H. Kelm and R. van Eldik Inorg. Chem., 24, 423 (1985)
115)	Volumes of activation for inorganic and organometallic reactions: a tabulated compilation R. van Eldik "Mechanisms of Inorganic and Organometallic Reactions", Vol. 3, M. Twigg (Ed.), Plenum Publ. Co., 399 (1985)
116)	The effect of ionic strength and pressure on the hydrolysis equilibrium of aquated iron(III) ions P. Martinez, R. van Eldik and H. Kelm Ber. Bunsenges. Phys. Chem., 89, 81, 447 (1985)
117)	Concerning the mechanism of isomerization of cis-azoalkanes R. van Eldik, H. Kelm, M. Schmittel and C. Rüchardt J. Org. Chem., 50, 2998 (1985)
118)	Associative nature of substitution reactions of manganese(II) in aqueous solution R. Mohr, L.A. Mietta, Y. Ducommun and R. van Eldik Inorg. Chem., 24, 757 (1985)
119)	Kinetic and spectroscopic studies of the substitution reactions of [Rh(acac)(CO)₂] with triphenylphosphite R. van Eldik, S. Aygen, H. Kelm, A.M. Trzeciak and J.J. Ziolkowski Transition Met. Chem., 10, 167 (1985)
120)	Kinetics and mechanism of the formation, substitution, isomerization and acid-catalyzed aquation reactions of trans-(O-sulfito)cyanotetraamminecobalt(III) in aqueous solution J. Kraft and R. van Eldik Inorg. Chem., 24, 3391 (1985)
121)	The effect of ionic strength and pressure on the complex formation and hydrolysis equilibria in the aquated iron(III)-thiocyanate system P. Martinez and R. van Eldik Ber. Bunsenges. Phys. Chem., 89, 728 (1985)
122)	The catalytic effect of nitrate ions on Co(III) substitution reactions. Solvent exchange data from oxygen-17 NMR measurements S. Aygen, H. Hanssum and R. van Eldik Inorg. Chem., 24, 2853 (1985)
123)	Solvatochromic, piezochromic and thermochromic behaviour of Mo(CO)₄(NN) complexes H.-T. Macholdt, R. van Eldik, H. Kelm and H. Elias Inorg. Chim. Acta, 104, 115 (1985)
124)	Fast complex formation reactions of divalent first-row transition metal ions in aqueous solution: mechanistic information from volumes of activation R. Mohr and R. van Eldik Inorg. Chem., 24, 3396 (1985)
125)	Kinetics and mechanism of the formation, aquation and base hydrolysis reactions of a series of monodentate carbonato complexes of palladium(II) G. Mahal and R. van Eldik Inorg. Chem., 24, 4165 (1985)
126)	High pressure effects on ligand substitution reactions of molybdenum(O) carbonyl complexes H.-T. Macholdt and R. van Eldik Transition Met. Chem., 10, 323 (1985)
127)	Volumes of activation for outer-sphere electron transfer between cobalt-(II) and -(III) in solution P. Braun and R. van Eldik J. Chem. Soc., Chem. Commun., 1349 (1985)
Publications of 1986
128)	Charge-transfer photochemistry under high pressure: reductive elimination from trans-diazidotetracyanoplatinate(IV) W. Weber and R. van Eldik Inorg. Chim. Acta, 111, 129 (1986)
129)	Mechanistic information from the effect of pressure on some typical outer-sphere electron-transfer reactions of Co(III) complexes I. Krack, P. Braun and R. van Eldik Physica, 139/140 B, 680 (1986)
130)	The spectral characterization and kinetics of formation of hypoiodous acid in aqueous solution D.A. Palmer and R. van Eldik Inorg. Chem., 25, 928 (1986)
131)	Reactions of Rh(acac)[P(OPh)₃]₂ with H₂, CO and olefins A.M. Trzeciak, J.J. Ziolkowski, S. Aygen and R. van Eldik J. Mol. Catal., 34, 337 (1986)
132)	Mechanistic information from the effect of pressure on thermal and photochemical substitution reactions R. van Eldik Comments Inorg. Chem., 5, 135 (1986)
133)	Mechanistic information from the effect of pressure on some outer-sphere electron-transfer reactions involving the reduction of cobalt(III) by iron(II) complexes in aqueous solution I. Krack and R. van Eldik Inorg. Chem., 25, 1743 (1986)
134)	Volumes of activation for inorganic and organometallic reactions: a tabulated compilation R. van Eldik "Mechanisms of Inorganic and Organometallic Reactions", Vol. 4, M. Twigg (Ed.), Plenum Publ. Co., 433 (1986)
135)	Volumes of activation and mechanistic assignment for chelate ring replacement at tetracarbonylchromium(O) centers H.-T. Macholdt, R. van Eldik and G.R. Dobson Inorg. Chem., 25, 1914 (1986)
136)	Understanding reaction dynamics in coordination chemistry - application of high pressure techniques R. van Eldik Angew. Chem., 98, 671 (1986) Angew. Chem. Int. Ed. Engl., 25, 673 (1986)
137)	Transition metals as potential catalysts in atmospheric oxidation processes R. van Eldik "Chemistry of multiphase atmospheric systems", NATO Advanced Study Institute, W. Jaeschke (Ed.), Springer Verlag, 541 (1986)
138)	Leaving group effects on the kinetic parameters for solvolysis reactions of sterically hindered palladium(II) complexes in aqueous solution M. Kotowski and R. van Eldik Inorg. Chem., 25, 3896 (1986)
139)	Mechanistic information from medium and high-pressure effects on the photo- oxidation of nitrosylpentacyanoferrate(II) G. Stochel, R. van Eldik and Z. Stasicka Inorg. Chem., 25, 3663 (1986)
140)	Effect of pressure on the photochemical formation and thermal back-isomerization of a sulfinato-O complex of cobalt(III) W. Weber, H. Maecke and R. van Eldik Inorg. Chem., 25, 3093 (1986)
141)	The effect of ionic strength and pressure on the complex formation kinetics of the aquated iron(III)-thiocyanate system P. Martinez, R. Mohr and R. van Eldik Ber. Bunsenges. Phys. Chem., 90, 609 (1986)
142)	Kinetics and mechanism of the reactions of sulfito complexes in aqueous solution. 7. Formation and redox reactions of sulfur-bonded aqua(sulfito)- and bis(sulfito)[bis(phenantrholine) or -bis(bipyridine)]cobalt(III) complex ions V.K. Joshi, R. van Eldik and G.M. Harris Inorg. Chem., 25, 2229 (1986)
143)	The formation and reactivity of sulfito complexes of tetraethylenepentaminecobalt(III): X-ray structure of [Co(tetren)SO₃]ClO₄ K.J. Schneider, A. Roodt, J.G. Leipoldt and R. van Eldik Inorg. Chim. Acta, 122, 1 (1986)
144)	High pressure kinetics: fundamental and experimental aspects; concluding remarks R. van Eldik Inorganic High Pressure Chemistry: Kinetics and Mechanisms, R. van Eldik (Ed.), Elsevier Science Publishers, Amsterdam, 1986, Chapters 1 and 8
145)	Substitution, isomerization and related reactions of octahedral complexes R. van Eldik Inorganic High Pressure Chemistry: Kinetics and Mechanisms, R. van Eldik (Ed.), Elsevier Science Publishers, Amsterdam, 1986, Chapter 3
146)	Substitution, isomerization and related reactions of four-coordinate complexes M. Kotowski and R. van Eldik Inorganic High Pressure Chemistry: Kinetics and Mechanisms, R. van Eldik (Ed.), Elsevier Science Publishers, Amsterdam, 1986, Chapter 4
147)	Volume profiles for the base hydrolysis of a series of monoalkylsubstituted chloropentaamminecobalt(III) complexes in aqueous solution R. van Eldik, Y. Kitamura and C.P. Piriz Mac-Coll Inorg. Chem., 25, 4252 (1986)
148)	Pressure effects on the excited state reaction dynamics of bis(bipyridine)dichlororhodium(III), cis-Rh(bpy)₂Cl₂⁺ S. Wieland, J. DiBenedetto, R. van Eldik and P.C. Ford Inorg. Chem., 25, 4893 (1986)
149)	Kinetics and mechanism of the reaction between trans-dioxotetracyanotungstate(III) and azide in aqueous solution J.G. Leipoldt, R. van Eldik, S.S. Basson and A. Roodt Inorg. Chem., 25, 4639 (1986)
Publications of 1987
150)	Activation volumes for the substitution reactions of the triruthenium cluster anions HRu₃(CO)₁₁^- and Ru₃(CO)₁₁(CO₂CH₃)^- D.J. Taube, R. van Eldik and P.C. Ford Organometallics, 6, 125 (1987)
151)	Preparation, characterization and reactivity of a series of diethylenetriamine(dien) and substituted dien complexes of platinum(II) G. Mahal and R. van Eldik Inorg. Chim. Acta, 127, 203 (1987)
152)	Oxidation of L-ascorbic acid by trisoxalatoferrate(III) in aqueous solution. Kinetic and spectroscopic evidence for the formation of an intermediate species P. Martinez, J. Zuluaga, D. Uribe and R. van Eldik Inorg. Chim. Acta, 136, 11 (1987)
153)	Evidence for a strong labilization effect by coordinated sulfite in amine complexes of palladium(II) G. Mahal and R. van Eldik J. Chem. Soc., Chem. Commun., 328 (1987)
154)	High pressure studies of inorganic reaction mechanisms R. van Eldik "High pressure chemistry and biochemistry", Nato Advanced Study Institute, R. van Eldik and J. Jonas (Eds.), D. Reidel, Dordrecht, Series C, 197, 333 (1987)
155)	Inorganic photochemistry at high pressure R. van Eldik "High pressure chemistry and biochemistry", Nato Advanced Study Institute, R. van Eldik and J. Jonas (Eds.), D. Reidel, Dordrecht, Series C, 197, 357 (1987)
156)	Spectroscopic and structural studies of the unique hydrolysis product of a hexafluoroacetylacetonato complex of cobalt(III). The crystal structure of bis(ethylenediamine) (hexafluorohydroxoacetylacetonato) cobalt(III) bromide monohydrate, [Co(en)₂(hfac.OH)]Br.H₂O S. Aygen, E.F. Paulus, Y. Kitamura and R. van Eldik Inorg. Chem., 26, 769 (1987)
157)	The mechanism of complex formation reactions of diethylenetriaminepalladium(II) with nucleosides - a case of anation, aquation and manipulation E.L.J. Breet and R. van Eldik J. Chem. Soc., Chem. Commun., 408 (1987)
158)	Photoisomerization of bis(bipyridyl)rhodium(III) complexes G. Krüger, S. Wieland and R. van Eldik Angew. Chem., 99, 245 (1987) Angew. Chem. Int. Ed. Engl., 26, 240 (1987)
159)	Synthesis and structure of a novel rhodium(I)-complex P₃RhP' (P= P(OPh)₃, P'= PO(OPh)₂^-): application of 2D-³¹P, and ¹H, ¹³C and ¹⁷O NMR spectroscopy S. Aygen and R. van Eldik Organometallics, 6, 1080 (1987)
160)	Structure and reactivity of the H₃O₂^- bridging ligand in trans-hydroxoaquabis(ethylenediamine)rhodium(III) R. van Eldik, A. Roodt and J.G. Leipoldt Inorg. Chim. Acta, 129, L41 (1987)
161)	Kinetics and mechanism of the fundamental substitution processes during complex formation of the diethylenetriaminepalladium(II) center with nucleic bases, nucleosides and 5'-nucleotides in aqueous solution E.L.J. Breet and R. van Eldik Inorg. Chem., 26, 2517 (1987)
162)	Formation and reactivity of palladium(II) sulfito complexes in aqueous solution. I. Spectroscopic evidence for the labilization of a chelated amine G. Mahal and R. van Eldik Inorg. Chem., 26, 1837 (1987)
163)	Formation and reactivity of palldaium(II) sulfito complexes in aqueous solution. II. Kinetics and mechanisms G. Mahal and R. van Eldik Inorg. Chem., 26, 2838 (1987)
164)	The kinetics and mechanism of the reaction of 2'-deoxy-5'-guanosinemonophosphoric acid and diaqua form for cis-platin D.J. Evans, M. Green and R. van Eldik Inorg. Chim. Acta, 128, 27 (1987)
165)	Solvent, ligand, pressure and temperature effects on charge-transfer spectra of tetracarbonylmolybdenum(O) diimine complexes R. bin Ali, J. Burgess, M. Kotowski and R. van Eldik Transition Met. Chem., 12, 230 (1987)
166)	Piezochromic and thermochromic behaviour of ternary diimine-cyanide-iron(II) and -iron(III) complexes M. Kotowski, R. van Eldik, R. bin Ali, J. Burgess and S. Radulovic Inorg. Chim. Acta, 131, 225 (1987)
167)	Computer controlled data acquisition- and analysis-system for stopped-flow kinetic measurements: developed for a Dionex stopped-flow instrument with data handling on an Apple or compatible computer J. Kraft, S. Wieland, U. Kraft and R. van Eldik GIT Fachz. Lab., 31, 560 (1987)
168)	Aquation of neutral ligands from pentaammine-cobalt(III) and -chromium(III) ions: mechanistic differentiation G.A. Lawrance and R. van Eldik J. Chem. Soc., Chem. Commun., 1105 (1987)
169)	High pressure kinetic study of an unusual hydrolysis reaction of (hexafluoroacetylacetonato)bis(ethylenediamine)cobalt(III) in aqueous solution Y. Kitamura and R. van Eldik Inorg. Chem., 26, 2907 (1987)
170)	Pressure enhancement of substitution and oxidative addition reactions of Rh(I) complexes J.G. Leipoldt, E.C. Steynberg and R. van Eldik Inorg. Chem., 26, 3068 (1987)
171)	Substitution kinetics of diethylenetriamine complexes of palladium(II) with tris(hydroxymethyl)aminomethane in aqueous solution E.L.J. Breet and R. van Eldik Inorg. Chem., 26, 4264 (1987)
172)	The characterization of a ring-opened diethylenetriamine complex of Pt(II). The crystal structure of Pt(dien.HCl)Cl₂ G. Mahal, R. van Eldik, A. Roodt and J.G. Leipoldt Inorg. Chim. Acta, 132, 165 (1987)
173)	Volumes of activation for kinetically-labile organometallic complexes: solvent displacement from cis(C₆H₅Cl)(PPh₂R)W(CO)₄ (R= Ph, (CH₂)₄CH=CH₂) in chlorobenzene solution H.H. Awad, G.R. Dobson and R. van Eldik J. Chem. Soc., Chem. Commun., 1839 (1987)
174)	Volumes of activation for anion-diazonium ion recombination N.S. Isaacs, T.S. Najem and R. van Eldik Tetrahedron Lett., 28, 3043 (1987)
Publications of 1988
175)	Volumes of activation for inorganic and organometallic reactions: a tabulated compilation R. van Eldik "Mechanisms of Inorganic and Organometallic Reactions", Vol. 5, Twigg (Ed.), Plenum Publ. Co., 377 (1988)
176)	Kinetics and mechanism of the oxidation of L-ascorbic acid by trisoxalatocobaltate(III) in basic aqueous solution P. Martinez, J. Zuluaga, J. Kraft and R. van Eldik Inorg. Chim. Acta, 146, 9 (1988)
177)	From inorganic reaction mechanisms to homogeneous catalysis R. van Eldik in "Coordination Chemistry and Catalysis" J.J. Ziolkowski (Ed.), World Scientific, 145 (1988)
178)	Kinetics of the substitution reaction of labile palladium(II) dien complexes with TRIS - a case of basicity, nucleophilicity and complexity J.J. Peinaar, E.L.J. Breet and R. van Eldik S.A. J. Science, 84, 389 (1988)
179)	Ligand substitution in manganese(I) carbonyl complexes Mn(CO)₅X (X = Cl, Br): Activation parameters and X-ray structure of Mn(CO)₃(dab)Cl (dab = biacetylbis(phenylimine)) G. Schmidt, H. Paulus, R. van Eldik and H. Elias Inorg. Chem., 27, 3211 (1988)
180)	Kinetics and mechanism of the acid-catalyzed aquation and base hydrolysis of nitropentacyanoferrate(III) in aqueous solution. Evidence for a pseudo-zero-order hydrolysis process G. Stochel, R. van Eldik, E. Hejmo and Z. Stasicka Inorg. Chem., 27, 2767 (1988)
181)	Kinetics and mechanism of the formation of Fe^II(edta)NO in the system Fe^II(edta)/NO/HONO/NO₂^- in aqueous solution V. Zang, M. Kotowski and R. van Eldik Inorg. Chem., 27, 3279 (1988)
182)	Solvent dependence of the activation parameters for the solvolysis of a typical square planar complex pyridine(pentamethyldiethylenetriamine)palladium(II) M. Kotowski, S. Begum, J.G. Leipoldt and R. van Eldik Inorg. Chem., 27, 4472 (1988)
183)	Kinetics and mechanism of the ligand substitution reactions of ethylenediaminetetraacetate complexes of ruthenium(III) in aqueous solution H. C. Bajaj and R. van Eldik Inorg. Chem., 27, 4052 (1988)
184)	A compact, transportable and multi-purpose high pressure unit for UV-VIS spectroscopic measurements at pressures up to 200 MPa M. Spitzer, F. Gärtig and R. van Eldik Rev. Sci. Instrum., 59, 2092 (1988)
Publications of 1989
185)	Substitution kinetics of palladium(II)diethylenetriamine complexes in basic medium J.J. Pienaar, E.L.J. Breet and R. van Eldik Inorg. Chim. Acta, 155, 249 (1989)
186)	Volumes of acitvation and volume profiles as mechanistic criteria for base hydrolysis reactions of cobalt(III) amine complexes Y. Kitamura, G.A. Lawrance and R. van Eldik Inorg. Chem., 28, 333 (1989)
187)	Activation volumes for aquation on chromium(III) pentaamine complexes with neutral leaving groups: comparison with and mechanistic differentiation from cobalt(III) analogues N.J. Curtis, G.A. Lawrance and R. van Eldik Inorg. Chem., 28, 329 (1989)
188)	Volume profiles for solvolysis reactions of sterically hindered diethylenetriamine complexes of palladium(II) in aqueous solution J.J. Pienaar, M. Kotowski and R. van Eldik Inorg. Chem., 28, 373 (1989)
189)	Kinetics and mechanism of the solvolysis reaction of nitropentacyanoferrate(III) G. Stochel and R. van Eldik Inorg. Chim. Acta, 155, 95 (1989)
190)	The influence of atomic size on mechanism: displacement of chelating ligands coordinating through sulfur from their group VI B metal carbonyl complexes of Cr and Mo H.H. Awad, C.B. Dobson, G.R. Dobson, J.G. Leipoldt, K. Schneider, R. van Eldik and H.E. Wood Inorg. Chem., 28, 1654 (1989)
191)	Temperature, pressure and viscosity dependence of outer-sphere electron-transfer processes. The reduction of aquapentaamminecobalt(III) by hexacyanoiron(II) I. Krack and R. van Eldik Inorg. Chem., 28, 851 (1989)
192)	Isolation and identification of a trans-bis(bipyridine) complex of rhodium(III). Crystal structure of [trans-Rh(bpy)₂Cl]₂(H₅O₃)(ClO₄)₂ - evidence for a H₅O₃ - bridging group G. Krüger, A. Roodt, J.G. Leipoldt and R. van Eldik Inorg. Chem., 28, 3073 (1989)
193)	Concerning ring-opened diethylenetriamine complexes of Pt(II). The crystal structure of [Pt(dienH)Cl₂]₂[PtCl₄].H₂O G. Mahal, R. van Eldik, A. Roodt and J.G. Leipoldt Inorg. Chim. Acta, 156, 29 (1989)
194)	Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV)-oxides in aqueous solution. I. Formation of transient iron(III)-sulfur(IV) complexes J. Kraft and R. van Eldik Inorg. Chem., 28, 2297 (1989)
195)	Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV)-oxides in aqueous solution. II. Decomposition of transient iron(III)-sulfur(IV) complexes J. Kraft and R. van Eldik Inorg. Chem., 28, 2306 (1989)
196)	Pressure tuning spectroscopic study of electron tunnelling processes in solution N.A. Lewis, Y.S. Obeng, D.V. Taveras and R. van Eldik J. Am. Chem. Soc., 111, 924 (1989)
197)	A spectroscopic and mechanistic study of the enolization and diol formation reactions of hexafluoroacetylacetone in the presence of water and alcohol S. Aygen and R. van Eldik Chem. Ber., 122, 315 (1989)
198)	Mechanistic information on base hydrolysis and basepromoted linkage isomerization reactions of chromium(III) amine complexes from volumes of activation P. Guardado, G.A. Lawrance and R. van Eldik Inorg. Chem., 28, 976 (1989)
199)	Application of high pressure kinetic techniques to mechanistic studies in coordination chemistry M. Kotowski and R. van Eldik Coord. Chem. Rev., 93, 19 (1989)
200)	Activation and reaction volumes in solution II R. van Eldik, T. Asano and W.J. le Noble Chem. Rev., 89, 549 (1989)
201)	Evidence for multistep reactions in the iron(III) catalyzed autoxidation of sulfur(IV)-oxides: possible steps during acid rain formation J. Kraft and R. van Eldik J. Chem. Soc., Chem. Commun., 790 (1989)
202)	Kinetics and mechanism of the ligand substitution reactions of N-hydroxyethylethylenediaminetriacetate complexes of ruthenium(III) in aqueous solution H.C. Bajaj and R. van Eldik Inorg. Chem., 28, 1980 (1989)
203)	Pressure as a key parameter to distinguish between associative charge-transfer and dissociative ligand-field photochemistry. CO substitution in W(CO)₄(1,10-phenanthroline) S. Wieland and R. van Eldik J. Chem. Soc., Chem. Commun., 367 (1989)
204)	Apparatus for filling the pillbox high-pressure optical cell under unaerobic conditions S. Wieland and R. van Eldik Rev. Sci. Instrum., 60, 955 (1989)
205)	Mechanistic differentiation between solvolysis reactions of pentaammine(trifluoromethanesulfonato-O) complexes of cobalt(III), chromium(III), and rhodium(III) S. Suvachittanont and R. van Eldik Inorg. Chem., 28, 3660 (1989)
206)	Mechanistic interpretation of high pressure effects on the photosubstitution of pyridine and 4-substituted pyridine in complexes of tungstenpentacarbonyl S. Wieland, R. van Eldik, D. Crane and P.C. Ford Inorg. Chem., 28, 3663 (1989)
207)	Kinetics and mechanism of solvent exchange and anation reactions of sterically hindered diethylenetriamine complexes of palladium(II) in aqueous solution J. Berger, M. Kotowski, R. van Eldik, U. Frey, L. Helm and A.E. Merbach Inorg. Chem., 28, 3759 (1989)
208)	Kinetics and mechanism of the anation of aquocobalamin (Vitamin B_12a) by cyanoferrates. Isolation and indentification of a cyano-bridged product and mechanistic information from pressure effects G. Stochel, R. van Eldik, H. Kunkely and A. Vogler Inorg. Chem., 28, 4314 (1989)
