Publikationen 2010-heute
2010
775. Application of low-temperature rapid-scan techniques in the elucidation of inorganic reaction mechanisms
R. van Eldik and C.D. Hubbard
Coord. Chem. Rev., Special Issue dedicated to the 90th birthday of Ralph Pearson, 254, 297-308 (2010)
776. Mechanistic information on some inorganic and bioinorganic reactions from volume profile analysis
C.D. Hubbard and R. van Eldik
Inorg. Chim. Acta, Special Issue dedicated to Fred Basolo, 363, 2357-2374 (2010)
777. Application of high pressure in the elucidation of inorganic and bioinorganic reaction mechanisms
C.D. Hubbard and R. van Eldik
Physical Inorganic Chemistry. Principles, Methods and Models, A. Bakac (Ed.), Wiley, 269-365 (2010).
778. Ligand exchange processes on the solvated zinc cation II. [Zn(H2O)4L]2+.2H2O with L = NH3, NH2(CH3), NH(CH3)2 and N(CH3)3
B.M. Alzoubi, R. Puchta and R. van Eldik
Austr. J. Chem., 63, 236-244 (2010)
779. Mechanistic information on the reversible binding of NO to mono- and dinuclear FeII complexes of a biomimetic S4N ligand
S.Y. Shaban and R. van Eldik
Eur. J. Inorg. Chem., 554-561 (2010)
780. [RuIII(edta)(H2O)]- mediated oxidation of hydroxyurea with H2O2. Kinetic and mechanistic investigation
D. Chatterjee, K.A. Nayak, E. Ember and R. van Eldik
Dalton Trans., 39, 1695-1698 (2010)
781. MnII – a fascinating oxidation catalyst. Mechanistic insight into the catalyzed oxidation degradation of organic dyes by H2O2
E. Ember, H.A. Gazzaz, S. Rothbart, R. Puchta and R. van Eldik
Appl. Cat. B: Environmental, 95, 179-191 (2010)
782. Comparative study of the catalytic activity of [MnII(bpy)2Cl2] and [Mn2III/IV(μ-O)2(bpy)4](ClO4)3 in the H2O2 induced oxidation of organic dyes in carbonate buffered aqueous solution
S. Rothbart, E. Ember and R. van Eldik
Dalton Trans., 39, 3264-3272 (2010)
783. Fundamental signatures of short- and long-range electron transfer for the blue copper protein azurin at Au/SAM junctions
D.E. Koshtariya, T.D. Dolidze, M. Shushanyan, K.L. Davis, D.H. Waldeck and R. van Eldik
Proc. Natl. Acad. Sci. USA, 107, 2757-2762 (2010)
784. Five-coordinate zinc(II) complexes containing sterically demanding biomimetic N3S2 ligands. Synthesis, characterization and DFT calculations
S.Y. Shaban, R. Puchta and R. van Eldik
Z. Naturforsch., 65b, 251-257 (2010)
785. Ligand exchange processes on solvated zinc cations. Water exchange on [Zn(H2O)4(L)]2+.2H2O (L = heterocyclic ligand)
B.M. Alzoubi, R. Puchta and R. van Eldik
Chem. Eur. J., 16, 7300-7308 (2010)
786. Tuning the reactivity of chelated dinuclear Pt(II) complexes through a flexible diamine linker. A detailed kinetic and mechanistic study
A. Mambanda, D. Jaganyi, S. Hochreuther and R. van Eldik
Dalton Trans., 39, 3595-3608 (2010)
787. Ligand exchange processes on solvated lithium cations. VI. Determination of coordination numbers by ligand substitution and 7Li NMR
M. Schmeisser, A. Zahl, A. Scheuer, R. Puchta and R. van Eldik
Z. Naturforsch., 65b, 405-413 (2010)
788. Reinvestigation of the formation of a mononuclear Fe(III) hydroperoxido complex using high pressure kinetics
T. Nebe, A. Beitat, C. Würtele, C. Dücker-Benfer, R. van Eldik, C.J. McKenzie and S. Schindler
Dalton Trans., 39, 7768-7773 (2010)
789. Mechanistic studies on fast ligand substitution reactions of a very labile Pd(II) complex in several ionic liquids
S. Kern, P. Illner, S. Begel and R. van Eldik
Eur. J. Inorg. Chem., 4658-4666 (2010)
790. Advances in Inorganic Chemistry, Vol. 62: Theoretical and Computational Inorganic Chemistry
R. van Eldik and J. Harvey (Eds)
Elsevier Academic Press, San Diego, 522 pp (2010)
791. Determination of Henry products by chirale HPLC. Optimization of a method with phase comparison
T. Roth, T. Godau, S.M. Bleifuß, M. Pöhlein, M. Wolf and R. van Eldik