209)	Volumes of activation for inorganic and organometallic reactions: a tabulated compilation K.J. Schneider and R. van Eldik "Mechanisms of Inorganic and Organometallic Reactions", Vol. 6, M. Twigg (Ed.), Plenum Publ. Co., 437 (1989)
210)	High pressure ¹⁷O NMR study of solvent exchange on square planar complexes: water exchange on Pd(dien)H₂O²⁺ L. Helm, A.E. Merbach, M. Kotowski and R. van EldikHigh Pressure Research, 2, 49 (1989)
211)	Reaktionskinetik von Eisenchelatkomplexen mit SO_x and NO_y in wässriger Lösung: Abgasreinigung durch homogene Katalyse? V. Zang and R. van Eldik Dechema, 118, 143 (1989)
212)	Reductive elimination of hydrogen from H₃Ru₃( ₃-COMe)(CO)₉ and ligand substitution on HRu₃( -COMe)(CO)₁₀. Mechanistic information from high-pressure kinetics J. Anhaus, H.C. Bajaj, R. van Eldik, L.R. Nevinger and J.B. Keister Organometallics, 8, 2903 (1989)
213)	The possible role of iron(III)-sulfur(IV) complexes in the catalyzed autoxidation of sulfur(IV)-oxides. A mechanistic investigation J. Kraft and R. van Eldik Atmospheric Environment, 23, 2709 (1989)

1990-1994

Publications of 1990
214)	Parallel or reversable reactions? Complications in the substitution kinetics of octahedral metal carbonyl complexes K.J. Schneider and R. van Eldik Organometallics, 9, 92 (1990)
215)	Pressure as a mechanistic indicator in organometallic photochemistry S. Wieland and R. van Eldik Coord. Chem. Rev., 97, 155 (1990)
216)	Effect of pressure on the formation and deoxygenation kinetics of oxymyoglobin. Mechanistic information from a volume profile analysis H.-D. Projahn, C. Dreher and R. van Eldik J. Am. Chem. Soc., 112, 17 (1990)
217)	Volumes of activation for thermal ring-closure reactions of transient W(CO)₅(chelate) complexes K. Bal Reddy and R. van Eldik High Pressure Research, 5, 650 (1990)
218)	Volume of activation as mechanistic indicator in substitution reactions of organometallic complexes K. Schneider and R. van Eldik High Pressure Research, 5, 653 (1990)
219)	Solvent exchange and complex formation reactions of Pd(II) in aqueous solution: mechanistic information from high pressure studies B. Hellquist, L.I. Elding, A.E. Merbach, Y. Ducommun, L. Helm and R. van Eldik High Pressure Research, 5, 672 (1990)
220)	Pressure and solvent dependence of the substitution behaviour of octahedral metal carbonyl complexes: the influence of electronic effects on reaction mechanism K.J. Schneider and R. van Eldik Organometallics, 9, 1235 (1990)
221)	Substitution reactions of square planar complexes: steric crowding controls the nucleophilicity scale but not the mechanism H. Krüger and R. van Eldik J. Chem. Soc., Chem. Commun., 330 (1990)
222)	Temperature and pressure effects on the outer-sphere electron-transfer reaction between hexacyanoiron(II) and pentaamminecobalt(III) complexes in aqueous solution. Comparison of experimental and theoretical volumes of activation I. Krack and R. van Eldik Inorg. Chem., 29, 1700 (1990)
223)	Kinetics and mechanism of the autoxidation of iron(II) induced through chelation by ethylenediaminetetraacetate and related ligands V. Zang and R. van Eldik Inorg. Chem., 29, 1705 (1990)
224)	Application of a combined high-pressure stopped-flow photolysis technique in mechanistic studies. The termal ring-closure of photochemically produced W(CO)₅(bipyridyl) K. Bal Reddy and R. van Eldik Inorg. Chim. Acta, 169, 13 (1990)
225)	Mechanism of thermal ring-closure of M(CO)₅L (L = bidentate ligand) produced during photolysis of group 6 hexacarbonyl complexes K. Bal Reddy and R. van Eldik Organometallics, 9, 1418 (1990)
226)	Mechanistic information from a volume profile treatment for the complexation of aquocobalamin (Vitamin B_12a) by pyridine G. Stochel and R. van Eldik Inorg. Chem., 29, 2075 (1990)
227)	Labilization by steric crowding. Hydrolysis and racemization kinetics of Co(tmen)₃³⁺, tmen = 2,3-dimethyl-2,3-diaminobutane H. Diab, P. Hendry, A. Ludi, K. Bal Reddy and R. van Eldik Inorg. Chim. Acta, 175, 83 (1990)
228)	Ligand field and charge-transfer photochemistry of M(CO)₄(1,10 -phenanthroline) (M = Cr, Mo, W). Mechanistic information from high pressure effects S. Wieland, K. Bal Reddy and R. van Eldik Organometallics, 9, 1802 (1990)
229)	The effect of solvent and pressure on the reactivity of photoproduced M(CO)₅ transients as revealed by the observed quantum yields for the photosubstitution reactions of M(CO)₆ (M = Cr, Mo, W) S. Wieland and R. van Eldik J. Phys. Chem., 94, 5865 (1990)
230)	A spectrophotometric study of the interaction of pentacyanoferrate(II/III) complexes with nucleic bases, nucleosides and 5'-mononucleotides G. Stochel and R. van Eldik Inorg. Chim. Acta, 174, 217 (1990)
231)	Rate and equilibrium data for substitution reactions of diaqua(ethylenediamine)palladium(II) with chloride in aqueous solution H. Hohmann and R. van Eldik Inorg. Chim. Acta, 174, 87 (1990)
232)	Influence of the pendant group on the substitution lability of N-substituted ethylenediaminetriacetato complexes of ruthenium(III) in aqueous solution H.C. Bajaj and R. van Eldik Inorg. Chem., 29, 2855 (1990)
233)	Octahedral metal carbonyls. 71. Kinetics and mechanism of benzene displacement from photo-generated [(²-benzene)Cr(CO)₅] S. Zhang, G.R. Dobson, H.C. Bajaj, V. Zang, and R. van Eldik Inorg. Chem., 29, 3477 (1990)
234)	Mechanism of ligand binding to hemes and hemoproteins. A high pressure study D.J. Taube, H.-D. Projahn, R. van Eldik, D. Magde and T.G. Traylor J. Am. Chem. Soc., 112, 6880 (1990)
235)	The methyl(cyclam)nickel(III) dication in aqueous solutions: determination of the volume of reaction and volume of activation for the homolysis of the nickel-carbon bond R. van Eldik, H. Cohen, A. Meshulam and D. Meyerstein Inorg. Chem., 29, 4156 (1990)
236)	Mechanistic comparison of thermal and photochemical intramolecular electron-transfer reactions: differentiation on the basis of remarkably different pressure dependencies P. Guardado and R. van Eldik Inorg. Chem., 29, 3473 (1990)
237)	Mechanism of oxidation of aquated copper(II) ions by hydroxyl free radicals. A high-pressure pulse-radiolysis experiment H. Cohen, R. van Eldik, M. Masarwa and D. Meyerstein Inorg. Chim. Acta, 177, 31 (1990)
238)	Octahedral metal carbonyls. 72. Volumes of activation for solvent displacement in (solvent)M(CO)₅ transients (M = Cr, Mo, W) generated from M(CO)₆ via pulsed laser flash photolysis S. Zhang, V. Zang, H.C. Bajaj, G.R. Dobson and R. van Eldik J. Organomet. Chem., 397, 279 (1990)
239)	Influence of the polyaminocarboxylate chelate(L) on the kinetics and mechanism of the formation of Fe^II(L)NO in the system Fe^II(L)/NO/HONO/NO₂^- in aqueous solution V. Zang and R. van Eldik Inorg. Chem., 29, 4462 (1990)
240)	A kinetic study of the substitution behaviour of aqua and chloro complexes of ethylenediaminepalladium(II) in aqueous solution H. Hohmann, S. Suvachittanont and R. van Eldik Inorg. Chim. Acta, 177, 51 (1990)
Publications of 1991
241)	Determination of the volume of activation of the key reaction steps in the oxidation of phenanthroline-Cu(I) by molecular oxygen S. Goldstein, G. Czapski, R. van Eldik, H. Cohen and D. Meyerstein J. Phys. Chem., 95, 1282 (1991)
242)	Concerning the dependence of the volume of activation for a limiting D mechanism on the size of the leaving group. The aquation of pentacyano(amine)ferrate(II) complexes K. Bal Reddy and R. van Eldik Inorg. Chem., 30, 596 (1991)
243)	Chelate ring-closure in (o-phenanthroline)M(CO)₅ transients (M = Cr, Mo, W) generated by pulsed laser flash photolysis S. Zhang, V. Zang, G.R. Dobson and R. van Eldik Inorg. Chem., 30, 355 (1991)
244)	A study of the stability of Mn(III) and its redox reaction with Co(II) in aqueous azide medium N. Coichev, E.A. Neves and R. van Eldik Inorg. Chim. Acta, 179, 133 (1991)
245)	Pressure dependence of associative substitution reactions of (⁵-C₅H₅)Rh(CO)₂ P. Vest, J. Anhaus, H.C. Bajaj and R. van Eldik Organometallics, 10, 818 (1991)
246)	Kinetics and mechanism of the sulfite-induced autoxidation of Co(II) in aqueous azide medium N. Coichev and R. van Eldik Inorg. Chem., 30, 2375 (1991)
247)	Solvent, temperature and pressure dependence of the oxidative addition reactions of iodomethane to complexes of the type Rh^I( -diketonate)(CO)(PPh₃) J.A. Venter, J.G. Leipoldt and R. van Eldik Inorg. Chem., 30, 2207 (1991)
248)	Volumes of activation for inorganic and organometallic reactions: a tabulated compilation K.J. Schneider and R. van Eldik "Mechanisms of Inorganic and Organometallic Reactions", Vol. 7, M. Twigg (Ed.), Plenum Publ. Co., 371 (1991)
249)	Oxidation of benzenediols by the iron(III) tetracyano bipyridyl ion: a high pressure stopped-flow kinetics study C.D. Hubbard, H.C. Bajaj, R. van Eldik, J. Burgess and N.J. Blundell Inorg. Chim. Acta, 183, 1 (1991).
250)	A mechanistic study of the sulfite-induced autoxidation of Mn(II) in aqueous azide medium N. Coichev and R. van Eldik Inorg. Chim. Acta, 185, 69 (1991)
251)	Redox cycling of iron in atmospheric water: the important role of sulfite K. Bal Reddy, N. Coichev and R. van Eldik J. Chem. Soc., Chem. Commun., 481 (1991)
252)	Pressure dependence of inorganic electron-transfer reactions in solution R. van Eldik High Pressure Research, 6, 251 (1991)
253)	A volume profile analysis of the formation and dissociation of carboxymyoglobin. Comparison with the corresponding oxymyoglobin system. H.-D. Projahn and R. van Eldik Inorg. Chem., 30, 3288 (1991)
254)	Kinetics and mechanism of the oxidation of L-ascorbic acid by hexacyanoiron(III) in acidic aqueous solution. Application of high pressure techniques B. Bänsch, P. Martinez, J. Zuluaga, D. Uribe and R. van Eldik Z. Phys. Chem., 170, 59 (1991)
255)	A mechanistic study of the substitution behaviour of complexes of the type M(CO)₅(THF) (M = Cr, Mo, W) S. Wieland and R. van Eldik Organometallics, 10, 3110 (1991)
256)	Effect of pressure on an intramolecular electron-transfer reaction induced by pulse-radiolysis D. Meyerstein, I. Zilbermann, H. Cohen and R. van Eldik High Pressure Research, 6, 287 (1991)
257)	Effect of pressure on the complex formation and aquation kinetics of Fe(III) with hydroxamic acids M. Birus and R. van Eldik Inorg. Chem., 30, 4559 (1991)
258)	Pressure assisted formation of a cobalt-carbon - bond. A high pressure pulse radiolysis study R. van Eldik, H. Cohen and D. Meyerstein Angew. Chem., 103, 1177 (1991); Angew. Chem. Int. Ed. Engl., 30, 1158 (1991)
259)	Is the oxidation of L-ascorbic acid by aquated iron(III) in acidic aqueous solution substitution- or electron-transfer-controlled? A combined chloride, pH, temperature and pressure dependence study B. Bänsch, P. Martinez, D. Uribe, J. Zuluage and R. van Eldik Inorg. Chem., 30, 4555 (1991)
260)	Activation volumes for the base hydrolysis of some chloro(diamine)(triamine)chromium(III) complexes D.A. House, K. Bal Reddy and R. van Eldik Inorg. Chim. Acta, 186, 5 (1991)
261)	Effect of steric hindrance on kinetic and equilibrium data for substitution reactions of diaqua(N-substituted ethylenediamine)palladium(II) with chloride in aqueous solution H. Hohmann, B. Hellquist and R. van Eldik Inorg. Chim. Acta, 188, 25 (1991)
262)	Oxidation of dihydroxyaromatic substrates by hexachloroiridium(IV). Mechanistic information from volumes of activation C.D. Hubbard, A. Gerhard and R. van Eldik Inorg. Chem., 30, 5023 (1991)
263)	Kinetics and mechanism of the substitution of aquapentacyanoferrate(III) by cytosine, cytidine and cytidine-5'-monophosphate G. Stochel and R. van Eldik Inorg. Chim. Acta, 190, 55 (1991)
Publications of 1992
264)	Kinetics and mechanism of the sulfite-induced autoxidation of Fe(II) in acidic aqueous solution K. Bal Reddy and R. van Eldik Atmos. Environ., 26A, 661 (1992)
265)	Pressure acceleration of [2+2] cycloaddition reactions on the coordinated ligand of chromium and tungsten pentacarbonyl carbene complexes R. Pipoh, R. van Eldik, S.L.B. Wang and W.D. Wulff Organometallics, 11, 490 (1992)
266)	Experimental and theoretical determination of thermodynamic and kinetic parameters for non-symmetrical outersphere electron-transfer reactions. The reduction of a hexaminecobalt(III) complex by vanadium(II) in acidic aqueous solution B. Bänsch, P. Martinez and R. van Eldik J. Phys. Chem., 96, 234 (1992)
267)	Effect of pressure on the insertion kinetics of metal-carbene complexes K.J. Schneider, A. Neubrand, R. van Eldik and H. Fischer Organometallics, 11, 267 (1992)
268)	Kinetics and mechanism of the complex formation reactions of diaqua(ethylenediamine)- and diaqua(tetraethylethylenediamine)-palladium(II) with the purine nucleosides adenosine and inosine H. Hohmann, B. Hellquist and R. van Eldik Inorg. Chem., 31, 345 (1992)
269)	Temperature and pressure dependence of the addition of 4-cyanopyridine to tricarbonyl(1-5- -dienyl)iron(II) complexes (dienyl = C₆H₇ or C₇H₉) T.I. Odiaka and R. van Eldik J. Organomet. Chem., 425, 89 (1992)
270)	Kinetics and mechanism of the complex formation of ethylenediaminetetraacetateiron(III) with sulfur(IV)-oxides in aqueous solution M. Dellert-Ritter and R. van Eldik J. Chem. Soc., Dalton Trans., 1037 (1992)
271)	Kinetics and mechanism of the redox behaviour of the ethylenediaminetetraacetateiron(III)-sulfite system in aqueous solution M. Dellert-Ritter and R. van Eldik J. Chem. Soc., Dalton Trans., 1045 (1992)
272)	High pressure kinetics. A decisive dimension in mechanistic studies of inorganic reactions R. van Eldik and A.E. Merbach Comments Inorg. Chem., 12, 341 (1992)
273)	A kinetic study of the interaction of aquated palladium(II) complexes with purine 5'-nucleoside monophosphates and ribose-5'-monophosphate in aqueous solution. Effects of steric hindrance and phosphate induced reactivity H. Hohmann, B. Hellquist and R. van Eldik Inorg. Chem., 31, 1090 (1992)
274)	Quinquedentate coordination of 10-methyl-1,4,8,12-tetraazacyclopentadecane-10-amine(1) to rhodium(III). Crystal structure of cis-[Rh(1)Cl](ClO₄)₂.H₂O and comparative activation volumes for base hydrolysis of [M(1)Cl]²⁺ (M = Rh, Co, Cr) G.A. Lawrance, M. Martinez, B.W. Skelton, R. van Eldik and A.H. White Austr. J. Chem., 45, 351 (1992)
275)	Development of analytical procedures for the detection of nitrogen-sulfur-oxides produced during the reaction of SO_x and NO_y species in aqueous solution M. GeiÃŸler and R. van Eldik Precipitation Scavenging and Atmosphere-Surface Exchange, Vol. 1, Hemisphere Publ. Co., Washington, 189 (1992)
276)	Pressure as a mechanistic indicator in substitution reactions of metal complexes R. van Eldik Pure Applied Chem., 64, 1439 (1992)
277)	The synergistic effect of manganese(II) in the sulfite-induced autoxidation of metal ions and complexes in aqueous solution N. Coichev, K. Bal Reddy and R. van Eldik Atmos. Environ., 26A, 2295 (1992)
278)	Mechanistic information from the effect of pressure on ligand substitution and chelate ring-closure reactions of photogenerated chlorobenzene solvates of tungsten tetracarbonyl intermediates in mixed solvents V. Zang, S. Zhang, C.B. Dobson, G.R. Dobson and R. van Eldik Organometallics, 11, 1154 (1992)
279)	Metal ion catalyzed autoxidation of sulfur(IV)-oxides: Redox cycling of metal ions induced by sulfite R. van Eldik, N. Coichev, K. Bal Reddy and A. Gerhard Ber. Bunsenges. Phys. Chem., 96, 478 (1992)
280)	Mechanistic information on the reaction of model palladium(II) complexes with purine nucleotides and 5'-nucleosides in reference to the antitumor activity of related platinum complexes M. Shoukry, H. Hohmann and R. van Eldik Inorg. Chim. Acta, 198-200, 187 (1992)
281)	Mechanism of oxidation of 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecanenickel(II) by HO₂ free radicals in aqueous solution. A pulse-radiolysis study A. Meshulam, H. Cohen, R. van Eldik and D. Meyerstein Inorg. Chem., 31, 2151 (1992)
282)	High pressure pulse radiolysis. Modification of an optical cell for 2MeV electron pulse radiolysis at pressures up to 200 MPa J.F. Wishart and R. van Eldik Rev. Sci. Instrum., 63, 3224 (1992)
283)	Kinetics of the oxidation of L-ascorbic acid by diaquatetraamminecobalt(III) in acidic aqueous solution. Application of the Fouss model and the Marcus-Sutin cross-relationship for electron-transfer processes P. Martinez, J. Zuluaga, P. Noheda and R. van Eldik Inorg. Chim. Acta, 195, 249 (1992)
284)	Mechanistic information from the effect of temperature and pressure on the addition of 4-ethylpyridine to tricarbonyl(1-5- -dienyl)iron(II) complexes (dienyl = C₆H₇, 2-MeOC₆H₆ and C₇H₉) T.I. Odiaka and R. van Eldik J. Chem. Soc., Dalton Trans., 2215 (1992)
285)	The oxidation of L-ascorbic acid by trisoxalatoferrate(III) in weakly acidic aqueous solution revisited. Evidence for parallel inner-sphere and outer-sphere electron-transfer reaction paths B. Bänsch, R. van Eldik and P. Martinez Inorg. Chim. Acta, 201, 75 (1992)
286)	Thermal ring closure in Mo(CO)₅L (L = bpy, dmbpy, dpbpy) transients generated by pulsed laser flash photolysis. Mechanistic information from high pressure effects K. Bal Reddy, R. Hoffmann, G. Konya, R. van Eldik and E.M. Eyring Organometallics, 11, 2319 (1992)
287)	Interpretation and evaluation of repetitive scan UV-VIS spectra in kinetic studies of chemical reactions in solution H. Apel, C. Brandt, R. Pipoh and R. van Eldik Spectroscopy Europe, 4(3), 24 (1992)
288)	Significance of entropies and volumes of activation for the addition of 4-formylpyridine to tricarbonyl(1-5- -dienyl)iron(II) complexes (dienyl = C₆H₇, 2-MeOC₆H₆ and C₇H₉) T.I. Odiaka and R. van Eldik J. Organomet. Chem., 438, 131 (1992)
289)	Elucidation of reaction pathways through volume profile analysis R. van Eldik "Perspectives in Coordination Chemistry" A.F. Williams, C. Floriani, A.E. Merbach (Eds.), VHCA Basel, VCH Weinheim, 55 (1992)
290)	Kinetics and mechanism of the acetate-catalyzed heterolysis of the metal-carbon σ bond of -hydroxyalkyl-chromium(III) complexes. Effects of the non-participating ligands, temperature and pressure H. Cohen, W. Gaede, A. Gerhard, D. Meyerstein and R. van Eldik Inorg. Chem., 31, 3805 (1992)
291)	Effect of pressure on intramolecular ring-closure reactions of molybdenum carbonyl complexes induced by flash photolysis K. Bal Reddy, B. Ryan Brady, E.M. Eyring and R. van Eldik J. Organomet. Chem., 440, 113 (1992)
292)	High pressure pulse radiolysis study of intramolecular and intermolecular reduction of cytochrome c by ruthenium(II) ammine complexes J.F. Wishart, R. van Eldik, J. Sun, C. Su and S.S. Isied Inorg. Chem., 31, 3986 (1992)
293)	Volumes of activation for solvent displacement reactions on pentacarbonylchromium(O). Comparison of data for pure and mixed solvents S. Zhang, H.C. Bajaj, V. Zang, G.R. Dobson and R. van Eldik Organometallics, 11, 3901 (1992)
294)	High pressure kinetic evidence for a dissociative interchange (I_d) substitution mechanism for aquated chromium(II) R. van Eldik, W. Gaede, H. Cohen and D. Meyerstein Inorg. Chem., 31, 3695 (1992)
295)	Development of a gradient ion-pair chromatographic procedure for the simultaneous detection of nitrogen-sulfur-oxides produced during the reaction of SO_x and NO_y species in aqueous solution M. GeiÃŸler and R. van Eldik Anal. Chem., 64, 3004 (1992)
296)	The feasibility of a limiting D mechanism for complex formation and ligand substitution reactions of pentacyanoferrate(II) G. Stochel, J. Chatlas, P. Martinez and R. van Eldik Inorg. Chem., 31, 5480 (1992)
297)	Steric and electronic tuning of the lability of square planar d⁸ metal complexes: Pt(II) Âº Pd(II) M. Schmülling, A.D. Ryabov and R. van Eldik J. Chem. Soc., Chem. Commun., 1609 (1992)
298)	Metal-catalyzed autoxidation of S(IV). The importance of sulfite-induced oxidation of metal ions R. van Eldik Laboratory Studies on Atmospheric Chemistry, Air Pollution Research Report 42, R.A. Cox (Ed.); Commission of the European Communities, 13 (1992)
Publications of 1993
299)	The reaction of nitric oxide with sulfur(IV) oxides in the presence of iron(II) complexes in aqueous solution V. Zang and R. van Eldik J. Chem. Soc., Dalton Trans., 111 (1993)
300)	Application of high pressure techniques in mechanistic and synthetic studies of organometallic systems in solution R. van Eldik Organometallics in Organic Synthesis Vol. 4, Vieweg Verlag, 27 (1993)
301)	Pressure effects on the photoreactions of the iron acyl complex ( ⁵-C₅H₅)Fe(CO)₂ (COCH₃) D.W. Ryba, R. van Eldik and P.C. Ford Organometallics, 12, 104 (1993)
302)	Spectrophotometric stopped-flow apparatus suitable for high pressure experiments to 200 MPa R. van Eldik, W. Gaede, S. Wieland, J. Kraft, M. Spitzer and D.A. Palmer Rev. Sci. Instrum., 64, 1355 (1993)
303)	Lithium ion-crown ether complexes in a molten salt E.M. Eyring, D.P. Cobranchi, B.A. Garland, A. Gerhard, A.M. Highley, Y. Huang, G. Konya, S. Petrucci and R. van Eldik Pure Appl. Chem., 65, 451 (1993)
304)	Rapid measurements of oxygen concentrations in aqueous solution. Reaction kinetics of the transition metal catalyzed oxidation of sulfur(IV) oxides C. Brandt, N. Coichev, E. Hostert and R. van Eldik GIT Fachz. Lab., 37, 277 (1993)
305)	A mechanistic study of the addition of pyrrolidine to , -unsaturated Fischer carbene complexes. The structure of pentacarbonyl[(2E)-3-phenyl-3-N-pyrrolidino-1-ethoxypropen-1-ylidene]tungsten(O) R. Pipoh, R. van Eldik and G. Henkel Organometallics, 12, 2236 (1993)
306)	High pressure mechanistic studies of inorganic and organometallic systems R. van Eldik High Pressure Chemistry, Biochemistry and Materials Science, R. Winter and J. Jonas (Eds.), Kluwer (Dordrecht), C401, 309 (1993)
307)	Bioinorganic kinetics at elevated pressure. Application of stopped-flow, T-jump, flash-photolysis and pulse-radiolysis techniques R. van Eldik High Pressure Chemistry, Biochemistry and Materials Science, R. Winter and J. Jonas (Eds.), Kluwer (Dordrecht), C401, 329 (1993)
308)	Redox cycling and synergistic effect of manganese in the metal-catalyzed autoxidation of sulfur(IV) N. Coichev and R. van Eldik Photo-oxidants: Precursors and Products, P.M. Borrell, P. Borell, T. Cvitas and W. Seiler (Eds.), SPB Academic Publishing bv, Den Haag, 589 (1993)
309)	Iron(III)-catalyzed oxidation of sulfur(IV)-oxides: evidence for a novel reaction step in the presence of oxygen C. Brandt and R. van Eldik Photo-oxidants: Precursors and Products, P.M. Borell, P. Borell, T. Cvitas and W. Seiler (Eds.), SPB Academic Publishing bv, Den Haag, 593 (1993)
310)	Anion-catalyzed heterolysis of chromium-carbon - bonds. Effect of different anions, temperature and pressure W. Gaede, R. van Eldik, H. Cohen and D. Meyerstein Inorg. Chem., 32, 1997 (1993)
311)	Influence of acetate ion on the formation reactions of organochromium(III) species. A rapid-scan and high pressure pulse-radiolysis study W. Gaede, A. Gerhard, R. van Eldik, H. Cohen and D. Meyertein J. Chem. Soc., Dalton Trans., 2065 (1993)
312)	Insertion of alkynes into the Pd-C bond of palladacycles. Mechanistic information from high pressure kinetics and X-ray structural data A.D. Ryabov, R. van Eldik, G. Le Borgne and M. Pfeffer Organometallics, 12, 1386 (1993)
313)	Ligand substitution reactions of aquacobalamin (vitamin B_12a) revisited. Conclusive evidence for the operation of a dissociative interchange mechanism M. Meier and R. van Eldik Inorg. Chem., 32, 2635 (1993)
314)	On the reaction of thiocyanate and thiourea with Rh(III) aqua ions C. Dücker-Benfer, M. Schmülling, D.A. House and R. van Eldik Transition Met. Chem., 18, 537 (1993)
315)	Mechanistic information from the effect of temperature and pressure on the addition of a series of para-substituted anilines to an , -acetylenic pentacarbonylchromium carbene complex R. Pipoh and R. van Eldik Organometallics, 12, 2668 (1993)
316)	Versatile complex-formation kinetics observed for the reactions of a model cis-bis(amine)palladium(II) complex with DNA nucleosides and nucleotides S. Suvachittanont, H. Hohmann, R. van Eldik and J. Reedijk Inorg. Chem., 32, 4544 (1993)
317)	Complex-formation kinetics of iron(III) with chlorite ion in aqueous solution. Mechanistic information from pressure effects I. Fabian and R. van Eldik Inorg. Chem., 32, 3339 (1993)
318)	Bridging of platinacycles by cis-azobenzenes: synthesis and photochemical study. Structure of the twisted inorganic Z-1,1,2,2-tetrasubstituted diazaethene ((Z)-1,2-diphenyldiazaethene) bis[chloro(((dimethylamino) methyl)phenyl -C,N)platinum(II)] A.D. Ryabov, L.G. Kuz'mina, N.V. Dvortsova, D.J. Stufkens and R. van Eldik Inorg. Chem., 32, 3166 (1993)
319)	Anionopentaaminecobalt(III) complexes with polyamine ligands 26. Spontaneous and Hg²⁺-assisted chloride release kinetics from some CoCl(tacn)(diamine)²⁺ complexes D.A. House and R. van Eldik Austr. J. Chem., 46, 1775 (1993)
320)	Kinetics and mechanism of the hydration of CO₂ and dehydration of HCO₃^- catalyzed by a Zn(II) complex of 1,5,9-triazacyclododecane as a model for carbonic anhydrase X. Zhang, R. van Eldik, T. Koike and E. Kimura Inorg. Chem., 32, 5749 (1993)
321)	Pressure as a kinetic parameter in mechanistic studies of chemical reactions induced by flash photolysis and pulse radiolysis R. van Eldik Pure Appl. Chem., 65, 2603 (1993)
322)	Information on the nature of the transition state for the addition of pyrazole to an , -unsaturated Fischer carbene complex from a combined solvent, temperature and pressure dependence study R. Pipoh, P. Martinez and R. van Eldik Ber. Bunsenges. Phys. Chem., 97, 1435 (1993)
Publications of 1994
323)	Volumes of activation for inorganic and organometallic reactions: a tabulated compilation A. Neubrand and R. van Eldik "Mechanisms of Inorganic and Organometallic Reactions", Vol. 8, M. Twigg (Ed.), Plenum Publ. Co., 399 (1994)
324)	Kinetics and mechanism of the phophate-catalyzed heterolysis of the metal-carbon - bond of -hydroxyalkyl-chromium(III) complexes. Effects of the non-participating ligands, temperature and pressure W. Gaede and R. van Eldik Inorg. Chim. Acta, 215, 173 (1994)
325)	Pressure as a kinetic parameter in the elucidation of the mechanisms of inorganic, organometallic and bioinorganic reactions in solution R. van Eldik Quimica Nova (Braz.), 17, 55 (1994)
326)	Metal catalyzed atmospheric oxidation reactions. A challenge to coordination chemists N. Coichev and R. van Eldik New. J. Chem., 18, 123 (1994)
327)	Volume profiles for the reversible binding of dioxygen to cobalt(II) complexes. Evidence for a substitution-controlled process M. Zhang, R. van Eldik, J.H. Espenson and A. Bakac Inorg. Chem., 33, 130 (1994)
328)	Can steric hindrance cause a gradual change in the ring-closure mechanism of complexes of the type W(CO)₅N-N, where N-N represents a series of substituted bipyridine ligands? S. Cao, K. Bal Reddy, E.M. Eyring and R. van Eldik Organometallics, 13, 91 (1994)
329)	Kinetics and mechanism of the iron(III) catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. Evidence for the redox cycling of iron in the presence of oxygen and modeling of the overall reaction mechanism C. Brandt, I. Fabian and R. van Eldik Inorg. Chem., 33, 687 (1994)
330)	Kinetic evidence for unexpectedly strong precursor formation in ligand substitution reactions of aquacobalamin (vitamin B_12a) F.F. Prinsloo, M. Meier and R. van Eldik Inorg. Chem., 33, 900 (1994)
331)	Steric and nucleophilic control over the versatile complex-formation kinetics of model cis-bis(amine)palladium(II) complexes with inosine and inosine 5'-monophosphate S. Suvachittanont and R. van Eldik Inorg. Chem., 33, 895 (1994)
332)	Pressure effects on the rates of intramolecular electron transfer in ruthenium-modified cytochrome c. Role of intervening medium in tuning distant Fe²⁺:Ru³⁺ electronic coupling M. Meier, R. van Eldik, I.-J. Chang, G.A. Mines, D.S. Wutke, J.R. Winkler and H.B. Gray J. Am. Chem. Soc., 116, 1577 (1994)
333)	A fascinating demonstration of sulfite-induced redox cycling of metal ions initiated by shaking N. Coichev and R. van Eldik J. Chem. Educ., 71, 767 (1994)
334)	An UV-VIS fast scanning spectrometer, based on a double diode array detector coupled to a stopped-flow instrument, to record absorption spectra in the millisecond time range A. Gerhard, W. Gaede, A. Neubrand, V. Zang, R. van Eldik and P. Stanitzeck Instrum. Sci. Techn., 22, 13 (1994)
335)	Kinetics and mechanism of the oxidation of glutathione by hexacyanoferrate(III) in aqueous solution G. Stochel, P. Martinez and R. van Eldik J. Inorg. Biochem, 54, 131 (1994)
336)	Chemistry under extreme conditions - new possibilities and challenges R. van Eldik Editorial in GIT Fachz.Lab., 38, 3 (1994)
337)	Ligand interchange controls many oxidations of divalent first row transition metal ions by free radicals R. van Eldik, H. Cohen and D. Meyerstein Inorg.Chem., 33, 1566 (1994)
338)	To what extent can the Pt-C bond of a metallacycle labilize the trans position? A temperature and pressure dependent mechanistic study M. Schmülling, A.D. Ryabov and R. van Eldik J. Chem. Soc., Dalton Trans., 1257 (1994)
339)	A high-pressure NMR probehead for measurements at 400 MHz A. Zahl, A. Neubrand, S. Aygen and R. van Eldik Rev. Sci. Instrum., 65, 882 (1994)
340)	An easy route to homo- and heteroleptic biscycloplatinated complexes without recourse to organolithium compounds A.D. Ryabov and R. van Eldik Angew. Chem., 106, 798 (1994) Angew. Chem. Int. Ed. Engl., 33, 783 (1994)
341)	A volume profile analysis of oxidative addition to palladium(II) and reductive elimination from palladium(IV) C. Dücker-Benfer, R. van Eldik and A.J. Canty Organometallics, 13, 2412 (1994)
342)	The mechanism of decomposition of Cu(III)GlyGlyHis. A pulse radiolysis study S. Goldstein, G. Czapski, H. Cohen, D. Meyerstein and R. van Eldik Inorg. Chem., 33, 3255 (1994)
343)	The influence of organic acids and metal ions on the kinetics of the oxidation of sulfur(IV) by hydrogen peroxide L. Breytenbach, W. van Pareen, J.J. Pienaar and R. van Eldik Atmos. Environment, 28, 2451 (1994)
344)	Kinetics of the oxidation of chromium(II) by hydrogen peroxide. Effect of different anions, temperature and pressure W. Gaede and R. van Eldik Inorg. Chem., 33, 2204 (1994)
345)	Metal to ligand charge transfer photochemistry of metal-metal bonded complexes. 12. The primary photo-process of (CO)₅ReMn(CO)₃(-diimine) complexes studied by temperature and pressure dependent photochemistry and pico- and nanosecond flash photolysis B.D. Rossenaar, T. van der Graaf, R. van Eldik, C.H. Langford, D.J. Stufkens and A. Vlcek Inorg. Chem., 33, 2865 (1994)
346)	Mechanistic information on ligand substitution reactions of gadolinium(III) in aqueous solution from high-pressure stopped-flow experiments K.B. Reddy, S. Cao, E.C. Orr, I. Fabian, R. van Eldik and E.M. Eyring J. Chem. Soc., Dalton Trans., 2497 (1994)
347)	Kinetics and mechanism of the substitution reaction of cis-diamminebis(1-methyluracilato)platinum(II) in aqueous solution M. Schmülling, B. Lippert and R. van Eldik Inorg. Chem., 33, 3276 (1994)
348)	Volumes of activation for -elimination and related reactions of chromium(III)-alkyl complexes in aqueous solution H. Cohen, R. van Eldik, W. Gaede, A. Gerhard, S. Goldstein, G. Czapski and D. Meyerstein Inorg. Chim. Acta, 227, 57 (1994)
349)	Influence of mixed sulfur-nitrogen-oxides on the redox kinetics of manganese ions in aqueous solution F.F. Prinsloo, J.J. Pienaar, R. van Eldik and H. Gutberlet J. Chem. Soc., Dalton Trans, 2373 (1994)
350)	Volume profile analysis for intermolecular electron transfer between cytochrome c and Co(terpy)₂^2+/3+ M. Meier and R. van Eldik Inorg. Chim. Acta, 225, 95 (1994)
351)	Product identification and kinetic data for the reaction of S(IV) with N(III) oxoacids in aqueous solution in the absence and presence of metal ions M. GeiÃŸler and R. van Eldik Polyhedron, 13, 2983 (1994)
352)	Steric and electronic tuning of Michael addition reactions induced by pentacarbonyl metal fragments R. Pipoh and R. van Eldik Inorg. Chim. Acta, 222, 207 (1994)
353)	Investigation of rain and snow water samples by AAS and IC C. Brandt, V. Lepentsiotis, A. Paul, H. Hohmann and R. van Eldik GIT Fachz. Lab., 38, 770 (1994)
354)	Kinetics and mechanism of the oxidation of sulfur(IV) by ozone in aqueous solution C.F. Botha, J. Hahn, J.J. Pienaar and R. van Eldik Atmos. Environment., 28, 3207 (1994)
355)	Mechanistic information from the first volume profile analysis for a reversible intermolecular electron-transfer reaction involving isonicotinamide(pentaammine)ruthenium and cytochrome c B. Bänsch, M. Meier, P. Martinez, R. van Eldik, C. Su, J. Sun, S.S. Isied and J.F. Wishart Inorg. Chem., 33, 4744 (1994)
356)	Outer-sphere redox reactions in sterically hindered pentaam(m)inecobalt(III) complexes. A temperature and pressure dependence study M. Martinez, M.-A. Pitarque and R. van Eldik J. Chem. Soc. Dalton Trans., 3159 (1994)
357)	⁷Li-NMR determination as a function of temperature for lithium-crown ether complexes in a molten salt mixture A. Gerhard, D.P. Cobranchi, B.A. Garland, A.M. Highley, Y.-H. Huang, G. Konya, A. Zahl, R. van Eldik, S. Petrucci and E.M. Eyring J. Phys. Chem., 98, 7923 (1994)
358)	Evidence for a chelate-induced changeover in the substitution mechanism of aquated copper(II). Volume profile analysis of water exchange and complex-formation reactions D.H. Powell, A.E. Merbach, I. Fabian, S. Schindler and R. van Eldik Inorg. Chem., 33, 4468 (1994)
359)	Dioxygen binding to a macrocyclic dinuclear copper(II) monoxygenase model system. Ambient and high pressure kinetics. M. Becker, S. Schindler and R. van Eldik Inorg. Chem., 33, 5370 (1994)
360)	The synthesis, X-ray structure and hydrolysis kinetics of chloro (2-aminomethylpyridine)(triamine)chromium(III) salts D.A. House, S. Schaffner, R. van Eldik, A. McAuley and M. Zhender Inorg. Chim. Acta, 227, 11 (1994)

1995-1999

Publications of 1995
361)	Transition metal catalyzed oxidation of sulfur(IV)-oxides. Atmospheric-relevant processes and mechanisms C. Brandt and R. van Eldik Chem. Rev., 95, 119-190 (1995)
362)	Mechanistic study of the coordination of hydrogen peroxide to methylrhenium trioxide O. Pestovsky, R. van Eldik, P. Huston and J.H. Espenson J. Chem. Soc. Dalton Trans., 133 (1995)
363)	Pressure effects on the rates of Hg²⁺-assisted chloride release from some [CrCl(diamine)(triamine)]²⁺ complexes D.A. House and R. van Eldik Inorg. Chim. Acta, 230, 29 (1995)
364)	Temperature and pressure effects on the kinetics of the bromate ion - iodide ion - L ascorbic acid clock reaction I. Fabian and R. van Eldik Int. J. Chem. Kinet., 27, 491 (1995)
365)	Substitution reactions of trans-[Ru(NH₃)₄(P(OEt)₃)(H₂O)]²⁺ revisited. Mechanistic elucidation from a volume profile analysis B.S. Lima Neto, D.W. Franco and R. van Eldik J. Chem. Soc., Dalton Trans. 463, (1995)
366)	Kinetics and mechanism of halogen-bridge cleavage in dimethylaminomethyl-phenyl-C,N-pallada- and platinacycles by pyridines. Pressure effects and X-Ray structural characterization of the N,N-cis-[Pt(o-C₆H₃(4-MeO)CH₂NMe₂)-Cl(py)] reaction product, its N,N-trans-[Pt(o-C₆H₄C(Me)=NOH)Cl(py)] orthometallated analog and trans-[(ⁿBu₃P)IPd(-I)₂Pd(PⁿBu₃)I], the dimer of similar reactivity A.D. Ryabov, L.G. Kuz'mina, V.A. Polyakov, G.M. Kazankov, E.S. Ryabova, M. Pfeffer and R. van Eldik J. Chem. Soc., Dalton Trans., 999 (1995)
367)	Kinetic evidence for the redox cycling of Mn(II/III) in the presence of N-nitroso hydroxyl-amine-N-sulfonate in aqueous medium F.F. Prinsloo, J.J. Pienaar and R. van Eldik J. Chem. Soc., Dalton Trans., 293 (1995)
368)	Steric control over the complex-formation and chelation kinetics of cis-bis(amine)- palladium(II) complexes with methionine and S-methyl-cysteine in weakly acidic aqueous solution S. Suvachittanont and R. van Eldik J. Chem. Soc., Dalton Trans., 2027 (1995)
369)	New optical cell design for laser flash photolysis studies in supercritical fluids Q. Ji, E.M. Eyring, R. van Eldik, K. Bal Reddy, S.R. Goates and M.L. Lee Rev. Sci. Instrum., 66, 222 (1995)
370)	Complex-formation reactions of aquacobalamin revisited: effect of chloride on the observed rate and activation parameters F.F. Prinsloo, E.L.J. Breet and R. van Eldik J. Chem. Soc., Dalton Trans., 685 (1995)
371)	Spontaneous aquation reactions of a promising tumor inhibitor trans-imidazolium-tetrachlorobis(imidazole)ruthenium(III), trans-HIm[RuCl₄(Im)₂] J. Chatlas, R. van Eldik and B.K. Keppler Inorg. Chim. Acta, 233, 59 (1995)
372)	Pressure tuning voltammetry. Reaction volumes for electron transfer in cytochrome c and ruthenium-modified cytochrome c J. Sun, J.F. Wishart, R. van Eldik, R.D. Shalders and T.W. Swaddle J. Am. Chem. Soc., 117, 2600 (1995)
373)	Use of high pressure techniques for measuring reaction rates in liquid solutions C.D. Hubbard and R. van Eldik Instrum. Sci. Techn., 23, 1 (1995)
374)	Influence of -subunits on the high-pressure stability of apo and holo ₂-subunits in the bienzyme complex tryptophan synthase from Escherichia coli S. Sindern, R. van Eldik and P. Bartholmes Biochemistry, 34, 1959 (1995)
375)	Equilibria in Chemistry R. van Eldik Editorial in GIT Fachz. Lab. 39, 83 (1995)
376)	Activation parameter correlations for nucleophilic additon to ( ₂-H)₂Os₃(CO)₁₀ A. Neubrand, A.J. Poe and R. van Eldik Organometallics, 14, 3249 (1995)
377)	Temperature, pressure and solvent isotope effects on the precursor formation constant and reorganization dynamics in outer-sphere charge transfer between free mobile [Fe(CN)₆]^3- and [Fe(CN)₆]^4- ions D.E. Khoshtariya, R. Billing, M. Ackermann and R. van Eldik J. Chem. Soc., Faraday Trans., 91, 1625 (1995)
378)	A functional model for carbonic anhydrase. Thermodynamic and kinetic study of a tetraazacyclododecane complex of zinc(II) X. Zhang and R. van Eldik Inorg. Chem., 34, 5606 (1995)
379)	Formation and deoxygenation kinetics of oxyhemerythrin and oxyhemocyanin. A pressure dependence study H.-D. Projahn, S. Schindler, R. van Eldik, D.G. Fortier, C.R. Andrew and A.G. Sykes Inorg. Chem., 34, 5935 (1995)
380)	Complex-formation reactions of dichloro(L-methionine)palladium(II) with inosine and inosine 5'-monophosphate. Labilization induced by S-donor chelate F.F. Prinsloo, J.J. Pienaar and R. van Eldik J. Chem. Soc., Dalton Trans., 3581 (1995)
381)	Electronically tuned trans-labilization controls the substitution behaviour of rhodo ximes C. Dücker-Benfer, R. Dreos and R. van Eldik Angew. Chem., 107, 2414 (1995) Angew. Chem. Int. Ed. Engl., 34, 2245 (1995)
382)	Laser flash photolysis studies of metal carbonyls in supercritical CO₂ and ethane Q. Ji, E.M. Eyring, R. van Eldik, K.P. Johnston, S.R. Goates and M.L. Lee J. Phys. Chem., 99, 13461 (1995)
383)	The reaction of aquapentaamminerhodium(III) with carbonate in strongly basic solution - A multiple choice of potential interactions resolved E. Cloete, E. Breet and R. van Eldik J. Chem. Soc., Dalton Trans., 3591 (1995)
384)	Leaving group effects on ligand substitution reactions of pentacyanoferrate(II) complexes: rate constant and activation volume correlation S. Alsheri, J. Burgess, R. van Eldik and C.D. Hubbard Inorg. Chim. Acta, 240, 305 (1995)
Publications of 1996
385)	Correlation between kinetic and thermodynamic complex-formation constants for the interaction of bis(amine)palladium(II) with inosine, inosine 5'-monophosphate and guanosine 5'-monophosphate M. Shoukry and R. van Eldik J. Chem. Soc., Dalton Trans., 2673 (1996)
386)	Mechanistic insight from kinetic studies on the interaction of model palladium(II) complexes with nucleic acid components T. Rau and R. van Eldik in "Metal Ions in Biological Systems, Vol. 32, Interactions of Metal Ions with Nucleotides, Nucleic Acids, and their Constituents", H. Sigel and A. Sigel (Eds.), Marcel Dekker, New York, 339 (1996).