GIT Special Separation, 30, 40-42 (2010)
792. Kinetic studies on the reactions of different bifunctional platinum(II) complexes with selected nucleophiles
J. Bogojeski, Z.D. Bugarcic, R. Puchta and R. van Eldik
Eur. J. Inorg. Chem., 5439-5445 (2010)
793. Thermodynamic, electrochemical, high-pressure kinetic and mechanistic studies of the formation of oxo FeIV-TAML® species in water
D.L. Popescu, M. Vrabel, A. Brausam, P. Madsen, G. Lente, I. Fabian, A.D. Ryabov, R. van Eldik and T.J. Collins
Inorg. Chem., 49, 11439-11448 (2010)
794. Volume profile analysis for the reversible binding of superoxide to form iron(II)-superoxo/iron(III)-peroxo porphyrin complexes
K. Dürr, N. Jux, A. Zahl, R. van Eldik and I. Ivanovic-Burmazovic
Inorg. Chem., 49, 11254-11260 (2010)
795. Charge transfer mechanism at SAM-modified electrodes. Impact of complex environments
D.E. Koshtariya, T.D. Dolidze and R. van Eldik
Advanced biological active polyfunctional compounds and composites, Nova Science Publishers N.Y., 103-128 (2010)
2011
796. Understanding chemical reaction mechanisms in ionic liquids: Successes and challengesC.D. Hubbard, P. Illner and R. van Eldik
Chem. Soc. Rev., 40, 272-290 (2011)
797. Structural and mechanistic information on the nitrosation of model Fe(II) complexes containing a biomimetic S4N chelate
S.Y. Shaban and R. van Eldik
Dalton Trans., 40, 287-294 (2011)
798. Kinetics and mechanism of the reaction of [RuII(tpy)(pic)(H2O)]+ with KHSO5 in oxidative cleavage of DNA
D. Chatterjee, A. Sengupta and R. van Eldik
J. Coord. Chem., 64, 30-37 (2011)
799. How or not to calculate Ni(II) Werner-type complexes. Evaluation of quantum chemical methods
M. Walther, B.M. Alzubi, R. Puchta, G. Linti, R. Meier and R. van Eldik
J. Coord. Chem., 64, 18-29 (2011)
800. Structures of vanadium(III)-ethylenediamine-N,N’-diacetato-N,N’-di-3-propionato complexes. Critical role of px-dx donation in determining the coordination number
R. Meier, S. Mitzenheim, H. Pritzkow and R. van Eldik
Inorg. Chem., 50, 1005-1013 (2011)
801. Redox reactions of a RuIII-edta complex with thioamino acids. Kinetic and mechanistic studies
D. Chatterjee, U. Pal, S. Ghosh and R. van Eldik
Dalton Trans., 40, 1302-1306 (2011)
802. Solvent, salt and high pressure effects on the rate and equilibrium constants for the formation of tributylphosphoniumdithiocarboxylate
G.G. Iskhakova, V.D. Kiselev, R. van Eldik, A. Zahl, M.S. Shihab and A.I. Konovalov
J. Phys. Org. Chem., 24, 360-365 (2011)
803. Mechanistic studies on the reactions of cyanide with a water-soluble Fe(III) prophyrin and their effect on the binding of NO
M. Oszaja, A. Franke, M. Brindell, G. Stochel and R. van Eldik
Inorg. Chem., 50, 3413-3424 (2011)
804. Thermodynamic and kinetic studies on the interaction of RuIII(edta) with NO in an ionic liquid
S. Begel and R. van Eldik
Dalton Trans., 40, 4892-4897 (2011)
805. Ligand exchange processes on solvated beryllium cations V. Exchange on [Be(X)(H2O)3]+ (X: H-, F-, Cl-, Br-, OH-, CN-, NCNCN-)
A. Budimir, M. Walther, R. Puchta and R. van Eldik
Z. Anorg. Allg. Chem., 637, 515-522 (2011)
806. The classic “brown-ring” reaction in a new medium: Kinetics, mechanism, and spectroscopy of the revesible binding of nitric oxide to iron(II) in an ionic liquid
S. Begel, F.W. Heinemann, G. Stopa, G. Stochel and R. van Eldik
Inorg. Chem., 50, 3946-3958 (2011)
807. Diverse role of conformational dynamics in carboxypeptidase A-driven peptide and ester hydrolyses. Disclosing the “perfect induced fit” and “protein local unfolding” pathways by altering protein stability
M. Shushanyan, D.E. Khoshtariya, T. Tretyakova, M. Makharadze and R. van Eldik
Biopolymers, 95, 852-870 (2011)
808. Coordination of 1,10-phenanthroline and 2,2’-bipyridine to Li+ in different ionic liquids. How innocent are ionic liquids?