387)	Comparative rates of ligand substitution reactions of Pt-C bonded complexes in aqueous solution and the x-ray structure of [Pt{C₆H₃(CH₂NMe₂)₂-2,6}(OH₂)]- [OSO₂CF₃] M. Schmülling, D.M. Grove, G. van Koten, R. van Eldik, N. Veldman and A.L. Spek Organometallics, 15, 1384 (1996)
388)	Volume of activation for the self-exchange reaction of cytochrome c M. Meier and R. van Eldik Inorg. Chim. Acta, 242, 185 (1996)
389)	Mechanistic information on ligand substitution reactions of europium(III) in aqueous solution from high pressure stopped-flow experiments Y. Shi, Q. Ji, E.M. Eyring and R. van Eldik J. Chem. Soc., Dalton Trans., 2127 (1996)
390)	Novel building blocks for biomimetic assemblies. Synthesis, characterization, spectroscopic and electrochemical properties of new bidentate ligands derived from lysine and cysteine and their complexes with bis(2,2'-bipyridine)ruthenium(II) R. Alsfasser and R. van Eldik Inorg. Chem., 35, 628 (1996)
391)	An unified mechanistic view obtained from the temperature and pressure depen dence of the spontaneous, acid-, and base-assisted cyclometallation reactions of dirhodium(II) complexes F. Estevan, G. Conzales, P. Lahuerta, M. Martinez, E. Peris and R. van Eldik J. Chem. Soc., Dalton Trans., 1045 (1996)
392)	Influence of mixed sulfur-nitrogen-oxides on the redox kinetics of iron ions in aqueous solution V. Lepentsiotis, F.F. Prinsloo, R. van Eldik and H. Gutberlet J. Chem. Soc., Dalton Trans., 2135 (1996)
393)	Comparative kinetic analysis of reversible intermolecular electron-transfer reac tions between a series of pentaammineruthenium complexes and cytochrome c M. Meier, J. Sun, J.F. Wishart and R. van Eldik Inorg. Chem., 35, 1564 (1996)
394)	Reaction mechanism of phenanthroline derivatives chelating Mo(CO)₅ deduced from pulsed photolysis in several solvents at high pressure S. Cao, Y. Shi, J. Hollmann, R. van Eldik and E.M. Eyring J. Chem. Soc., Dalton Trans., 1629 (1996)
395)	Synthesis and characterization of highly fluorinated tungsten(II) metallocyclopropane complexes. Kinetics and mechanism of an unprecedented ²-vinyl isomerization J.L. Kiplinger, T.G. Richmond, A.M. Arif, C. Dücker-Benfer and R. van Eldik Organometallics, 15, 1545 (1996)
396)	Mechanistic studies on the formation and decay of diiron(III) peroxo complexes in the reaction of diiron(II) precursors with dioxygen A.L. Feig, M. Becker, S. Schindler, R. van Eldik and S.J. Lippard Inorg. Chem., 35, 2590 (1996)
397)	Tuning the reactivity of platinum(II) complexes through cyclometallation. A reply M. Schmülling, A.D. Ryabov and R. van Eldik J. Chem. Soc., Dalton Trans., 1471 (1996)
398)	Formation of sulfur and sulfur-nitrogen compounds in the flue gas desulfurization plants and their influence on the oxidation kinetics of sulfite H. Gutberlet, S. Finkler, B. Pätsch, R. van Eldik and F.F. Prinsloo VGB Kraftwerktechnik, 76, 139 (1996)
399)	Carbonic anhydrase catalysis. A volume profile analysis X. Zhang, C.D. Hubbard and R. van Eldik J. Phys. Chem., 100, 9161 (1996)
400)	Outer-sphere redox reactions of [Co^III(NH₃)₅(H_XP_YO_Z)]^(n-3)- complexes. A tempera ture- and pressure-dependence kinetic study on the influence of the phosphorous oxoanions M. Martinez, M.-A. Pitarque and R. van Eldik J. Chem. Soc., Dalton Trans., 2665 (1996)
401)	Theoretical study of the water exchange reaction on divalent zinc ion using density functional theory M. Hartmann, T. Clark and R. van Eldik J. Mol. Model., 2, 354 (1996)
402)	Investigation of the uncatalyzed hydration of CO₂ and the first approximations to the active site of carbonic anhydrase - A combined ab-initio and DFT study M. Hartmann, T. Clark and R. van Eldik J. Mol. Model., 2, 358 (1996)
403)	Chemistry goes supercritical - A host of environmental friendly new possibilities for the chemical process industry E. Breet, R. van Eldik and R. Steiner Chemical Processing SA, August, 6 (1996)
404)	Photo-substitution reactions of Cr(CO)₄(1,10-phenanthroline). Mechanistic information from entering nucleophile, irradiation wavelength and pressure dependences W.-F. Fu and R. van Eldik Inorg. Chim. Acta, 251, 341 (1996)
405)	Kinetics and mechanism of the reduction of 1,2-diaminocyclohexanetetraacetato-manganese(III) by hydroxylaminemonosulfonate and hydroxylaminedisulfonate F.F. Prinsloo, J.J. Pienaar and R. van Eldik J. Chem. Soc., Dalton Trans., 4393 (1996)
406)	Review of the activities and achievements of the EUROTRAC subproject HALIPP P. Warneck, P. Mirabel, G.A. Salmon, R. van Eldik, C. Vinckier, K.J. Wannowius and C. Zetzsch "Heterogeneous and Liquid-Phase Processes", P. Warneck (Ed.), Springer, Chapter 2, 1996.
407)	The interaction of SO_X and NO_Y species in aqueous solution. Photo and metal ion catalysis R. van Eldik, M. GeiÃŸler, C. Brandt and V. Lepentsiotis "Heterogeneous and Liquid.Phase Processes", P. Warneck (Ed.), Springer, 126 (1996)
408)	Geometric factors in the structural and thermodynamic properties of copper(II) complexes with tripodal tetraamines A.M. Dittler-Klingemann, C. Orvig, F.E. Hahn, F. Thaler, C.D. Hubbard, R. van Eldik, S. Schindler and I. Fabian Inorg. Chem., 35, 7798 (1996)
Publications of 1997
409)	Formation of transient iron(III)-sulfur(IV) complexes revisited. Application of rapid-scan techniques F.F. Prinsloo, C. Brandt, V. Lepentsiotis, J.J. Pienaar and R. van Eldik Inorg. Chem., 36, 119 (1997)
410)	Kinetic and thermodynamic study of the mechanism of reversible intermolecular electron-transfer reactions between horse heart cytochrome c and a series of co balt imine complexes M. Meier and R. van Eldik Chemistry Eur. J., 3, 33 (1997)
411)	Photo-substitution reactions of M(CO)₄(1,10-phenanthroline) (M = Mo, W). Influence of entering ligand, irradiation wavelength and pressure W.-F. Fu and R. van Eldik Organometallics, 16, 572 (1997)
412)	Probing the solvation properties of liquid versus supercritical fluids with laser flash photolysis of W(CO)₆ in the presence of 2,2'-bipyridine Q. Ji, C.R. Lloyd, E.M. Eyring and R. van Eldik J. Phys. Chem., A, 101, 243 (1997)
413)	Effect of pressure on inorganic reactions C.D. Hubbard and R. van Eldik in "Chemistry under Extreme or Non-Classical Conditions", R. van Eldik and C.D. Hubbard (Eds.), Wiley/Spektrum, New York/Heidelberg, Chapter 2, 1997
414)	Kinetic and thermodynamic measurements under pressure D. Magde and R. van Eldik in "High Pressure Techniques in Chemistry and Physics: a practical approach", N. Isaacs and W. Holzapfel (Eds.), Oxford University Press, Oxford, Chapter 6, 1997
415)	Photochemical behaviour of metal complexes. Pressure effects versus mechanism G. Stochel and R. van Eldik Coord. Chem. Rev., 159, 153 (1997)
416)	Outer-sphere redox reactions of (N)₅-macrocyclic cobalt(III) complexes. A tempe rature and pressure dependence kinetic study on the influence of size and geome try of different macrocycles M. Martinez, M.-A. Pitarque and R. van Eldik Inorg. Chim. Acta, 256, 51 (1997)
417)	Anionopetaaminecobalt(III) complexes. 27. Activation volumes for spontaneous and Hg²⁺-assisted chloride release reactions J. Chatlas, D.A. House, A. Neubrand and R. van Eldik Inorg. Chim. Acta, 257, 173 (1997)
418)	Coordination and organometallic chemistry under extreme or non-classical conditions R. van Eldik and C.D. Hubbard New J. Chem., 21, 825 (1997)
419)	Complex-formation and ligand substitution reactions of 2-picolylamine palladium(II) with various biologically relevant ligands. Characterization of 2-picolylamine-(1,1-cyclobutane- dicarboxylate)palladium(II) T. Rau, M. Shoukry and R. van Eldik Inorg. Chem., 36, 1454 (1997)
420)	Reactivity of nucleophiles toward x-3-(p-tolylsulfonyl)-1,2,3-benzoxathiaole-2,2- dioxides: Kinetics, activation volumes, and mechanism K.K. Andersen, C.D. Hubbard, A. Gerhard, R. van Eldik and M.G. Kociolek J. Phys. Org. Chem., 10, 175 (1997)
421)	Kinetics and mechanism of the reduction of hexacyanoferrate(III) by myoglobin in aqueous solution E. Ilkowska, R. van Eldik and G. Stochel J. Biol. Inorg. Chem., 2, 603 (1997)
422)	Copper(III) pyrophosphate complexes in aqueous solution. A pulse radiolysis study at ambient and high pressure D.E. Cabelli, J.F. Wishart, J. Holcman, M. Meier and R. van Eldik J. Phys. Chem. A, 101, 5131 (1997)
423)	Evidence for the unexpected associative displacement of adenosyl by cyanide in coenzyme B₁₂ N.E. Brasch, M.S.A. Hamza and R. van Eldik Inorg. Chem., 36, 3216 (1997)
424)	Competing thermal and photochemical ligand substitution of the dimetallacycle (CO)₄Mo( -PMD)₂Mo(CO)₄, PMD = pentamethylenediazirine. Mechanistic infor mation from nucleophile and pressure dependences W.-F. Fu, H. Kisch and R. van Eldik Organometallics, 16, 3439 (1997)
425)	Preferred coordination sites for metal fragments in , -bimetallic complexes. Detailed mechanistic insights from heteroatom, bridging ligand, solvent, tempera ture and pressure effects on the irreversible exchange of coordination sites T.A. Waldbach, R. van Eldik, P.H. van Rooyen and S. Lotz Organometallics, 16, 4056 (1997)
426)	Kinetics and thermodynamics of the aquation of amminepentacyanoferrate(II). A volume profile analysis I. Maciejowska, R. van Eldik, G. Stochel and Z. Stasicka Inorg. Chem., 36, 5409 (1997)
427)	Activation parameters for the decomposition of peroxynitrite and peroxynitrate, and their reduction by iodide. An insight into the detailed mechanism S. Goldstein, D. Meyerstein, R. van Eldik and G. Czapski J. Phys. Chem. A, 101, 7114 (1997)
428)	Kinetics and mechanism of reduction of tris(acetylacetonato)manganese(III) by HONH(SO₃)^- and HON(SO₃)₂^2- in aqueous solution F.F. Prinsloo, J.J. Pienaar and R. van Eldik J. Chem. Soc., Dalton Trans., 1871 (1997)
429)	Application of extreme or non-classical conditions in chemistry R. van Eldik and C.D. Hubbard GIT Laboratory Journal, 1, 9 (1997)
430)	Dynamics of CO binding to lacunar iron(II) cyclidene complexes M. Buchalova, P.R. Warburton, R. van Eldik and D.H. Busch J. Am. Chem. Soc., 119, 5867 (1997)
431)	A mechanistic study of the reduction of quinones by ascorbic acid N.S. Isaacs and R. van Eldik J. Chem. Soc., Perkin Trans. 2, 1465 (1997)
432)	Hydration and water exchange of zinc(II) ions. Application of density functional theory M. Hartmann, T. Clark and R. van Eldik J. Am Chem. Soc., 119, 7843 (1997)
433)	The formation of dithionate during the iron(III)-catalyzed autoxidation of sulfur(IV)-oxides C. Brandt and R. van Eldik Atmos. Environm., 31, 4247 (1997)
434)	Kinetics of Fe^II(edta) oxidation by molecular oxygen revisited. New evidence for a multistep mechanism S. Seibig and R. van Eldik Inorg. Chem., 36, 4115 (1997)
435)	Fixation of CO₂ by zinc(II) chelates in alcoholic medium. X-ray structure of {[Zn(cyclen)]₃( ₃-CO₃)}(ClO₄)₄ and [Zn(cyclen)EtOH](ClO₄)₂ A. Schrodt, A. Neubrand and R. van Eldik Inorg. Chem., 36, 4579 (1997)
436)	Formation of an association complex without a substitution reaction occurring between methylcobalamin and cyanide N.E. Brasch, F. Müller, A. Zahl and R. van Eldik Inorg. Chem., 36, 4891 (1997)
437)	X-ray and solution structure of inosine 5'-monophosphate coordinated to (ethylene diamine)palladium(II). The importance of intramolecular hydrogen bonding T. Rau and R. van Eldik Chem. Ber./Recueil, 130, 1551 (1997)
438)	Kinetics and mechanism of substitution reactions of cis-[PtMe₂(dmso)₂] with pyridine M. Schmülling and R. van Eldik Chem. Ber./Recueil, 130, 1791 (1997)
439)	Kinetics and mechanism of the Fe(III) complexation by lipophilic 3-hydroxy-2- methyl-1( -stearoamidopropyl)-4-pyridinone (HMSP) Y. Shi, E.M. Eyring, R. van Eldik, G. Liu, F.W. Bruenger and S.C. Miller J. Biol. Inorg. Chem., 2, 728 (1997)
440)	Pyrolysis of plastics containing brominated flame retardants B. Danzer, M. Riess, H. Thoma, O. Vierle and R. van Eldik Organohalogen Compounds, 31, 108 (1997)
Publications of 1998
441)	Electron-transfer reactions under high pressure. Application of spectroscopic and electrochemical techniques R. van Eldik in "Photochemistry and Radiation Chemistry: Complementary Methods in the Study of Electron Transfer", D. Nocera and J.F. Wishart (Eds.), Advances in Chemistry Series Vol. 254, Chapter 19, American Chemical Society, Washington, 1998
442)	Pressure tuning photochemistry of metal complexes in solution R. van Eldik and P.C. Ford Advances in Photochemistry, Vol. 24, D.C. Neckers, D.H. Volman and G. von Bünau (Eds.), Wiley, New York, 61 (1998)
443)	Kinetic analysis of the complexation of aqueous lanthanide(III) ions by arsenazo III Y. Shi, E.M. Eyring and R. van Eldik J. Chem. Soc., Dalton Trans., 967 (1998)
444)	Systematic tuning of the photo-substitution mechanism of M(CO)₄(1,10-phenanthroline) by variation of the metal, entering nucleophile, excitation wavelength and pressure W.-F. Fu and R. van Eldik, Inorg. Chem., 37, 1044 (1998)
445)	Thermal ring-closure reactions of pentacarbonylchromium complexes wirth biden tate N-N ligands revisited. Elimination of side reactions and the elucidation of the intimate mechanism C. Dücker-Benfer, F.-W. Grevels and R. van Eldik Organometallics, 17, 1669 (1998)
446)	Effect of pressure on the reversible binding of acetonitrile to the "Co(I)-CO₂" adduct to form Co(III) carboxylate E. Fujita and R. van Eldik Inorg. Chem., 37, 360 (1998)
447)	Photochemistry of the triangular clusters Os₃(CO)₁₀(-diimine). Homolysis of an Os-Os bond and solvent-dependent formation of biradicals and zwitterions J. Nijhoff, M.J. Bakker, F. Hartl, D.J. Stufkens, W.-F. Fu and R. van Eldik Inorg. Chem., 37, 661 (1998)
448)	Mechanistic insight from energy and volume profiles for CO binding to a lacunar iron(II) cyclidene complex M. Buchalova, D.H. Busch and R. van Eldik Inorg. Chem., 37, 1116 (1998)
449)	The double-well cage effect for a ferrocyanide/dimethylviologen ion pair in vis cous media. Kinetic and thermodynamic probings through the CT transition band D.E. Koshtariya, A. Neubrand and R. van Eldik Chem. Phys. Lett., 284, 121 (1998)
450)	Mechanistic insight from rapid-scan stopped-flow spectrophotometry into the autoxidation of ascorbate catalysed by an iron porphyrin complex V. Lepentsiotis and R. van Eldik J. Chem. Soc., Dalton Trans., 999 (1998)
451)	Specific chelate tuning of the substitution kinetics of platinum(II) complexes in aqueous solution U. Fekl and R. van Eldik Eur. J. Inorg. Chem., 389 (1998)
452)	Reactive intermediates in the photodecarbonylation of the cyclopentadienyl and the indenyl complexes of CpFe(CO)₂(C(O)CH₃) and IndFe(CO)₂(C(O)CH₃) (Cp = ⁵-C₅H₅; Ind = ⁵-C₉H₇) K.L. McFarlane, B. Lee, W.-F. Fu, R. van Eldik and P.C. Ford Organometallics, 17, 1826 (1998)
453)	Relative reactivity of N- and S-donor ligands in the substitution reactions of aquaethylenedinitrilotetraacetatoruthenium(III) in aqueous solution H.C. Bajaj, A. Das and R. van Eldik J. Chem. Soc., Dalton Trans., 1563 (1998)
454)	Cooperative oxidation of edta by Ni(III) and dioxygen. A pulse radiolysis study I. Zilbermann, E. Maimon, H. Cohen, R. van Eldik and D. Meyerstein Inorg. Chem. Commun., 1, 46 (1998)
455)	Regio- and stereoselective cyclization reactions of unsaturated silyl enol ethers by photoinduced electron transfer. Mechanistic aspects and synthetic approach S. Hintz, J. Mattay, R. van Eldik and W.-F. Fu Eur. J. Org. Chem., 1583 (1998)
456)	High-pressure oxygen-17 NMR study of the dihydroxo-bridged rhodium(III) hy drolytic dimer. Mechanistic evidence for limiting dissociative water exchange pathways A. Drljaca, A. Zahl and R. van Eldik Inorg. Chem., 37, 3948 (1998)
457)	Structural, spectroscopic, thermodynamic and kinetic properties of copper(II) com plexes with tripodal tetraamines F. Thaler, C.D. Hubbard, F.W. Heinemann, R. van Eldik, S. Schindler, I. Fabian, A.M. Dittler-Klingemann, F.E. Hahn and C. Orvig Inorg. Chem., 37, 4022 (1998)
458)	Kinetics and mechanism of the iron(III)-catalyzed autoxidation of sulfur(IV) oxides in aqueous solution. The influence of pH, medium and aging C. Brandt and R. van Eldik Transition Metal Chem., 23, 667 (1998)
459)	Hydrogen carbonate inhibited and induced substitution reactions of labile square- planar diethylenetriaminepalladium(II) complexes E. Breet and R. van Eldik Ber. Bunsenges. Phys. Chem., 102, 1418 (1998)
460)	The redox kinetics of platinum(II)/(IV) complexes K. Hindmarsh, D.A. House and R. van Eldik Inorg. Chim. Acta, 278, 32 (1998)
461)	Structural and kinetic studies on the formation of platinum(II) and palladium(II) complexes with L-cysteine-derived ligands T. Rau, R. Alsfasser, A. Zahl and R. van Eldik Inorg. Chem., 37, 4223 (1998)
462)	Kinetics and mechanism of the ligand substitution reactions of bis(amine)-(cyclobutane-1,1-dicarboxylato)palladium(II) A. Shoukry, T. Rau, M. Shoukry and R. van Eldik J. Chem. Soc., Dalton Trans., 3105 (1998)
463)	Investigation of the redox interaction between iron(III) 5,10,15,20-tetrakis-(p-sulfonatophenyl)porphyrinate and aminoiminomethanesulfinic acid in aqueous solution V. Lepentsiotis, R. van Eldik, D.M. Stulov and S.V. Makarov J. Chem. Soc., Dalton Trans., 2915 (1998)
464)	Structural information on trans-1,2-diaminocyclohexane-N,N'-tetraacetateferrate(III) in the solid and aqueous phase S. Seibig and R. van Eldik Inorg. Chim Acta, 279, 37 (1998)
465)	Activation and reaction volumes in solution. 3 A. Drljaca, C.D. Hubbard, R. van Eldik, T. Asano, M.V. Basilevsky and W.J. le Noble Chem. Rev., 98, 2167-2289 (1998)
466)	Mechanistic elucidation of small molecule - transition metal interactions by kinetic techniques S. Schindler, C.D. Hubbard and R. van Eldik Chem Soc. Rev., 27, 387 (1998)
467)	Complex formation of iron(II/III) with [15]aneN₄ in aqueous solution. Kinetics of the oxidation of Fe^II([15]aneN₄) by dioxygen A. Schrodt and R. van Eldik Inorg. React. Mechn., 1, 57 (1998)
468)	Kinetics and mechanism of the reduction of pentacyanonitroferrate(III) by L-ascorbic acid in acidic aqueous solution A. Wanat, R. van Eldik and G. Stochel J. Chem. Soc. Dalton Trans., 2497 (1998)
469)	The important role of active site water in the catalytic mechanism of human car bonic anhydrase II. A semiempirical MO approach to the hydration of CO₂ M. Hartmann, K.M Merz, Jr., R van Eldik and T. Clark J. Mol. Model., 4, 355 (1998).
470)	Kinetics and mechanism of the complexation of aqueous lanthanide ions by 4-(2- pyridylazo)resorcinol Y. Shi, E.M. Eyring and R. van Eldik J. Chem. Soc., Dalton Trans., 3565 (1998)
471)	Effect of fumarate on the kinetics and the reaction mechanism of Cu⁺_aq with dioxygen N. Navon, H. Cohen, R. van Eldik and D. Meyerstein J. Chem. Soc., Dalton Trans., 3663 (1998)
472)	Extraction of flame retarded thermoplastic polymers by ASE M. RieÃŸ, T. Ernst, G. Biermann and R. van Eldik GIT Lab. Fachz., 1008 (1998)
473)	Mechanistic information from the first volume profile analysis for intramolecular electron-transfer reactions. Tetraammineruthenium(ligand) complexes of cytochrome c J. Sun, C. Su, M. Meier, S.S. Isied, J.F. Wishart and R. van Eldik Inorg. Chem., 37, 6129 (1998)
474)	High pressure studies in inorganic chemistry. Volume profiles for the activation of small molecules by transition metals S. Schindler and R. van Eldik in "High Pressure Food Science, Bioscience and Chemistry", N.S. Isaacs (Ed.), The Royal Society of Chemistry, London, 47 (1998)
475)	Analysis of flame retarded polymers and recycling materials M. Riess, T. Ernst, R. Popp, Th. Schubert, H. Thoma, O. Vierle, G.W. Ehrenstein and R. van Eldik Organohalogen Compounds, 35, 443 (1998)
476)	Identification of brominated flame retardants in polymeric materials by reversed- phase liquid chromatography with ultraviolet detection M. Riess and R. van Eldik J. Chromatogr. A, 827, 65 (1998)
Publications of 1999
477)	Mechanistic studies in coordination chemistry R. van Eldik Coord. Chem. Rev., 182, 373 (1999)
478)	The hydrolysis kinetics of cis-diamminedichloroplatinum(II). 10. Activation volumes for halide anation of some cis-[Pt(N)₂(OH₂)₂]²⁺ systems K. Hindmarsh, D.A. House and R. van Eldik Inorg. React. Mechn., (1999)
479)	Studies on kinetics and mechanism of imidazole substitution from cis-equatorial-[Cr(S-pdtra)(Him)]⁰ complex in acidic and alkaline aqueous solution [S-pdtra = (S)-propylenediamintriacetate] J. Chatlas, S. Kaizaki, E. Kita, P. Kita, N. Sakagami and R. van Eldik J. Chem. Soc., Dalton Trans., 91 (1999)
480)	Zinc(II) complexes of tripodal peptides mimicking the zinc(II)-coordination structure of carbonic anhydrase U. Herr, W. Spahl, W. Steglich, F. Thaler and R. van Eldik Bioorg. Medic. Chem., 7, 699 (1999)
481)	Kinetics of dissociation of the cobalt(II) and copper(II) complexes of 2,2',2"-tris(monomethylamino)triethylamine in aqueous acidic solution F. Thaler, C.D. Hubbard and R. van Eldik Inorg. React. Mechn., 1, 83 (1999)
482)	Multistep oxidation kinetics of [Fe^II(cdta)] [cdta = N,N',N'',N'''-(1,2-cyclohexane-diamine)tetraacetate] with molecular oxygen S. Seibig and R. van Eldik Eur. J. Inorg. Chem., 447 (1999)
483)	Models for the initial stage of oxidative addition. Synthesis, characterization and mechanistic investigation of η¹-I₂ organometallic "pincer" complexes of the platinum group metals. The x-ray crystal structures of [PtI(C₆H₃{CH₂NMe₂}₂-2,6)- (η¹- I₂)], exo-meso-[Pt(η¹-I₃)(η¹-I₂)(C₆H₃{CH₂N(t-Bu)Me}₂-2,6)] and [PdI(C₆H₃-{CH₂NMe₂}₂-2,6)]^.(I₂)₂ R.A. Gossage, A.D. Ryabov, A.L. Spek, D.J. Stufkens, J.A.M. van Beek, R. van Eldik and G. van Koten J. Am. Chem. Soc., 121, 2488 (1999)
484)	Elucidation of inorganic reaction mechanisms through volume profile analysis G. Stochel and R. van Eldik Coord. Chem. Rev., 187, 329 (1999)
485)	Control of iron(II) spin states in 2,2':6',2''-terpyridine complexes through ligand substitution E.C. Constable, G. Baum, E. Bill, R. Dyson, R. van Eldik, D. Fenske, S. Kaderli, D. Morris, A. Neubrand, M. Neuburger, D.R. Smith, K. Wieghardt, M. Zehnder and A.D. Zuberbühler Chem. Eur. J., 5, 498 (1999)
486)	Kinetics and mechanism of the base hydrolysis in cobalt(III) complexes - The case of a complex CoLCl²⁺ where L has the novel topology of a square-pyramidal NN₄ coordination cap T. Poth, H. Paulus, H. Elias, R. van Eldik and A. Grohmann Eur. J. Inorg. Chem., 643 (1999)
487)	The influence of steric effects on the oxidation kinetics of [Fe^II(aminopolycarboxylato)] complexes with dioxygen S. Seibig and R. van Eldik Inorg. React. Mechn., 1, 91 (1999)
488)	Kinetic, structural, and electrostatic aspects of the reduction of pentacyanoferrate(III) complexes by myoglobin E. Ilkowska, K. Lewinski, R. van Eldik and G. Stochel J. Biol. Inorg. Chem., 4, 302 (1999)
489)	The catalytic action of iron(II) complexes of 1-methyl-5,8-bis(2'-pyridylmethyl)- 1,5,8-triazacycloundecane and 1-methyl-5,9-bis(2'-pyridylmethyl)-1,5,9-triazacyclododecane X. Zhang, D. Zhang, D.H. Busch and R. van Eldik J. Chem. Soc., Dalton Trans., 2751, 1999
490)	Oxidation of benzenediols by hexabromoiridate(IV): Kinetics at ambient and elevated pressures C. Ciosto, H.C. Bajaj, R. van Eldik and C.D. Hubbard J. Chem. Soc., Dalton Trans., 1503, 1999.
491)	Kinetics and mechanism of the complexation of La³⁺ and Cu²⁺ ions with N-methylacetohydroxamic acid and desferrioxamine B M. Birus, M. Gabricevic, O. Kronja, B. Klaic, R. van Eldik and A. Zahl Inorg. Chem., 38,4064,1999
492)	Inorganic and bioinorganic reaction kinetics under high pressure R. van Eldik High Pressure Molecular Science, R. Winter and J. Jonas (Eds.), Kluwer Academic Publishers, Dordrecht, 267 (1999)
493)	Pressure effect on the decomposition rate of peroxynitrous acid resolved. Evidence for homolysis S. Goldstein, D. Meyerstein, R. van Eldik and G. Czapski J. Phys. Chem. A, 103, 6587 (1999)
494)	Detailed mechanistic information on methane elimination from a methyl(hydrido)-platinum(IV) complex. Relevance for the mechanism of methane activation U. Fekl, A. Zahl and R. van Eldik Organometallics, 18, 4156 (1999)
495)	Kinetics and mechanism of the outer-sphere oxidation of horse heart cytochrome c by an anionic chromium(V) complex. Kinetic evidence for precursor formation and a late electron-transfer transition state M. Körner and R. van Eldik Eur. J. Inorg. Chem., 1805 (1999)
496)	Enantioselectivities in electron-transfer and excited state quenching reactions of a chiral ruthenium complex possessing a helical structure T. Hamada, B.S. Brunschwig, K. Eifuku, E. Fujita, M. Körner, S. Sasaki, R. van Eldik and J.F. Wishart J. Phys. Chem. A, 103, 5645 (1999)
497)	Mechanistic information on the redox cycling of Ni(II/III) complexes in the presence of sulfur oxides and oxygen. Correlation with DNA damage experiments V. Lepentsiotis, J. Domagala, I. Grgic, R. van Eldik, J.G. Muller and C.J. Burrows Inorg. Chem., 38, 3500 (1999)
498)	Structural and functional investigation on diiron complexes: Catalase-like activity and mechanistic studies on the formation of (-peroxo)diiron(III) adducts R. Than, A. Schrodt, L. Westerheide, R. van Eldik and B. Krebs Eur. J. Inorg. Chem., 1537 (1999)
499)	A kinetic study of the redox behaviour of Fe^III(TPPS) in the presence of peroxomonosulfate, hydrogen peroxide, and sulfite/oxygen. Direct evidence for multiple redox cycling and suggested mechanisms V. Lepentsiotis, R. van Eldik, F.F. Prinsloo and J.J. Pienaar J. Chem. Soc., Dalton Trans., 2759 (1999)
500)	Mass spectrometric analysis of nitric oxide modified caspase-3 B. Zech, M. Wilm, R. van Eldik and B. Brüne J. Biol. Chem., 274, 20931 (1999)
501)	Water exchange reactions and hydrolysis of hydrated titanium(III) ions. A density functional theory study M. Hartmann, T. Clark and R. van Eldik J. Phys. Chem. A, 103, 9899 (1999)
502)	Kinetic and mechanistic analysis of the reactions in the aqueous system: pentacyanoferrate(II)-ammonia-nitrite I. Maciejowska, Z. Stasicka, G. Stochel and R. van Eldik J. Chem. Soc., Dalton Trans., 3643 (1999)
503)	Inorganic and bioinorganic reaction mechanisms: Application of high-pressure techniques R. van Eldik, C. Dücker-Benfer and F. Thaler Adv. Inorg. Chem., 49, 1 (1999)

2000-2004

Publications of 2000
504)	Identification of flame retardants in polymers using curie point pyrolysis-gas chromatography/mass spectrometry M. Riess, H. Thoma. O. Vierle and R. van Eldik J. Anal. Appl. Pyrolysis, 53, 135 (2000)
505)	Analysis of flame retarded polymers and recycling materials M. Riess, T. Ernst, R. Popp, B. Müller, H. Thoma, O. Vierle, M. Wolf and R. van Eldik Chemosphere, 40, 937 (2000)
506)	High pressure pulse-radiolysis as a tool in the study of transition metal reaction mechanisms R. van Eldik and D. Meyerstein Acc. Chem. Res., 33, 207 (2000)
507)	Application of a purge and trap TDS-GC/MS procedure for the determination of emissions from flame retarded polymers M. Wolf, M. Riess, D. Heitmann, M. Schreiner, H. Thoma, O. Vierle and R. van Eldik Chemosphere, 41, 693 (2000)
508)	Elucidation of inorganic reaction mechanisms. Application of high pressure I. Fundamental aspects, thermally induced reactions R. van Eldik and C.D. Hubbard Chemie in unserer Zeit, 34, 240 (2000)
509)	On the mechanism of radical C-N coupling in type B semiconductor photocatalysis. A high pressure study A. Reinheimer, R. van Eldik and H. Kisch J. Phys. Chem. B, 104, 1014 (2000)
510)	Aquacobalamin (Vitamin B_12a) does not bind NO in aqueous solution. Nitrite impurities account for observed reaction M. Wolak, G. Stochel, M. Hamza and R. van Eldik Inorg. Chem., 39, 2018 (2000)
511)	Correlation between spectroscopic, electrochemical and kinetic properties of cyano-bridged binuclear complexes. Analysis of temperature, pressure and solvent effects D.E. Khoshtariya, H.C. Bajaj, P.A. Tregloan and R. van Eldik J. Phys. Chem. A, 104, 5535 (2000)
512)	Isolation and characterization of the first stable bicarbonato complexes of bis(1,10-phenanthroline)copper(II). Identification of Lipscomb- and Lindskog-type intermediates Z.-W. Mao, G. Liehr and R. van Eldik J. Am. Chem. Soc., 122, 4839 (2000)
513)	Various contributions to "Catalysis from A to Z, a concise encyclopedia" R. van Eldik Catalysis from A to Z, B. Cornils, W.A. Herrmann, R. Schögl and C.-H. Wong (Eds), Wiley-VCH, Weinheim, 2000.
514)	Elucidation of inorganic reaction mechanisms. Application of high pressure II. Electron transfer, photo and radiation induced reactions R. van Eldik and C.D. Hubbard Chemie in unserer Zeit, 34, 306 (2000)
515)	Substitution behaviour of an alkylcobaltammine complex. Evidence for a limiting dissociative mechanism C. Dücker-Benfer, M.S.A. Hamza, C. Eckhardt and R. van Eldik Eur. J. Inorg. Chem., 1563 (2000)
516)	Quantification of heavy metals for the recycling of waste plastics from electrotechnical applications T. Ernst, R. Popp and R. van Eldik Talanta, 53, 347 (2000)
517)	Ligand substitution behaviour of a simple model for coenzyme B₁₂ M.S.A. Hamza, C. Dücker-Benfer and R. van Eldik Inorg. Chem., 39, 3777 (2000)
518)	A new cylindrical, six-membered iron(III) cluster consisting of three oxo-bridged diiron subunits linked by carboxylate bridges T. Schneppensieper, G. Liehr, R. van Eldik, J. Ensling and P. Gütlich Inorg. Chem., 39, 5565 (2000)
519)	Effects of trifluoromethyl substituents in a tris(pyrazolyl)borate ligand: A structural and spectroscopic study of analogous Pt(IV) trimethyl complexes U. Fekl, R. van Eldik, S. Lovell and K.I. Goldberg Organometallics, 19, 3535 (2000)
520)	Kinetics and mechanism of the carbonate ion inhibited aqueous ozone decomposition A. Nemes, I. Fabian and R. van Eldik J. Phys. Chem. A, 104, 7995 (2000)
521)	Mechanistic differences between "reductive" and "oxidative" heterolysis of metal-carbon -bonds N. Shaham, H. Cohen, R. van Eldik and D. Meyerstein J. Chem. Soc., Dalton Trans., 3356 (2000)
522)	Evidence for adduct formation between ONOO- and CO₂ from high pressure pulse radiolysis S. Goldstein, D. Meyerstein, R. van Eldik and G. Czapski J. Phys. Chem. A, 104, 9712 (2000)
523)	Fog, spot, fanfare - how students can still learn chemistry A. Kerk, C. Dücker-Benfer, T. Schneppensieper, B. Müller, M. Galle, R. van Eldik, C. Felser, F. Renz, W. Tremel, R. Zimehl and M. DrieÃŸ Nachr. Chem., 48, 1481 (2000)
524)	Elucidation of inorganic reaction mechanisms. Application of high pressure R. van Eldik and C.D. Hubbard SA Journal of Chemistry, 53, 139-168 (2000)
525)	Ionic and hydrogen bonding dynamics coupled to optical and thermal electron transfer. Temperature, pressure and viscosity effects D.E. Khoshtariya, T.D. Dolidze, A. Neubrand and R. van Eldik J. Mol. Liq., 89, 127 (2000)
Publications of 2001
526)	Thermodynamic and kinetic studies on complex-formation reactions of a cobalt(II) tripodal tetraamine complex Z.-L. Lu, M.S.A. Hamza and R. van Eldik Eur. J. Inorg. Chem., 503 (2001)
527)	Tuning the reversible binding of NO to iron(II) aminocarboxylate and related complexes in aqueous solution T. Schneppensieper, S. Finkler, A. Czap, R. van Eldik, M. Heus, P. Nieuwenhuizen, C. Wreesmann and W. Abma Eur. J. Inorg. Chem., 491 (2001)
528)	Mechanistic studies on the reversible binding of nitric oxide to metmyoglobin L.E. Laverman, A. Wanat, J. Oszajca, G. Stochel, P.C. Ford and R. van Eldik J. Am. Chem. Soc., 123, 285 (2001)
529)	Kinetics and mechanism of water substitution in half-sandwich iridium(III) aqua cations Cp^Ir(A-B)(H₂O)^2+/+ in aqueous solution (Cp^ = ⁵-pentamethylcyclopentadienyl anion; A-B = bidentate N,N or N,O ligand) T. Poth, H. Paulus, H. Elias, C. Dücker-Benfer and R. van Eldik Eur. J. Inorg. Chem., 1361 (2001)
530)	Thermodynamic and kinetic studies on the reaction between the vitamin B₁₂ derivative (N-methylimidazole)cobalamin and N-methylimidazole: Ligand displacement at the axial site of cobalamins by an imidazole type ligand A.G. Cregan, N.E. Brasch and R. van Eldik Inorg. Chem., 40, 1438 (2001)
531)	Mechanistic studies on the metal catalyzed autoxidation of sulfur(IV) oxides R. van Eldik Dynamics and Chemistry of Hydrometeors, R. Jaenicke (Ed.), Wiley-VCH, Weinheim, 387 (2001)
532)	A bowl-shaped and highly inert bis-(m-hydroxo)-platinum(II) dimer U. Fekl, R. van Eldik, C. Richardson and W.T. Robinson Inorg. Chem., 40, 3247 (2001)
533)	Controlling the lability of square planar Pt(II) complexes through electronic communication between -acceptor ligands D. Jaganyi, A. Hofmann and R. van Eldik Angew. Chem. Int. Ed., 40, 1680 (2001)
534)	Water exchange controls the complex-formation mechanism of water-soluble iron(III) porphyrins. Conclusive evidence for dissociative water exchange from a high pressure ¹⁷O NMR study T. Schneppensieper, A. Zahl and R. van Eldik Angew. Chem. Int. Ed., 40, 1678 (2001)
535)	Electrostriction and counter ion effects in an outer-sphere electron transfer reaction. Kinetics of the reduction of hexachloroiridate(IV) by iodide ion C.D. Hubbard, A. Gerhard and R. van Eldik J. Chem. Soc., Dalton Trans., 1069 (2001)
536)	Structural and mechanistic information on the reaction of bicarbonate with Cu(II) and Zn(II) complexes of tris(2-aminoethyl)amine. Identification of intermediate and product species Z.-W. Mao, G. Liehr and R. van Eldik J. Chem. Soc., Dalton Trans., 1593 (2001)
537)	A high pressure pulse-radiolysis study of the formation and decomposition of complexes with iron-carbon s bonds. A mechanistic comparison for different metal centers S. Goldstein, G. Czapski, R. van Eldik, N. Shaham, H. Cohen and D. Meyerstein Inorg. Chem., 40, 4966 (2001)
538)	Influence of chelate effects on the water exchange mechanism of polyaminecarboxylate complexes of iron(III) T. Schneppensieper, S. Seibig, A. Zahl, P. Tregloan and R. van Eldik Inorg. Chem., 40, 3670 (2001)
539)	Ligand effects on the kinetics of the reversible binding of NO to selected iron(II) aminocarboxylate complexes in aqueous solution T. Schneppensieper, A. Wanat, G. Stochel, S. Goldstein, D. Meyerstein and R. van Eldik Eur. J. Inorg. Chem., 2317 (2001)
540)	Mechanistic study of the electron transfer reaction between cytochrome c and trisoxalatocobalt(III) J. Macyk and R. van Eldik J. Chem. Soc., Dalton Trans., 2288 (2001)
541)	Kinetics and mechanism of the reversible binding of nitric oxide to reduced cobalamin B_12r M. Wolak, A. Zahl, T. Schneppensieper, G. Stochel and R. van Eldik J. Am. Chem. Soc., 123, 9780 (2001)
542)	Equilibrium and kinetic studies on the reactions of alkylcobalamins with cyanide M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik Inorg. Chem., 40, 5440 (2001)
543)	Complex-formation reactions of Cu(II) and Zn(II) 2,2'-bipyridine and 1,10-phenanthroline complexes with bicarbonate. Identification of different carbonate coordination modes Z.-W. Mao, F.W. Heinemann, G. Liehr and R. van Eldik J. Chem. Soc., Dalton Trans., 3652 (2001)
Publications of 2002
544)	Nitrite binding to metmyoglobin and methemoglobin in comparison to nitric oxide binding A. Wanat, J. Gdula-Argasinska, D. Rutkowska-Zbik, M. Witko, G. Stochel and R. van Eldik J. Biol. Inorg. Chem., 7, 165 (2002)
545)	Five-coordination and adduct formation in Co(III) corrinoids: Dissecting ligand substitution into its component parts M.S.A. Hamza, R. van Eldik, P.L.S. Harper, J.M. Pratt and E.A. Betterton Eur. J. Inorg. Chem., 580 (2002)
546)	Kinetics, mechanism and spectroscopy of the reversible binding of nitric oxide to aquated iron(II). An undergraduate text book reaction revisited A. Wanat, T. Schneppensieper, G. Stochel, R. van Eldik, E. Bill and K. Wieghardt Inorg. Chem., 41, 4 (2002) This manuscript is featured on the cover of the January 14, 2002 issue of Inorganic Chemistry!
547)	¹³⁹La NMR kinetic study of lanthanum(III) complexation with acetohydroxamic acid M. Birus, R. van Eldik, M. Gabricevic and A. Zahl Eur. J. Inorg. Chem., 819 (2002)
548)	Kinetics and mechanism of the reaction of chelated Pd(II) complexes with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pd(bpma)Cl]Cl^.H₂O (bmpa = bis(2-pyridylmethyl)amine) Z.D. Bugarcic, G. Liehr and R. van Eldik J. Chem. Soc., Dalton Trans., 951 (2002)
549)	Die Zaubervorlesung: "Chemie am laufenden Band" B. Müller, M. Galle, T. Schneppensieper, C. Dücker-Benfer and R. van Eldik Chemie in unserer Zeit, 36, 246 (2002)
550)	High Pressure Chemistry: Synthetic, Mechanistic and Supercritical Applications R. van Eldik and F.-G. Klärner (Eds.) VCH-Wiley, Weinheim, Germany, 2002.
551)	The substitution mechanism of [Ru^III(edta)(H₂O)]^- with DNA bases, nucleosides and nucleotides in aqueous solution revisited D. Chatterjee, A. Mitra, M.S.A. Hamza and R. van Eldik J. Chem. Soc., Dalton Trans., 962 (2002)
552)	Phantom activation volumes" are indeed real activation volumes C.F. Weber and R. van Eldik J. Phys. Chem. A, 106, 6904 (2002)
553)	Effect of pressure on inorganic reactions. Introduction and mechanistic applications R. van Eldik and C.D. Hubbard in "High Pressure Chemistry: Synthetic, Mechanistic and Supercritical Applications", R. van Eldik and F.-G. Klärner (Eds.), VCH-Wiley, Weinheim, Germany, 2002, p. 3-40.
554)	Effect of pressure on electron transfer reactions in inorganic and bioinorganic chemistry J. Macyk and R. van Eldik in "Frontiers in High Pressure Biochemistry and Biophysics", Biochim. Biophys. Acta, 1595, 283 (2002)
555)	Equilibrium, kinetic and leaving group effect studies on ligand substitution reactions of a simple model for coenzyme B₁₂ B.M. Alzoubi, M.S.A. Hamza, C. Dücker-Benfer and R. van Eldik Eur. J. Inorg. Chem., 968 (2002)
556)	Cation-independent electron transfer between ferricyanide and ferrocyanide ions in aqueous solution A. Zahl, R. van Eldik and T.W. Swaddle Inorg. Chem., 41, 757 (2002)
557)	Mechanism of water exchange on five-coordinate copper(II) complexes A. Neubrand, F. Thaler, M. Körner, A. Zahl, C.D. Hubbard and R. van Eldik J. Chem. Soc., Dalton Trans., 957 (2002)
558)	To be or not to be NO in coordination chemistry? A mechanistic approach M. Wolak and R. van Eldik Coord. Chem. Rev., 230, 263 (2002)
559)	Thermodynamics and kinetics of Ru^III(edta) as efficient scavenger for nitric oxide in aqueous solution A. Wanat, T. Schneppensieper, A. Karocki, G. Stochel and R. van Eldik J. Chem. Soc., Dalton Trans., 941 (2002)
560)	Ligand effects on the reactivity of Cu(I)L complexes toward Cl₃CCO₂^- N. Navon, A. Burg, H. Cohen, R. van Eldik and D. Meyerstein Eur. J. Inorg. Chem., 423 (2002)
561)	Liquid water (D₂O): A dynamic model emerging from near-infrared DO-D stretching overtone studies D.E. Koshtariya, T.D. Dolidze, P. Lindquist-Reis, A. Neubrand and R. van Eldik J. Mol. Liq., 96/97, 45 (2002)
562)	Mechanistic information from pressure acceleration of hydride formation via proton binding to a cobalt(I) macrocycle E. Fujita, J.F. Wishart and R. van Eldik Inorg. Chem., 41, 1579 (2002)
563)	Laser flash photolysis as tool in the elucidation of the nitric oxide binding mechanism to metallobiomolecules A. Wanat, M. Wolak, L. Orzel, M. Brindell, R. van Eldik and G. Stochel Coord. Chem. Rev., 229, 37 (2002)
564)	Mechanistic information on the reversible binding of NO to selected iron(II) chelates from activation parameters T. Schneppensieper, A. Wanat, G. Stochel and R. van Eldik Inorg. Chem., 41, 2565 (2002)
565)	Solvation largely accounts for the effect of N-alkylation on the properties of nickel(II/I) and chromium(III/II) cyclam complexes T. Clark, M. Hennemann, R. van Eldik and D. Meyerstein Inorg. Chem., 41, 2927 (2002)
566)	Activation volume measurement for C-H activation. Evidence for associative benzene substitution at a platinum(II) center J. Procelewska, A. Zahl, R van Eldik, H.A. Zhong, J.A. Labinger and J.E. Bercaw Inorg. Chem., 41, 2808 (2002)
567)	Sovatochromism and piezochromism of dicyano-, tricyano-, and tetracyano-diimine-iron(II) complexes A. Alousy, N.J. Blundell, J. Burgess, C.D. Hubbard and R. van Eldik Transition Met. Chem., 27, 244 (2002)
568)	Kinetics and mechanism of the reactions of [Pt(terpy)H₂O]²⁺ with thiols in acidic aqueous solution. Synthesis and crystal structure of [Pt(terpy)(tu)](ClO₄)₂ (tu = thiourea) Z. Bugarcic, G. Liehr and R. van Eldik J. Chem. Soc., Dalton Trans., 2825 (2002)
569)	Mechanistic insight from a volume profile for electron transfer between promazine and hexaaquairon(III) J. Wisniewska and R. van Eldik Inorg. Chem., 41, 3802 (2002)
570)	A detailed mechanistic study of the behaviour of an unusual seven-coordinate iron(III) complex in aqueous solution I. Ivanovic-Burmazovic, M.S.A. Hamza and R. van Eldik Inorg. Chem., 41, 5150 (2002)
571)	Kinetics and mechanism of the formation of nitroprusside from aquapentacyanoferrate(III) and NO. Complex-formation is controlled by outer-sphere electron transfer F. Roncaroli, J.A. Olabe and R. van Eldik Inorg. Chem., 41, 5417 (2002)
572)	Equilibrium and kinetic data for the interaction of diaqua-(S-methyl-L-cysteine)palladium(II) with biologically relevant ligands Z.D. Bugarcic, M.M. Shoukry and R. van Eldik J. Chem. Soc., Dalton Trans., 3945 (2002)
573)	Detailed kinetic and thermodynamic studies on the cyanation of alkylcobalamins. A generalized mechanistic description M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik J. Chem. Soc., Dalton Trans., 3832 (2002)
574)	Substitution behaviour of an unusual seven-coordinate iron(III) complex in different solvents I. Ivanovic-Burmazovic, M.S.A. Hamza and R. van Eldik Inorg. Chem. Commun., 5, 937 (2002)
575)	Reactions of methyl viologen and nitrite with thiourea dioxide. New opportunities for an old reductant. S.V. Makarov, E.V. Kudrik, R. van Eldik and E.V. Naidenko J. Chem. Soc., Dalton Trans., 4074 (2002)
576)	Photochemistry of concentrated sulfuric acid in the presence of SO₂ and Fe(II), and implications for the cloud chemistry of Venus G.A. Rowland, R. van Eldik and L.F. Phillips J. Photochem. Photobiol. A, 153, 1 (2002)
577)	Haemoglobins with multiple reactive sulfhydryl groups: reactions of 5,5’-dithiobis(2-nitrobenzoate) with CysF9[93] and CysH3[125] of guinea pig haemoglobin J.O. Babelola, L.U. Uko, K.O. Okonjo and R. van Eldik Bull. Chem. Soc. Ethiopia, 16, 175 (2002)

Publications of 2003
578)	Analysis of eco-relevant elements and noble metals in printed wiring boards using AAS, ICP-AES and EDXRF T. Ernst, R. Popp, M. Wolf and R. van Eldik Anal. Bioanal. Chem., 375, 805 (2003)
579)	Thermodynamic and kinetic data for the base-on/base-off equilibration of alkylcobalamins M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik Eur. J. Inorg. Chem., 268 (2003)
580)	Molecular orbital and DFT studies on water exchange mechanisms of metal ions H. Erras-Hanauer, T. Clark and R. van Eldik Coord. Chem. Rev., 238-239, 233 (2003)
581)	Structures of carbonato and bicarbonato complexes of bis(1,10-phenanthroline)-zinc(II): experiment and theory H. Erras-Hanauer, Z.-W. Mao, G. Liehr, T. Clark and R. van Eldik Eur. J. Inorg. Chem., 1562 (2003)
582)	Kinetics and mechanism of the cobalt phthalocyanine catalyzed reduction of nitrite and nitrate by dithionite in aqueous solution E.V. Kudrik, S.V. Makarov, A. Zahl and R. van Eldik Inorg. Chem., 42, 618 (2003)
583)	Mechanistic studies on the interaction of reduced cobalamin (vitamin B_12r) with nitroprusside M. Wolak, G. Stochel and R. van Eldik J. Am. Chem. Soc., 125, 1334 (2003)
584)	Interaction of [Ru^III(edta)H₂O]^- with amino acids in aqueous solution. Equilibrium, kinetic and protease inhibition studies D. Chatterjee, M.S.A. Hamza, M.M. Shoukry, A. Mitra, S. Deshmukh and R. van Eldik Dalton Trans., 203 (2003)
585)	Electronic tuning of the lability of Pt(II) complexes through -acceptor effects. Correlations between thermodynamic, kinetic and theoretical parameters A. Hofmann, D. Jaganyi, O.Q. Munro, G. Liehr and R. van Eldik Inorg. Chem., 42, 1688 (2003)
586)	The reaction between methylcobalamin and cyanide revisited S.J. Brodie, A.G. Cregan, R. van Eldik and N.E. Brasch Inorg. Chim. Acta, 348, 221 (2003)
587)	The unusually fast reaction between ruthenium(III)-ammine complexes and NO revisited A. Czap and R. van Eldik Dalton Trans., 665 (2003)
588)	Mechanistic insight from activation parameters for the reaction between coenzyme B₁₂ and cyanide: Further evidence that heterolytic Co-C bond cleavage is solvent-assisted. M.S.A. Hamza, A.G. Cregan, N.E. Brasch and R. van Eldik Dalton Trans., 596 (2003)
589)	Complex-formation reactions and stability constants for mixed-ligand complexes of diaqua(2-picolylamine)palladium(II) with some bio-relevant ligands A.A. El-Sherif, M.M. Shoukry and R. van Eldik Dalton Trans., 1425 (2003)
590)	Outer-sphere electron-transfer between horse heart cytochrome c and anionic Cu(II/I) complexes. Evidence for precursor formation and coordination sphere reorganization for electron transfer M. Koerner, P.A. Tregloan and R. van Eldik Dalton Trans., 2710 (2003) This manuscript is featured on the inside cover of the July 7, 2003 issue of Dalton Transactions!
591)	Self-exchange reactions of metallocenes revisited: Insights from the decamethylferricinium-decamethylferrocene reaction at variable pressure A. Zahl, R. van Eldik, M. Matsumoro and T.W. Swaddle Inorg. Chem., 42, 3718 (2003) This manuscript is featured on the cover of the June 16, 2003 issue of Inorganic Chemistry!
592)	Mechanistic insight gained into the ligand substitution reactions of (triphenylphosphine)bis(o-benzosemiquinonediiminato)cobalt(III). Kinetic, solvent and volume profile studies B.M. Alzoubi, M.S.A. Hamza, C. Dücker-Benfer and R. van Eldik Eur. J. Inorg. Chem., 2972 (2003)
593)	Kinetics of the reduction of cytochrome c by [Fe^II(edta)H₂O]^2-. Outer-sphere versus inner-sphere electron transfer mechanisms J. Macyk and R. van Eldik Dalton Trans., 2704 (2003)
594)	Kinetics and mechanism of the interaction of nitric oxide with pentacyanoferrate(II). Formation and dissociation of [Fe(CN)₅NO]^3- F. Roncaroli, J.A. Olabe and R. van Eldik Inorg. Chem., 42, 4179 (2003)
595)	A compact high pressure unit for UV-VIS-NIR spectroscopic measurements at pressures up to 400 MPa A. Zahl, P. Igel, M. Weller, D. Koshtariya, M.S.A. Hamza and R. van Eldik Rev. Sci. Instrum., 74, 3758 (2003)
596)	Electrostatic complexation and photo-induced electron transfer between Zn-cytochrome c and polyanionic fullerene dendrimers M. Braun, S. Atalick, D.M. Guldi, H. Lanig, M. Brettreich, S. Burghardt, M. Hatzimarinaki, E. Ravanelli, M. Prato, R. van Eldik and A. Hirsch Chem. Eur. J., 9, 3867 (2003)
597)	Coenzyme B₁₂ model studies. Kinetics of axial ligation of alkyl cobalt complexes containing a tridentate amino-oximate ligand B.M. Alzoubi, M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik Eur. J. Inorg. Chem., 3738 (2003)
598)	Positive activation volume for a cytochrome c electrode process: Evidence for a “protein friction” mechanism from high pressure studies T.D. Dolidze, D.E. Khoshtariya, D.H. Waldeck, J. Macyk and R. van Eldik J. Phys. Chem. B, 107, 7172 (2003)
599)	Kinetic and thermodynamic studies on the cyanation reactions and base-on/base-off equilibria of alkyl-13-epicobalamins M.S.A. Hamza, X. Zou, K.L. Brown and R. van Eldik Dalton Trans., 2986 (2003)
600)	Advances in Inorganic Chemistry, Vol. 54: Inorganic Reaction Mechanisms R. van Eldik and C.D. Hubbard (Eds) Academic Press, San Diego, 477 pp, 2003
601)	Thermodynamic and kinetic study of the interaction between the Pt(II) centres in [Pt₂(N,N,N’,N’-tetrakis(2-pyridylmethyl)diamine)(H₂O)₂]⁴⁺. Influence of the bridging ligand A. Hofmann and R. van Eldik Dalton Transactions, 2979 (2003)
602)	Magic Show 2003 W. SchieÃŸl, A. Hofmann, C. Dücker-Benfer, N. Summa, M. Galle and R. van Eldik GIT Labor Fachz., 616 (2003)
603)	Extraction of brominated flame retardants from polymeric waste material using different solvents and supercritical carbon dioxide A. mnim Altwaiq, M. Wolf and R. van Eldik Anal. Chim. Acta, 491, 111 (2003)
604)	Cyclometallated analogues of platinum terpyridine complexes: Kinetic study of the strong -donor cis and trans effects of carbon in the presence of a -acceptor ligand backbone A. Hofmann, L. Dahlenburg and R. van Eldik Inorg. Chem., 42, 6528 (2003)
605)	Evaluation of activation volumes for the conversion of peroxynitrous to nitric acid R. Kissner, C. Thomas, M.S.A. Hamza, R. van Eldik and W.H. Koppenol J. Phys. Chem. A, 107, 11261 (2003)
Publications of 2004
606)	Highly localized charges control electrostriction. Reaction volumes for the reduction of mononuclear and bridged Ru complexes H.C. Bajaj, P.A. Tregloan and R. van Eldik Inorg. Chem., 43, 1429 (2004)
607)	Mechanistic information on the copper-catalysed autoxidation of mercaptosuccinic acid in aqueous solution M. Pawelec, G. Stochel and R. van Eldik Dalton Trans., 292 (2004)
608)	The profound influence of a single metal-carbon bond on the reactivity of bio-relevant cobalt(III) complexes M.S.A. Hamza and R. van Eldik Dalton Trans., 1 (2004) This manuscript is featured on the cover of the January 7, 2004 issue of Dalton Transactions!
609)	Substitution reactions of [Pt(terpy)X]²⁺ with some biologically relevant ligands. Synthesis and crystal structures of [Pt(terpy)(cyst-S)](ClO₄)₂^.0.5 H₂O and [Pt(terpy)(guo-N⁷)](ClO₄)₂^.0.5 guo^.1.5 H₂O Z.D. Bugarcic, F.W. Heinemann and R. van Eldik Dalton Trans., 279 (2004)
610)	Mechanistic studies on a facile ring-flipping process in planar-chiral ferrocenes under ambient and high pressure and its relevance to symmetric catalysis O.J. Curnow, G.M. Fern, M.L. Hamilton, A. Zahl and R. van Eldik Organometallics, 23, 429 (2004)
611)	Electronically and sterically tuned trans labilization controls the substitution behaviour of cobaloximes M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik Dalton Trans., 287 (2004)
612)	Role of chelate substituents and cis -effects on the rate of ligand substitution at Pt(N-N-N) and Pt(N-N-C) centres D. Jaganyi, D. Reddy, J.A. Gertenbach, A. Hofmann and R. van Eldik Dalton Trans., 299 (2004)
613)	Kinetics and mechanism of water substitution in the low spin Fe(II) complex of 4-octasulfophenylpyrazinoporphyrazine E.V. Kudrik, R. van Eldik and S.V. Makarov Dalton Trans., 429 (2004)
614)	Kinetics and mechanism of axial ligand substitution of alkyl cobaloximes by substituted pyridines in different solvents B.M. Alzoubi, M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik Eur. J. Inorg. Chem., 653 (2004) This manuscript is featured on the cover of the February 6, 2004 issue of Eur. J. Inorg. Chem. !
615)	NO Binding to cobalamin: Influence of the metal oxidation state C. SelÃ§uki, R. van Eldik and T. Clark Inorg. Chem., 43, 2828 (2004)
616)	Effect of inhibitors on the catalyzed dehydration of HCO₃^- by copper(II) complexes re-evaluated R. van Eldik Inorg. Chem., 43, 2756 (2004)
617)	Substrate binding favours enhanced NO binding to P450_cam A. Franke, G. Stochel, C. Jung and R. van Eldik J. Am. Chem. Soc., 126, 4181 (2004)
618)	Advances in Inorganic Chemistry, Vol. 55 R. van Eldik (Ed) Elsevier Academic Press, San Diego, 447 pp, 2004
619)	Structure and characterization of non-cyclic tetraaza complexes of copper(II) and their reactions with nitric oxide C.-H. Kwak, J.-E. Jee, M. Pyo, J. Kim and R. van Eldik Inorg. Chim. Acta, 357, 2643 (2004)
620)	Further mechanistic information on the reaction between Fe^III(edta) and hydrogen peroxide. Observation of a second reaction step and importance of pH A. Brausam and R. van Eldik Inorg. Chem., 43, 5351 (2004)
621)	A new high-pressure NMR probe designed for a narrow bore magnet system A. Zahl, P. Igel, M. Weller and R. van Eldik Rev. Sci. Instrum., 75, 3152 (2004)
622)	Mechanistic elucidation of the substitution behavior of alkyl cobaloximes in water and methanol as solvents B.M. Alzoubi, G. Liehr and R. van Eldik Inorg. Chem., 43, 6093 (2004)
623)	Local dense structural heterogeneities in liquid water from ambient to 300 MPa pressure: Evidence for multiple liquid-liquid transitions D.E. Khoshtariya, A. Zahl, T.D. Dolidze, A. Neubrand and R. van Eldik ChemPhysChem, 5, 1398 (2004)
624)	The role of positively charged meso-substituents on the kinetics of the reductive nitrosylation of iron(III)-porphyrins. The catalytic role of nitrite A. Theodoridis and R. van Eldik J. Mol. Cat. A, 224, 197 (2004)
625)	Advances in Inorganic Chemistry, Vol. 56: Redox-active metal complexes R. van Eldik (Ed) Elsevier Academic Press, San Diego, 273 pp, 2004
626)	Discrimination of diverse (pressure/temperature-dependent/independent) inherent sub-structures in liquid water (D₂O) from difference vibrational spectroscopy D.E. Khoshtariya, A. Zahl, T.D. Dolidze, A. Neubrand and R. van Eldik J. Phys. Chem. B, 108, 14796 (2004)
627)	Comparison of thermodesorption and soxhlet extraction for GC/MS analysis of plastic additives M. Pöhlein, B. Müller, M. Wolf and R. van Eldik GIT Labor-Fachzeitschrift, 754 (2004)
628)	The influence of terpyridine as -acceptor ligand on the kinetics and mechanism of the reaction of NO with ruthenium(III) complexes A. Czap, F.W. Heinemann and R. van Eldik Inorg. Chem., 43, 7832 (2004)
629)	Kinetic and mechanistic study on the reaction of alkylcobaloximes with azoles M.S.A. Hamza, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik Dalton Trans., 3835 (2004)
630)	Evidence for associative ligand exchange processes on solvated lithium cations R. Puchta, M. Galle, N. van Eikema Hommes, E. Pasgreta and R. van Eldik Inorg. Chem., 43, 8227 (2004)

2005-2009

Publications of 2005
631)	Application of high pressure in inorganic and bioinorganic chemistry R. van Eldik and C.D. Hubbard in “Chemistry at Extreme Conditions”, M. Riad Manaa (Ed.), Elsevier, Amsterdam, p. 109-164, 2005
632)	Analysis of flame retardant additives in polymer fractions of waste of electric and electronic equipment (WEEE) by means of HPLC-UV/MS and GPC-HPLC-UV M. Schlummer, F. Brandl, A. Mäurer and R. van Eldik J. Chrom. A, 1064,39-51 (2005)
633)	Kinetic and thermodynamic studies on ligand substitution reactions and base-on/base-off equilibria of cyanoimidazolylcobamide, a vitamin B₁₂ analog with an imidazole axial nucleoside M.S.A. Hamza, X. Zou, R. Banka, K.L. Brown and R. van Eldik Dalton Trans., 782-787 (2005)
634)	The kinetics of the silver(I)-induced oxidation of chromium(III) by peroxodisulphate A.M. Bogopane, J.J. Pienaar, G. Lachmann, M.S.A. Hamza and R. van Eldik S. Afr. J. Chem., 58, 30-36 (2005)
635)	The release of NO from reduced nitroprusside ion. Iron-dinitrosyl formation and NO-disproportionation reactions F. Roncaroli, R. van Eldik and J.A. Olabe Inorg. Chem., 44, 2781-2790 (2005)
636)	Reduction pathway of end-on terminally coordinated dinitrogen. V. N-N bond cleavage in Mo/W hydrazidium complexes with diphosphine coligands. Comparison with triamidoamine systems K. Meersmann, K.H. Horn, N. Böres, N. Lehnert, F. Studt, F. Paulat, G. Peters, I. Ivanovic-Burmazovic, R. van Eldik and F. Tuczek Inorg. Chem., 44, 3031-3045 (2005)
637)	High pressure chemistry: principles, technology, and applications to liquid systems C.D. Hubbard and R. van Eldik Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley, 2005
638)	Rapid identification of RoHS-relevant flame retardants from polymer housings by ultrasonic extraction and RP-HPLC/UV M. Pöhlein, A. S. Llopis, M. Wolf and R. van Eldik J. Chrom. A, 1066, 111-117 (2005)
639)	Kinetics and mechanism of the Co(II)-assisted oxidation of thiourea by dioxygen E.V. Kudrik, A. Theodoridis, R. van Eldik and S.V. Makarov Dalton Trans., 1117-1122 (2005)
640)	Mechanistic studies on the binding of nitric oxide to a synthetic heme-thiolate complex relevant to cytochrome P450 A. Franke, G. Stochel, N. Suzuki, T. Higuchi, K. Okuzono and R. van Eldik J. Am. Chem. Soc., 127, 5360-5375 (2005)
641)	Pressure and temperature effects on metal-to-metal charge transfer in cyano-bridged Co^III-Fe^II complexes B.P. Macpherson, B.M. Alzoubi, P.V. Bernhardt, M. Martinez, P.A. Tregloan and R. van Eldik Dalton Trans., 1459-1467 (2005)
642)	Advances in Inorganic Chemistry, Vol. 57: Relaxometry of Water-Metal Ion Interactions R. van Eldik and I. Bertini (Eds) Elsevier Academic Press, San Diego, 485 pp, 2005
643)	Mechanistic studies on the formation of Pt(II) hydroformylation catalysts in imidazolium-based ionic liquids P. Illner, A. Zahl, R. Puchta, N. van Eikema Hommes, P. Wasserscheid and R. van Eldik J. Organomet. Chem. (Special issue on Organometallic Chemistry in Ionic Liquids), 690, 3567-3576 (2005)
644)	Evidence for interchange ligand-exchange processes on solvated beryllium cations R. Puchta, N. van Eikema Hommes and R. van Eldik Helv. Chim. Acta, 88, 911-922 (2005)
645)	Experimental and theoretical approaches to the protonation of thiourea. A convenient nucleophile in coordination chemistry revisited W.C. Schiessl, N.K. Summa, C.F. Weber, S. Gubo, C. Dücker-Benfer, R. Puchta, N.J.R. van Eikema Hommes and R. van Eldik Z. Anorg. Allg. Chemie (Special issue dedicated to the 70^th birthday of Prof. H.W. Roesky), 631, 2812-2819 (2005)
646)	Introduction to thematic issue: Inorganic and bioinorganic mechanisms R. van Eldik (Guest Editor) Chem. Rev., 105, 1917-1921 (2005)
647)	Transition-state effects of ionic liquids in substitution reactions of Pt(II) complexes C.F. Weber, R. Puchta, N.J.R. van Eikema-Hommes, P. Wasserscheid and R. van Eldik Angew. Chem. Int. Ed., 44, 6033-6038 (2005)
648)	Kinetics and mechanism of the phthalocyanine catalyzed reduction of nitrite by dithionite and sulfoxylate in aqueous solution E.V. Kudrik, S.V. Makarov, A. Zahl and R. van Eldik Inorg. Chem., 44, 6470-6475 (2005)
649)	Effect of pressure on proton-coupled electron transfer reactions of seven-coordinate iron complexes in aqueous solution D. Sarauli, R. Meier, G.-F. Lui, I. Ivanovic-Burmazovic and R. van Eldik Inorg. Chem., 44, 7624-7633 (2005)
650)	Mechanistic information on the reductive elimination from cationic trimethylplatinum(IV) complexes to form carbon-carbon bonds J. Procelewska, A. Zahl, G. Liehr, R. van Eldik, N.A. Smythe, B.S. Williams and K.I. Goldberg Inorg. Chem., 44, 7732-7742 (2005) This manuscript is featured on the cover of the October 31, 2005 issue of Inorganic Chemistry!
651)	pH controls the rate and mechanism of nitrosylation of water-soluble Fe(III) porphyrin complexes M. Wolak and R. van Eldik J. Am. Chem. Soc., 127, 13312-13315 (2005)
652)	Kinetic and mechanistic studies on the reaction of nitric oxide with a water-soluble octa-anionic Fe(III)-porphyrin complex J.-E. Jee, S. Eigler, F. Hampel, N. Jux, M. Wolak, A. Zahl, G. Stochel and R. van Eldik Inorg. Chem., 44, 7717-7731 (2005)
653)	Equilibrium, kinetic and solvent effect studies on the reactions of [Ru^III(Hedta)H₂O] with thiols M.M. Shoukry, M.R. Shehata, M.S.A. Hamza and R. van Eldik Dalton Trans., 3921-3926 (2005)
654)	Influence of solvent on ligand substitution reactions of Pt(II) complexes as a function of the -acceptor properties of the spectator chelate C.F. Weber and R. van Eldik Eur. J. Inorg. Chem., 4755-4761, 2005
655)	The new safety film for chemical laboratory workers Der neue Sicherheitsfilm für das Arbeiten in chemischen Laboratorien C. Dücker-Benfer, W. Schiessl, M. Galle and R. van Eldik GIT Labor-Fachzeitschrift, 964-967 (2005)
656)	Mechanism of isomerization of Ni(cyclam) in aqueous solutions E. Maimon, I. Zilbermann, H. Cohen, D. Kost, R. van Eldik and D. Meyerstein Eur. J. Inorg. Chem., 4997-5004 (2005)
Publications of 2006
657)	High-pressure probing of a changeover in the charge-transfer mechanism for intact cytochrome c at Au/SAM junctions D.E. Koshtariya, T.D. Dolidze, D. Sarauli and R. van Eldik Angew. Chem. Int. Ed., 45, 277-281 (2006)
658)	Reactivity of aquacobalamin and reduced cobalamin toward S-nitrosoglutathione and S-nitroso-N-acetylpenicillamine M. Wolak, G. Stochel and R. van Eldik Inorg. Chem.,45, 1367-1379 (2006)
659)	A comparative mechanistic study of the reversible binding of NO to a water-soluble octa-cationic Fe^III porphyrin complex J.-E. Jee, M. Wolak, D. Balbinot, N. Jux, A. Zahl and R. van Eldik Inorg. Chem, 45, 1326-1337 (2006)
660)	Transition state characterization for the reversible binding of dihydrogen to bis(2,2’-bipyridine)rhodium(I) from temperature- and pressure-dependent experimental and theoretical studies E. Fujita, B.S. Brunschwig, C. Creutz, J.T. Muckerman, N. Sutin, D. Szalda and R. van Eldik Inorg. Chem., 45, 1595-1603 (2006)
661)	Solvent-tuning of the substitution behavior of a seven-coordinate iron(III) complex I. Ivanovic-Burmazovic, M.S.A. Hamza and R. van Eldik Inorg. Chem., 45, 1575-1584 (2006)
662)	Guest exchange dynamics in an M₄L₆ tetrahedral host A.V. Davis, D. Fiedler, G. Seeber, A. Zahl, R. van Eldik and K.N. Raymond J. Am. Chem. Soc., 128, 1324-1333 (2006)
663)	Thermodynamic and kinetic studies on reactions of Pt(II) complexes with biologically relevant nucleophiles N. Summa, W. Schiessl, R. Puchta, N. van Eikema Hommes and R. van Eldik Inorg. Chem., 45, 2948-2959 (2006)
664)	Mechanistic information from low temperature rapid scan and NMR measurements on the protonation and subsequent reductive elimination reaction of a (diimine)Pt^II dimethyl complex B.J. Wik, I. Ivanovic-Burmazovic, M. Tilset and R. van Eldik Inorg. Chem., 45, 3613-3621 (2006)
665)	Mechanistic analysis of reductive nitrosylation on water-soluble cobalt(III)-porphyrins F. Roncaroli and R. van Eldik J. Am. Chem. Soc., 128, 8042-8053 (2006)
666)	Advances in Inorganic Chemistry, Vol. 58: Homogeneous Biomimetic Oxidation Catalysis R. van Eldik and J. Reedijk (Eds) Elsevier Academic Press, San Diego, 290 pp, 2006
667)	Chemistry edutaiment: Magic show with Salvador DalÃ W. Schiessl, C. Dücker-Benfer, N. Summa, A. Brausam, P. Pfeifer and R. van Eldik Chemie in unserer Zeit, 40, 184-193 (2006)
668)	Kinetics and mechanism of the reactions of Pd(II) complexes with azoles and diazines. Crystal structure of [Pd(bpma)(H₂O)](ClO₄)₂^.2 H₂O Z.D. Bugarcic, S.T. Nandibewoor, M.S.A. Hamza, F. Heinemann and R. van Eldik Dalton Trans., 2984-2990 (2006)
669)	The reaction mechanisms of zinc enzymes G. Schürer, T. Clark and R. van Eldik in “The chemistry of organozinc compounds”, Z. Rappoport and I. Marek (Eds), John Wiley & Sons, p. 1-29, 2006.
670)	Rational design of cation hosts. Prediction of cation selectivity by quantum chemical calculations M. Galle, R. Puchta, N.J.R. van Eikema Hommes and R. van Eldik Z. Phys. Chem. (Special issue dedicated to the 85th birthday of Prof. W. Jaenicke), 220, 511-523 (2006)
671)	Oxidation of hydroxyurea with oxovanadium(V) ions in acidic aqueous solution M. Gabricevic, E. Besic, M. Birus, A. Zahl and R. van Eldik J. Inorg. Biochem., 100, 1606-1613 (2006)
672)	A new enantiomerisation mechanism for tripodal penta-coordinate Zn^II(nta) complexes. Theoretical clarification of the observed ¹H-NMR spectrum R. Puchta, N. van Eikema Hommes, R. Meier and R. van Eldik Dalton Trans., 3392-3395 (2006) This manuscript is featured on the cover of the July 28, 2006 issue of Dalton Transactions!
673)	Mechanistic information from a volume profile for electron transfer between promethazine and hexaaquairon(III) J. Wisniewska and R. van Eldik Inorg. React. Mechn., 6, 1-8 (2006)
674)	Mechanistic studies on the nitrite-catalyzed reductive nitrosylation of highly charged anionic and cationic Fe^III-porphyrin complexes J.-E. Jee and R. van Eldik Inorg. Chem., 45, 6523-6534 (2006)
675)	Kinetic, thermodynamic and mechanistic patterns for free (unbound) cytochrome c at Au/SAM junctions. Impact of electronic coupling, hydrostatic pressure and stabilizing/denaturing additives D.E. Khoshtariya, T.D. Dolidze, S. Seifert, D. Sarauli, G. Lee and R. van Eldik Chem. Eur. J., 12, 7041-7056 (2006) This manuscript is featured on the cover of the September 18, 2006 issue of Chem. Eur. J.!
676)	Quantum chemical analysis of the enantiomerisation mechanism of complexes of the type [M^II(XU)₄]F⁺ (M = Pt, Pd, Ni; X = S, Se, Te; U = urea) R. Puchta, R. Meier, N.J.R. van Eikema Hommes and R. van Eldik Eur. J. Inorg. Chem., 4063-4067 (2006)
677)	Nitrite impurities are responsible for the reaction observed between vitamin B₁₂ and nitric oxide in acidic aqueous solution F. Roncaroli, T.E. Shubina, T. Clark and R. van Eldik Inorg. Chem., 45, 7869-7876 (2006)
678)	The interpretation and mechanistic significance of activation volumes for organometallic reactions R. van Eldik and C.D. Hubbard Adv. Phys. Org. Chem., 41, 1-78 (2006)
679)	Thermodynamic and kinetic studies on the binding of nitric oxide to a new enzymatic mimic of cytochrome P450 A. Franke, N. Hessenauer-Ilicheva, D. Meyer, G. Stochel, W.-D. Woggon and R. van Eldik J. Am. Chem. Soc., 128, 13611-13624 (2006)
680)	Kinetics and mechanism of the reaction of [Ru^III(edta)(H₂O)]^- with HOBr to form an intermediate Ru^V=O complex in aqueous solution D. Chatterjee, A. Mitra and R. van Eldik Dalton Trans., 4691-4695 (2006)
681)	Structure of sodium bis(N-methyl-iminodiacetato)iron(III). Trans-meridional N-coordination in the solid state and in solution R. Meier, M. Moliner, C. Anson, A.K. Powell; B. Kallies and R.van Eldik Dalton Trans., 5506-5514 (2006)
682)	Direct measurements of rate constants and activation volumes for the binding of H₂, D₂, N₂, C₂H₄ and CH₃CN to W(CO)₃(PCy₃)₂. Theoretical and experimental studies with time-resolved step-scan FTIR and UV-Vis spectroscopy D.C. Grills, R. van Eldik, J.T. Muckerman and E. Fujita J. Am. Chem. Soc., 128, 15728-15741 (2006)
Publications of 2007
683)	Advances in Inorganic Chemistry, Vol. 59: Template Effects and Molecular Organization R. van Eldik and K. Bowman-James (Eds) Elsevier Academic Press, San Diego, 320 pp, 2007
684)	Experimental methods and techniques: Kinetics studies R. van Eldik and C.D. Hubbard Comprehensive Organometallic Chemistry III, R.H. Crabtree and D.M.P. Mingos (Eds.), Volume 1, 509-540 (2007)
685)	Ligand exchange processes on solvated lithium cations. II. Complexation by cryptands in -butyrolactone as solvent E. Pasgreta, R. Puchta, M. Galle, N. van Eikema Hommes, A. Zahl and R. van Eldik J. Incl. Phen. Macr. Chem., 58, 81-88 (2007)
686)	Chemistry edutaiment put to the test. Evaluation of the “chemistry magic show with Salvador DalÃ” W. Schiessl, P. Pfeifer and R. van Eldik CHEMKON, 14, 84-89 (2007)
687)	Characterization of polymer fractions from waste electric and electronic equipment (WEEE) and implications for waste management M. Schlummer, L. Gruber, A. Müller, G. Wolz and R. van Eldik Chemosphere, 67, 1866-1876 (2007)
688)	Mechanistic studies on peroxide activation by a water-soluble iron(III) porphyrin. Implications for O-O bond activation in aqueous and non-aqueous solvents M. Wolak and R. van Eldik Chem. Eur. J., 13, 4873-4883 (2007)
689)	Searching for stable five-coordinate, aquated Al(III) species. Water exchange mechanism and effect of pH H. Hanauer, R. Puchta, T. Clark and R. van Eldik Inorg. Chem., 46, 1112-1122 (2007)
690)	Electronic tuning of the lability of inert Co(III) and Pt(II) complexes R. van Eldik Adv. Inorg. Chem., 59, 265-310 (2007)
691)	Host-guest complexes of oligo pyridine cryptands. Prediction of ion selectivity by quantum chemical calculations II R. Puchta and R. van Eldik Eur. J. Inorg. Chem., 1120-1127 (2007)
692)	Mechanistic studies of reactions of coordination compounds. Some recent highlights C.D. Hubbard and R. van Eldik Invited review in J. Coord. Chem., 60, 1-51 (2007) This manuscript is featured on the cover of the January 10, 2007 issue of J. Coord. Chem.!
693)	The impact of different chelating leaving groups on the substitution kinetics of mononuclear Pt^II(dach)(X-Y) complexes N. Summa, T. Soldatovic, L. Dahlenburg, Z.D. Bugarcic and R. van Eldik J. Biol. Inorg. Chem., 12, 461-475 (2007)
694)	Mechanistic studies on the activation of NO by iron and cobalt complexes A. Franke, F. Roncaroli and R. van Eldik Microreview in Eur. J. Inorg. Chem., 773-798 (2007) This manuscript is featured on the cover of the 6th issue of Eur. J. Inorg. Chem.!
695)	Systematic counter-ion tuning of the solid state structure of [Pt(thiourea)₄]²⁺ W. Schiessl, R. Puchta, Z.D. Bugarcic, F.W. Heinemann and R. van Eldik Eur. J. Inorg. Chem., 1390-1404 (2007)
696)	Post-combustion syntheses of PCDD/F and PBDD/F from halogen-rich fuel is suppressed by a pebble heater technology M. Schlummer, M. Faulstich, W. Fischer, P. Quicker, A. Mäurer and R. van Eldik Env. Sci. Pollut. Res., 14, 414-420 (2007)
697)	Reaction of [Ru^III(edta)(H₂O)]^- with H₂O₂ in aqueous solution. Kinetic and mechanistic investigation D. Chatterjee, A. Mitra and R. van Eldik Dalton Trans., 943-948 (2007)
698)	Possible biotransformation reactions of polynuclear Pt(II) complexes N. Summa, J. Maigut, R. Puchta and R. van Eldik Inorg. Chem., 46, 2094-2104 (2007)
699)	Influence of an extremely negatively charged porphyrin on the reversible binding kinetics of NO to Fe(III) and the subsequent reductive nitrosylation J.-E. Jee, S. Eigler, N. Jux, A. Zahl and R. van Eldik Inorg. Chem., 46, 3336-3352 (2007)
700)	Fascinating inorganic/bioinorganic reaction mechanisms R. van Eldik Coord. Chem. Rev., 251, 1649-1662 (2007)
701)	Ligand exchange processes on solvated lithium cations. III. DMSO and water/DMSO mixtures E. Pasgreta, R. Puchta, M. Galle, N. van Eikema Hommes, A. Zahl and R. van Eldik ChemPhysChem, 8, 1315-1320 (2007)
702)	Influence of the bridging ligand on the substitution behaviour of dinuclear Pt(II) complexes. An experimental and theoretical approach H. Ertürk, A. Hofmann, R. Puchta and R. van Eldik Dalton Trans., 2295-2301 (2007)
703)	Ligand exchange processes on solvated lithium cations. IV. Acetonitrile and hydrogen cyanide E. Pasgreta, R. Puchta, A. Zahl and R. van Eldik Eur. J. Inorg. Chem., 1815-1822 (2007)
704)	Nature of Cp^*MoO²⁺ in water and intramolecular proton transfer mechanism by stopped-flow kinetics and DFT calculations J.-E. Jee, A. Comas-Vives, C. Dioni, G. Ujaque, R. van Eldik, A. Lledos and R. Poli Inorg. Chem., 46, 4103-4113 (2007)
705)	Kinetics and mechanism of the reduction of (ImH)[trans-RuCl₄(dmso)(Im)] by ascorbic acid in acidic aqueous solution M. Brindell, D. Piotrowska, A.A. Shoukry, G. Stochel and R. van Eldik Inorg. Chem., 46, 4103-4113 (2007)
706)	Ligand exchange processes on solvated lithium ions. V. Complexation by cryptands in acetone as solvent E. Pasgreta, R. Puchta, A. Zahl and R. van Eldik Eur. J. Inorg. Chem., 3067-3076 (2007)
707)	X-ray structural characterization of imidazolylcobalamin and histidinylcobalamin: Cobalamin models for aquacobalamin bound to the B₁₂ transporter protein transcobalamin L. Hannibal, S.D. Bunge, R. van Eldik, D.W. Jacobsen, C. Kratky, K. Gruber and N.E. Brasch Inorg. Chem., 46, 3613-3618 (2007)
708)	Elucidation of the solution structure and water-exchange mechanism of paramagnetic [Fe^II(edta)(H₂O)]^2- J. Maigut, R. Meier, A. Zahl and R. van Eldik Inorg. Chem., 46, 5361-5371 (2007)
709)	Structural and kinetic study of reversible CO₂ fixation by dicopper macrocyclic complexes. From intramolecular binding to self-assembly of molecular boxes A. Company, J.-E. Jee, X. Ribas, J.M. Lopez-Valbuena, L. Gomez, M. Corbella, A. Llobet, J. Mahia, J. Benet-Buchholz, M. Costas and R. van Eldik Inorg. Chem., 46, 9098-9110 (2007)
710)	Kinetics and mechanism of the substitution behaviour of Pd(II) piperazine complexes with different biologically relevant nucleophiles A. Shoukry, M. Brindell and R. van Eldik Dalton Trans., 4169-4174 (2007)
711)	Low-temperature rapid-scan detection of reactive intermediates in epoxidation reactions catalyzed by a new enzyme mimic of cytochrome P450 N. Hessenauer-Ilicheva, A. Franke, D. Meyer, W.-D. Woggon and R. van Eldik J. Am. Chem. Soc., 129, 12473-12479 (2007)
712)	[FeIII(tmdta)]^- - twist-boat/half-chair conformer ratio reliably deduced from DFT calculated Raman spectra R. Meier, J. Maigut, B. Kallies, N. Lehnert, F. Paulat, F.W. Heinemann, G. Zahn, M.P. Feth, H. Krautscheid and R. van Eldik Chem. Commun., 3960-3962 (2007)
713)	Kinetics and mechanism of the substitution reactions of [PtCl(bpma)]⁺, [PtCl(gly-met-S,N,N)] and their aqua analogues with L-methionine, glutathione and 5’-GMP Z.D. Bugarcic, J. Rosic, B. Petrovic, N. Summa, R. Puchta and R. van Eldik J. Biol. Inorg. Chem., 12, 1141-1150 (2007)
714)	A kinetic and mechanistic study of the chromium(VI) reduction by hydrogen peroxide in acidic aqueous solutions W. van Niekerk, J.J. Pienaar, G. Lachmann, R. van Eldik and M. Hamza Water SA, 33, 619-625 (2007)
715)	Rapid ligand substitution reactions in ionic liquids studied by stopped-flow technique P. Illner, S. Kern, S. Begel and R. van Eldik Chem. Commun., 4803-4805 (2007)
716)	Host-guest complexes of bicyclic hexaamine cryptands – Prediction of ion selectivity by quantum chemical calculations III R. Puchta, R. Meier and R. van Eldik Austr. J. Chem., 60, 889-897 (2007) This manuscript is featured on the cover of the December issue of Austr. J. Chem!
Publications of 2008
717)	Complex-formation reactions of dichloro(S-methyl-L-cysteine)palladium(II) with bio-relevant ligands. Labilization induced by S-donor chelates M.R. Shehata, M.M. Shoukry, F.M.H. Nasr and R. van Eldik Dalton Trans., 779-786 (2008)
718)	Host-guest complexes of mixed glycol-phenanthroline cryptands – Prediction of ion selectivity by quantum chemical calculations IV R. Puchta and R. van Eldik J. Inclus. Phenom., 60, 383-392 (2008)
719)	High-pressure testing of heterogeneous charge transfer in a room-temperature ionic liquid: Evidence for solvent dynamic control T.D. Dolidze, D.E. Khoshtariya, P. Illner, L. Kulisiewicz, A. Delgado and R. van Eldik J. Phys. Chem. B, 112, 3085-3100 (2008)
720)	Kinetic studies on the reactions of [Pd(dach)(X-Y)] complexes with some DNA constituents B. Petrovic, Z.D. Bugarcic and R. van Eldik Dalton Trans., 807-813 (2008)
721)	Ligand exchange processes on solvated beryllium cations II. [Be(solvent)(12-Crown-4)] R. Puchta and R. van Eldik Z. Anorg. Allg. Chem., 634, 735-739 (2008)
722)	A novel iron(III)-porphyrazine complex. Complex speciation and reactions with NO and H₂O₂ A. Theodoridis, J. Maigut, R. Puchta, E.V. Kudrik and R. van Eldik Inorg. Chem., 47, 2994-3013 (2008)
723)	Substitution reactions of amine-bridged dinuclear Pt(II) complexes with bio-relevant nucleophiles H. Ertürk, J. Maigut, R. Puchta and R. van Eldik Dalton Trans., 2759-2766 (2008)
724)	Heterogeneous electron transfer at Au/SAM junctions in a room-temperature ionic liquid under pressure T.D. Dolidze, D.E. Koshtariya, P. Illner and R. van Eldik Chem. Commun., 2112-2114 (2008)
725)	Effect of chelate dynamics on water exchange reactions of paramagnetic aminopolycarboxylate complexes J. Maigut, R. Meier, A. Zahl and R. van Eldik Inorg. Chem., 47, 5702-5719 (2008)
726)	Kinetics and mechanism of O-O bond cleavage in the reaction of [Ru^III(edta)(H₂O)]^- with hydroperoxides in aqueous solution D. Chatterjee, A. Sikdar, V.R. Patman, A. Theodoridis and R. van Eldik Dalton Trans., 3851-3856 (2008)
727)	Which oxidant is really responsible for P450 model oxygenation reactions? – A kinetic approach A. Franke, C. Fertinger and R. van Eldik Angew. Chem. Int. Ed., 47, 5238-5242 (2008)
728)	Influence of fluoride on the reversible binding of NO by [Fe^II(edta)(H₂O)]^₂-. Inhibition of autoxidation of [FeII(edta)(H₂O)]^2- J. Maigut, R. Meier and R. van Eldik Inorg. Chem., 47, 6314-6321 (2008)
729)	The reduction of (ImH)[trans-Ru^IIICl₄(dmso)(Im)] under physiological conditions. Preferential reaction of the reduced complex with human serum albumin M. Brindell, I. Sawoska, J. Supel, A. Skoczowski, G. Stochel and R. van Eldik J. Biol. Inorg. Chem., 13, 909-918 (2008)
730)	Metal complex-assisted activation of small molecules. From NO to superoxide and peroxides I. Ivanovic-Burmazovic and R. van Eldik Perspective article in Dalton Trans., 5259-5275 (2008) This manuscript is featured on the cover of the October 21, 2008 issue of Dalton Transactions!
731)	Ligand exchange processes on solvated beryllium cations III. Which model reaction is preferable for quantum chemical investigations of water exchange mechanisms? R. Puchta and R. van Eldik Helv. Chim. Acta, 91, 1063-1071 (2008)
732)	Mechanistic studies on fast ligand substitution reactions of Pt(II) in different ionic liquids. Role of solvent polarity and ion-pair formation S. Begel, P. Illner, S. Kern, R. Puchta and R. van Eldik Inorg. Chem., 47, 7121-7132 (2008)
733)	Triggering water exchange mechanisms via chelate architecture. Shielding of transition metal centers by aminopolycarboxylate spectator ligands J. Maigut, R. Meyer, A. Zahl and R. van Eldik J. Am. Chem. Soc., 130, 14556-14569 (2008)
734)	Interplay between acetate ions, the peripherical groups, and the reactivity of the core nitrogens in transmetalation of tetrapyrroles L. Orzel, L. Fiedor, M. Wolak, A. Kania, R. van Eldik and G. Stochel Chem. Eur. J., 14, 9419-9430 (2008)
735)	Application of high pressure laser flash photolysis in studies on selected hemoprotein reactions M. Brindell, I. Stawoska, L. Orzel, P. Labuz, G. Stochel and R. van Eldik Biochim. Biophys. Acta - Proteins and Proteomics, 1784, 1481-1492 (2008)
736)	Ligand exchange processes on solvated beryllium cations. IV. [Be(H₂O)₂(imidazole-based chelate)] R. Puchta and R. van Eldik Z. Anorg. Allg. Chem., 634, 1915-1920 (2008)
737)	Versatile and fast gas chromatographic determination of frequently used brominated flame retardants in styrenic polymers M. Pöhlein, R. Urpi Bertran, M. Wolf and R. van Eldik J. Chrom. A, 1203, 217-228 (2008)
738)	The impact of tripodal chelates on water-exchange kinetics and mechanisms. A variable temperature and pressure ¹⁷O NMR study to clarify the structure-reactivity relationship in [Fe^II(L)(H₂O)₂]- complexes J. Maigut, R. Meier, A. Zahl and R. van Eldik Magn. Res. Chem., 46, 594-599 (2008)
739)	Importance of experiments in teaching chemistry R. van Eldik Why Chemistry?, Polish Academy of Sciences, Krakow, 67-73 (2008)
740)	Advances in Inorganic Chemistry, Vol. 60 R. van Eldik (Ed) Elsevier Academic Press, San Diego, 290 pp, 2008
741)	Iron chalates: a challenge to chemists and Mössbauer spectroscopists Z. Homonnay, P.A. Szilagyi, A. Vertes, R. Kuzmann, V.K. Sharma, G. Molnar, A. Bousseksou, J.-M. Greneche, A. Brausam, R. Meier and R. van Eldik Hyperfine Interact, 182, 77-86 (2008)
Publications of 2009
742)	From NO to peroxide activation by model iron(III) complexes A. Franke, N. Hessenauer-Ilicheva, J.-E. Jee and R. van Eldik In „Activating Unreactive Substrates“, C. Bolm and E. Hahn (Eds.), Wiley-VCH, 245-272 (2009)
743)	Mechanistic insight into formation of oxo-iron(IV) porphyrin pi-cation radicals from enzyme mimics of cytochrome P450 in organic solvents N. Hessenauer-Ilicheva, A. Franke, D. Meyer, W.-D. Woggon and R. van Eldik Chem. Eur. J., 15, 2941-2959 (2009).
744)	Metal ion-catalyzed oxidative degradation of orange II by H₂O₂. High catalytic activity of simple manganese salts E. Ember, S. Rothbart, R. Puchta and R. van Eldik New. J. Chem., 33, 34-49 (2009). This manuscript is featured on the cover of the January 2009 issue of the New Journal of Chemistry!
745)	Hydrogen cyanide exchange on [Al(HCN)₆]³⁺ - a DFT study R. Puchta, B.M. Alzoubi and R. van Eldik Z. Anorg. Allg. Chem., 635, 434-438 (2009).
746)	Fast substitution reactions of Pt(II) in different ionic liquids. Reactivity control by anionic components P. Illner, S. Begel, S. Kern, R. Puchta and R. van Eldik Inorg. Chem., 48, 588-597 (2009).
747)	Mechanistic behaviour of alkylcobaloxime and imino-oxime complexes related to vitamin B₁₂ B.M. Alzoubi, F. Vidali, R. Puchta, C. Dücker-Benfer, A. Felluga, L. Randaccio, G. Tauzher and R. van Eldik Dalton Trans., 2392-2399 (2009).
748)	Structural, spectroscopic and kinetic investigation of the molybdenum dialkylhydrazido complexes [MoBr(NNC₅H₁₀)(dppe)₂]Br and [Mo(NNC₅H10)(dppe)₂]: Activation parameters and revised mechanism for N-N cleavage A. Dreher, K. Mersmann, C. Näther, I. Ivanovic-Burmazoviz, R. van Eldik and F. Tuczek Inorg. Chem., 48, 2078-2093 (2009).
749)	Synthesis, characterization, thermodynamic and kinetic properties of a new series of dinuclear Pt(II) complexes H. Ertürk, R. Puchta and R. van Eldik Eur. J. Inorg. Chem., 1331-1338 (2009).
750)	Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations P. Illner, R. Puchta, F.W. Heinemann and R. van Eldik Dalton Trans., 2795-2801 (2009).
751)	Ligand exchange processes on the smallest solvated alkali and alkali earth metal cations. An experimental and theoretical approach R. Puchta, E. Pasgreta and R. van Eldik Adv. Inorg. Chem., 61, 523-571 (2009)
752)	Advances in Inorganic Chemistry, Vol. 61: Metal ion controlled reactivity R. van Eldik and C.D. Hubbard (Eds) Elsevier Academic Press, San Diego, 635 pp (2009)
753)	Activation parameters for heme-NO binding in Alcaligenes xylosoxidans cytochrome câ€™: The putative dinitrosyl intermediate forms via a dissociative mechanism D.A. Pixton, C.A. Petersen, A. Franke, R. van Eldik, E.M. Garton and C.R. Andrew J. Am. Chem. Soc., 131, 4846-4853 (2009)
754)	Multiple mechanisms for electron transfer at metal/self-assembled monolayer/room-temperature ionic liquid junctions: Dynamical arrest versus frictional control and non-adiabaticity D.E. Khoshtariya, T.D. Dolidze and R. van Eldik Chem. Eur. J., 5254-5262 (2009)
755)	Factors that affect the nature of the final oxidation products in â€œperoxo-shuntâ€ reactions of iron porphyrins A. Franke, M. Wolak and R. van Eldik Chem. Eur. J., 15, 10182-10198 (2009)
756)	Equilibrium and kinetic studies of the reactions between aqua[1-(2-aminoethyl)piperazine]palladium(II) and biologically relevant nucleophiles T. Soldatovic, M. Shoukry, R. Puchta, Z.D. Bugarcic and R. van Eldik Eur. J. Inorg. Chem., 2261-2270 (2009)
757)	Influence of the chloride concentration on ligand substitution reactions of [Pt(SMC)Cl₂] with biologically relevant nucleophiles T. Soldatovic, Z.D. Bugarcic and R. van Eldik Dalton Trans., 4526-4531 (2009)
758)	Preparation of reference materials for the determination of RoHS-relevant flame retardants in styrenic polymers M. Pöhlein, R. Urpi Bertran, M. Wolf and R. van Eldik Anal. Bioanal. Chem., 394, 583-595 (2009)
759)	Chelate electronic properties control the redox behaviour and superoxide reactivity of seven-coordinate manganese(II) complexes G.-F. Liu, K. Dürr, R. Puchta, F.W. Heinemann, R. van Eldik and I. Ivanovic-Burmazovic Dalton Trans., 6292-6295 (2009)
760)	Mechanistic information on CuII metalation and transmetalation of chlorophylls L. Orzel, R. van Eldik, L. Fiedor and G. Stochel Eur. J. Inorg. Chem., 2393-2406 (2009)
761)	A new trigonal-bipyramidal [Cu^II(py^tBuN₃)Cl₂] complex: Synthesis, structure and ligand substitution behaviour S.Y. Shaban, F.W. Heinemann and R. van Eldik Eur. J. Inorg. Chem., 3111-3118 (2009)
762)	Thermodynamic and kinetic studies on the reactions of Fe^III(meso-[tetra-(3-sulfonatomesityl)porphin]) with NO in an ionic liquid. Trace impurities can change the mechanism! M. Schmeisser and R. van Eldik Inorg. Chem., 48, 7466-7475 (2009)
763)	New mechanistic aspects of the Fenton reaction S. Rachmilovich-Calis, A. Masarwa, N. Meyerstein, D. Meyerstein and R. van Eldik Chem. Eur. J., 15, 8303-8309 (2009)
764)	Ligand exchange processes on solvated zinc cations. DFT analysis of hydrogen cyanide exchange on [Zn(HCN)₆]²⁺ B.M. Alzoubi, R. Puchta and R. van Eldik Z. Anorg. Allg. Chem., 635, 1536-1540 (2009)
765)	Mechanistic investigations on the reaction of an iron(III) octa-anionic porphyrin complex with hydrogen peroxide and the catalyzed oxidation of ABTS A. Brausam, S. Eigler, N. Jux and R. van Eldik Inorg. Chem., 48, 7667-7678 (2009)
766)	Detailed spectroscopic, thermodynamic and kinetic studies on the protolytic equilibria of Fe^III-cydta and the activation of hydrogen peroxide A. Brausam, P.A. Szilagyi, J. Maigut, R. Meier, H.-J. Buschmann, W. Massa, Z. Homonnay and R. van Eldik Inorg. Chem., 48, 7864-7884 (2009)
767)	Equilibrium studies on complex-formation reactions of Pd[2-(2-aminoethyl)-pyridine)(H₂O)₂]²⁺ with ligands of biological significance and displacement reactions of DNA constituents M.R. Shehata, M.M. Shoukry, F.H. Abdel-Shakour and R. van Eldik Eur. J. Inorg. Chem., 3912-3920 (2009)
768)	Spectroscopic and mechanistic studies on oxidation reactions catalyzed by the functional model SR complex for cytochrome P450: Influence of oxidant, substrate, and solvent N. Hessenauer-Ilicheva, A. Franke, M. Wolak, T. Higuchi and R. van Eldik Chem. Eur. J., 15, 12447-12459 (2009)
769)	Combined low temperature rapid scan and ¹H NMR mechanistic study of the protonation and subsequent benzene elimination from a (diimine)platinum(II) diphenyl complex relevant to arene C-H activation J. Parmene, I. Ivanovic-Burmazovic, M. Tilset and R. van Eldik Inorg. Chem., 48, 9092-9103 (2009)
770)	Kinetics and mechanism of the Co(II)-assisted oxidation of L-ascorbic acid by dioxygen and nitrite in aqueous solution E.A. Vlasova, N. Hessenauer-Ilicheva, D.S. Salnikov, E.V. Kudrik, S.V. Makarov and R. van Eldik Dalton Trans., 10541-10549 (2009)
771)	Mechanistic information from volume profiles for water exchange and complex-formation reactions of aquated Ni(II). pH, buffer and medium effects H.A. Gazzaz, E. Ember, A. Zahl and R. van Eldik Dalton Trans., 9486-9495 (2009)
772)	Direct comparison of the reactivity of model complexes for Compounds 0, I and II in oxygenation, hydrogen abstraction and hydride transfer processes C. Fertinger, N. Hessenauer-Ilicheva, A. Franke and R. van Eldik Chem. Eur. J., 15, 13435-13440 (2009)
773)	Washing and bleaching agent that is gentle on textiles and effective in hard water comprising peroxide and manganese complex A. Nordskog, W. von Rybinski, D. Sendor-Mueller, B. Middelhauve, S. Erpenbach, P. Schmiedel, S. Leopold, U. Huchel, T. Weber, R. van Eldik and E. Ember PCT Int. Appl., 30pp. CODEN: PIXXD2 WO 2009141258 A1 20091126 (2009)
774)	Unusual mechanism for the short-range electron transfer within gold-alkanethiol-ionic-liquid films of subnanometer thickness D. E. Khoshtariya, T. D. Dolidze and R. van Eldik Phys. Rev. E, 80, 065101(R) (2009)

2010-today

Publications of 2010
775)	Application of low-temperature rapid-scan techniques in the elucidation of inorganic reaction mechanisms R. van Eldik and C.D. Hubbard Coord. Chem. Rev., Special Issue dedicated to the 90th birthday of Ralph Pearson, 254, 297-308 (2010)
776)	Mechanistic information on some inorganic and bioinorganic reactions from volume profile analysis C.D. Hubbard and R. van Eldik Inorg. Chim. Acta, Special Issue dedicated to Fred Basolo, 363, 2357-2374 (2010)
777)	Application of high pressure in the elucidation of inorganic and bioinorganic reaction mechanisms C.D. Hubbard and R. van Eldik Physical Inorganic Chemistry. Principles, Methods and Models, A. Bakac (Ed.), Wiley, 269-365 (2010)
778)	Ligand exchange processes on the solvated zinc cation II. [Zn(H₂O)₄L]²⁺*2H₂O with L = NH₃, NH₂(CH₃), NH(CH₃)₂ and N(CH₃)₃ B.M. Alzoubi, R. Puchta and R. van Eldik Austr. J. Chem., 63, 236-244 (2010)
779)	Mechanistic information on the reversible binding of NO to mono- and dinuclear Fe^II complexes of a biomimetic S₄N ligand S.Y. Shaban and R. van Eldik Eur. J. Inorg. Chem., 554-561 (2010)
780)	[Ru^III(edta)(H₂O)]- mediated oxidation of hydroxyurea with H₂O₂. Kinetic and mechanistic investigation D. Chatterjee, K.A. Nayak, E. Ember and R. van Eldik Dalton Trans., 39, 1695-1698 (2010)
781)	Mn^II - a fascinating oxidation catalyst. Mechanistic insight into the catalyzed oxidation degradation of organic dyes by H₂O₂ E. Ember, H.A. Gazzaz, S. Rothbart, R. Puchta and R. van Eldik Appl. Cat. B: Environmental, 95, 179-191 (2010)
782)	Comparative study of the catalytic activity of [Mn^II(bpy)₂Cl₂] and [Mn₂^III/IV(μ-O)₂(bpy)₄](ClO₄)₃ in the H₂O₂ induced oxidation of organic dyes in carbonate buffered aqueous solution S. Rothbart, E. Ember and R. van Eldik Dalton Trans., 39, 3264-3272 (2010)
783)	Fundamental signatures of short- and long-range electron transfer for the blue copper protein azurin at Au/SAM junctions D.E. Koshtariya, T.D. Dolidze, M. Shushanyan, K.L. Davis, D.H. Waldeck and R. van Eldik Proc. Natl. Acad. Sci. USA, 107, 2757-2762 (2010)
784)	Five-coordinate zinc(II) complexes containing sterically demanding biomimetic N₃S₂ ligands. Synthesis, characterization and DFT calculations S.Y. Shaban, R. Puchta and R. van Eldik Z. Naturforsch., 65b, 251-257 (2010)
785)	Ligand exchange processes on solvated zinc cations. Water exchange on [Zn(H₂O)₄(L)]²⁺.2H₂O (L = heterocyclic ligand) B.M. Alzoubi, R. Puchta and R. van Eldik Chem. Eur. J., 16, 7300-7308 (2010)
786)	Tuning the reactivity of chelated dinuclear Pt(II) complexes through a flexible diamine linker. A detailed kinetic and mechanistic study A. Mambanda, D. Jaganyi, S. Hochreuther and R. van Eldik Dalton Trans., 39, 3595-3608 (2010)
787)	Ligand exchange processes on solvated lithium cations. VI. Determination of coordination numbers by ligand substitution and ⁷Li NMR M. Schmeisser, A. Zahl, A. Scheuer, R. Puchta and R. van Eldik Z. Naturforsch., 65b, 405-413 (2010)
788)	Reinvestigation of the formation of a mononuclear Fe(III) hydroperoxido complex using high pressure kinetics T. Nebe, A. Beitat, C. Würtele, C. Dücker-Benfer, R. van Eldik, C.J. McKenzie and S. Schindler Dalton Trans., 39, 7768-7773 (2010)
789)	Mechanistic studies on fast ligand substitution reactions of a very labile Pd(II) complex in several ionic liquids S. Kern, P. Illner, S. Begel and R. van Eldik Eur. J. Inorg. Chem., 4658-4666 (2010)
790)	Advances in Inorganic Chemistry, Vol. 62: Theoretical and Computational Inorganic Chemistry R. van Eldik and J. Harvey (Eds) Elsevier Academic Press, San Diego, 2010
791)	Determination of Henry products by chirale HPLC. Optimization of a method with phase comparison T. Roth, T. Godau, S.M. Bleifuß, M. Pöhlein, M. Wolf and R. van Eldik GIT Special Separation, 30, 40-42 (2010)
792)	Kinetic studies on the reactions of different bifunctional platinum(II) complexes with selected nucleophiles J. Bogojeski, Z.D. Bugarcic, R. Puchta and R. van Eldik Eur. J. Inorg. Chem., 5439-5445 (2010)
793)	Thermodynamic, electrochemical, high-pressure kinetic and mechanistic studies of the formation of oxo Fe^IV-TAML^® species in water D.L. Popescu, M. Vrabel, A. Brausam, P. Madsen, G. Lente, I. Fabian, A.D. Ryabov, R. van Eldik and T.J. Collins Inorg. Chem., 49, 11439-11448 (2010)
794)	Volume profile analysis for the reversible binding of superoxide to form iron(II)-superoxo/iron(III)-peroxo porphyrin complexes K. Dürr, N. Jux, A. Zahl, R. van Eldik and I. Ivanovic-Burmazovic Inorg. Chem., 49, 11254-11260 (2010)
795)	Understanding chemical reaction mechanisms in ionic liquids: Successes and challenges C.D. Hubbard, P. Illner and R. van Eldik Chem. Soc. Rev., 40, 272-290 (2011)
796)	Charge transfer mechanism at SAM-modified electrodes. Impact of complex environments D.E. Koshtariya, T.D. Dolidze and R. van Eldik Advanced biological active polyfunctional compounds and composites, Nova Science Publishers N.Y., 103-128 (2010)
Publications of 2011
797)	Structural and mechanistic information on the nitrosation of model Fe(II) complexes containing a biomimetic S₄N chelate S.Y. Shaban and R. van Eldik Dalton Trans., 40, 287-294 (2011)
798)	Kinetics and mechanism of the reaction of [Ru^II(tpy)(pic)(H₂O)]⁺ with KHSO₅ in oxidative cleavage of DNA D. Chatterjee, A. Sengupta and R. van Eldik J. Coord. Chem., 64, 30-37 (2011)
799)	How or not to calculate Ni(II) Werner-type complexes. Evaluation of quantum chemical methods M. Walther, B.M. Alzubi, R. Puchta, G. Linti, R. Meier and R. van Eldik J. Coord. Chem., 64, 18-29 (2011)
800)	Structures of vanadium(III)-ethylenediamine-N,N'-diacetato-N,N'-di-3-propionato complexes. Critical role of p_x-d_x donation in determining the coordination number R. Meier, S. Mitzenheim, H. Pritzkow and R. van Eldik Inorg. Chem., 50, 1005-1013 (2011)
801)	Redox reactions of a RuIII-edta complex with thioamino acids. Kinetic and mechanistic studies D. Chatterjee, U. Pal, S. Ghosh and R. van Eldik Dalton Trans., 40, 1302-1306 (2011)
802)	Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tributylphosphoniumdithiocarboxylate G.G. Iskhakova, V.D. Kiselev, R. van Eldik, A. Zahl, M.S. Shihab and A.I. Konovalov J. Phys. Org. Chem., 24, 360-365 (2011)
803)	Mechanistic studies on the reactions of cyanide with a water-soluble Fe(III) prophyrin and their effect on the binding of NO M. Oszaja, A. Franke, M. Brindell, G. Stochel and R. van Eldik Inorg. Chem., 50, 3413-3424 (2011)
804)	Thermodynamic and kinetic studies on the interaction of RuIII(edta) with NO in an ionic liquid S. Begel and R. van Eldik Dalton Trans., 40, 4892-4897 (2011)
805)	Ligand exchange processes on solvated beryllium cations V. Exchange on [Be(X)(H₂O)₃]⁺ (X: H^-, F^-, Cl^-, Br^-, OH^-, CN^-, NCNCN^-) A. Budimir, M. Walther, R. Puchta and R. van Eldik Z. Anorg. Allg. Chem., 637, 515-522 (2011)
806)	The classic "brown-ring" reaction in a new medium: Kinetics, mechanism, and spectroscopy of the revesible binding of nitric oxide to iron(II) in an ionic liquid S. Begel, F.W. Heinemann, G. Stopa, G. Stochel and R. van Eldik Inorg. Chem., 50, 3946-3958 (2011)
807)	Diverse role of conformational dynamics in carboxypeptidase A-driven peptide and ester hydrolyses. Disclosing the "perfect induced fit" and "protein local unfolding" pathways by altering protein stability M. Shushanyan, D.E. Khoshtariya, T. Tretyakova, M. Makharadze and R. van Eldik Biopolymers, 95, 852-870 (2011)
808)	Coordination of 1,10-phenanthroline and 2,2'-bipyridine to Li⁺ in different ionic liquids. How innocent are ionic liquids? M. Schmeisser, F.W. Heinemann, P. Illner, R. Puchta, A. Zahl and R. van Eldik Inorg. Chem., 50, 6685-6695 (2011)
809)	Remarkably high catalytic reactivity of the Ru^III(edta)/H₂O₂ system towards degradation of the azo-dye Orange II D. Chatterjee, E. Ember, U. Pal, S. Ghosh and R. van Eldik Dalton Trans., 40, 10473-10480 (2011)
810)	Calculation of some thermodynamic properties and detonation parameters of 1-ethyl-3-methyl-H-imidazolium perchlortae, [Emim][ClO₄], on the basis of CBS-4M and CHEETAH computations supplemented by VBT estimates T.M. Klapötke, J. Stierstorfer, H.D. Brooke Jenkins, R. van Eldik and M. Schmeisser Z. Anorg. Allg. Chem., 637, 1308-1313 (2011)
811)	Cobalamin reduction by dithionite. Evidence for the formation of a six-coordinate cobalamin(II) complex D.S. Salnikov, R. Silaghi-Dumitrescu, S.V. Makarov, R. van Eldik and G.R Boss Dalton Trans., 40, 9831-9834 (2011)
812)	Thermodynamic and kinetic studies on novel dinuclear platinum(II) complexes containing bidentate N,N-donor ligands S. Hochreuther, R. Puchta and R. van Eldik Inorg. Chem., 50, 8984-8996 (2011)
813)	An ionic liquid designed for coordination chemistry revisited. New synthetic routes and safety tests for [emim][ClO₄] M. Schmeisser, P. Keil, J. Stierstorfer, A. König, T.M. Klapötke and R. van Eldik Eur. J. Inorg. Chem., 4862-4868 (2011)
814)	Advances in Inorganic Chemistry, Vol. 63: Inorganic Photochemistry R. van Eldik and G. Stochel (Eds) Elsevier Academic Press, San Diego, 448 pp (2011)
815)	Kinetics and mechanism of the [Ru(edta)(H₂O)]^--mediated oxidation of cysteine by H₂O₂ D. Chatterjee, E. Ember, U. Pal, S. Ghosh and R. van Eldik Dalton. Trans., 40, 10997-11004 (2011)
816)	Cytochrome P450 enzyme mimics in 'peroxo-shunt' oxidation reactions - a kinetic and mechanistic approach A. Franke, C. Fertinger and R. van Eldik BioInorg. React. Mech., 7, 5-26 (2011)
817)	Novel dinuclear platinum(II) complexes containing mixed nitrogen-sulfur donor ligands S. Hochreuther, R. Puchta and R. van Eldik Inorg. Chem., 50, 12747-12761 (2011)
Publications of 2012
818)	Thermodynamic and kinetic behaviour of [Pt(2-methylthiomethylpyridine)(OH₂)₂]²⁺ S. Hochreuther, S.T. Nandibewoor, R. Puchta and R. van Eldik Dalton Trans., 41, 512-522 (2012)
819)	Mechanistic insight from thermal activation parameters for oxygenation reactions of different substrates with biomimetic iron porphyrin models for compounds I and II C. Fertinger, A. Franke and R. van Eldik J. Biol. Inorg. Chem., 17, 27-36 (2012)
820)	Substitution behaviour of novel Pt(II) complexes with bio-relevant nucleophiles T. Soldatovic, S. Jovanovic, Z.D. Bugarcic and R. van Eldik Dalton Trans., in press (2012)
821)	Mechanistic study of the oxidative degradation of dibenzoazepine derivatives by cerium(IV) complexes in acidic sulfate media J. Wisniewska, G. Wrzeszcz, M. Kurzawa and R. van Eldik Dalton Trans., in press (2012)
822)	Mechanistic studies on the oxidative degradation of Orange II by peracetic acid catalyzed by simple manganese(II) salts. Tuning the lifetime of the catalyst S. Rothbart, E.E. Ember and R. van Eldik New J. Chem., in press (2012)
823)	A complete volume profile for the reversible binding of camphor to cytochrome P450cam A. Franke, E. Hartmann, I. Schlichting and R. van Eldik J. Biol. Inorg. Chem., in press (2012)
824)	Role of π-acceptor effects in controlling the lability of novel mono-functional Pt(II) and Pd(II) complexes. Crystal structure of [Pt(tripyridinedimethane)Cl]Cl B. Petrovic, Z.D. Bugarcic, A. Dees, I. Ivanovic-Burmazovic, F.W. Heinemann, R. Puchta, S.N. Steimann, C. Corminboeuf and R. van Eldik Inorg. Chem., in press (2012)
825)	Mechanism of O-O- bond activation and substrate oxidation by Ru-edta complexes D. Chatterjee and R. van Eldik J. Mol. Cat. A, in press (2012)
826)	Kinetics and mechanism of the reactions of Au(III) complexes with some biologically relevant molecules A. Djekovic, B. Petrovic, Z.D. Bugarcic, R. Puchta and R. van Eldik Dalton Trans., in press (2012)
827)	Axial ligand and spin state influence on the formation and reactivity of hydroperoxo iron(III) porphyrin complexes A. Franke, C. Fertinger and R. van Eldik Chem. Eur. J., in press (2012)