M. Schmeisser, F.W. Heinemann, P. Illner, R. Puchta, A. Zahl and R. van Eldik
Inorg. Chem., 50, 6685-6695 (2011)
809. Remarkably high catalytic reactivity of the RuIII(edta)/H2O2 system towards degradation of the azo-dye Orange II
D. Chatterjee, E. Ember, U. Pal, S. Ghosh and R. van Eldik
Dalton Trans., 40, 10473-10480 (2011)
810. Calculation of some thermodynamic properties and detonation parameters of 1-ethyl-3-methyl-H-imidazolium perchlortae, [Emim][ClO4], on the basis of CBS-4M and CHEETAH computations supplemented by VBT estimates
T.M. Klapötke, J. Stierstorfer, H.D. Brooke Jenkins, R. van Eldik and M. Schmeisser
Z. Anorg. Allg. Chem., 637, 1308-1313 (2011)
811. Cobalamin reduction by dithionite. Evidence for the formation of a six-coordinate cobalamin(II) complex
D.S. Salnikov, R. Silaghi-Dumitrescu, S.V. Makarov, R. van Eldik and G.R Boss
Dalton Trans., 40, 9831-9834 (2011)
812. Thermodynamic and kinetic studies on novel dinuclear platinum(II) complexes containing bidentate N,N-donor ligands
S. Hochreuther, R. Puchta and R. van Eldik
Inorg. Chem., 50, 8984-8996 (2011)
813. An ionic liquid designed for coordination chemistry revisited. New synthetic routes and safety tests for [emim][ClO4]
M. Schmeisser, P. Keil, J. Stierstorfer, A. König, T.M. Klapötke and R. van Eldik
Eur. J. Inorg. Chem., 4862-4868 (2011)
814. Advances in Inorganic Chemistry, Vol. 63: Inorganic Photochemistry
R. van Eldik and G. Stochel (Eds)
Elsevier Academic Press, San Diego, 448 pp (2011)
815. Kinetics and mechanism of the [Ru(edta)(H2O)]--mediated oxidation of cysteine by H2O2
D. Chatterjee, E. Ember, U. Pal, S. Ghosh and R. van Eldik
Dalton. Trans., 40, 10997-11004 (2011)
816. Cytochrome P450 enzyme mimics in ‘peroxo-shunt’ oxidation reactions – a kinetic and mechanistic approach
A. Franke, C. Fertinger and R. van Eldik
BioInorg. React. Mech., 7, 5-26 (2011)
817. Novel dinuclear platinum(II) complexes containing mixed nitrogen-sulfur donor ligands
S. Hochreuther, R. Puchta and R. van Eldik
Inorg. Chem., 50, 12747-12761 (2011)
818. Thermodynamic and kinetic behaviour of [Pt(2-methylthiomethylpyridine)(OH2)2]2+
S. Hochreuther, S.T. Nandibewoor, R. Puchta and R. van Eldik
Dalton Trans., 41, 512-522 (2012)
2012
819. Mechanistic insight from thermal activation parameters for oxygenation reactions of different substrates with biomimetic iron porphyrin models for compounds I and IIC. Fertinger, A. Franke and R. van Eldik
J. Biol. Inorg. Chem., 17, 27-36 (2012)
820. Substitution behaviour of novel Pt(II) complexes with bio-relevant nucleophiles
T. Soldatovic, S. Jovanovic, Z.D. Bugarcic and R. van Eldik
Dalton Trans., 41, 876-884 (2012)
821. Mechanistic study of the oxidative degradation of dibenzoazepine derivatives by cerium(IV) complexes in acidic sulfate media
J. Wisniewska, G. Wrzeszcz, M. Kurzawa and R. van Eldik
Dalton Trans., 41, 1259-1267 (2012)
822. Mechanistic studies on the oxidative degradation of Orange II by peracetic acid catalyzed by simple manganese(II) salts. Tuning the lifetime of the catalyst
S. Rothbart, E.E. Ember and R. van Eldik
New J. Chem., 36, 732-748 (2012)
823. A complete volume profile for the reversible binding of camphor to cytochrome P450cam
A. Franke, E. Hartmann, I. Schlichting and R. van Eldik
J. Biol. Inorg. Chem., 17, 447-463 (2012)
824. Role of π-acceptor effects in controlling the lability of novel mono-functional Pt(II) and Pd(II) complexes. Crystal structure of [Pt(tripyridinedimethane)Cl]Cl
B. Petrovic, Z.D. Bugarcic, A. Dees, I. Ivanovic-Burmazovic, F.W. Heinemann, R. Puchta, S.N. Steimann, C. Corminboeuf and R. van Eldik
Inorg. Chem., 51, 1516-1529 (2012)
825. Mechanism of -O-O- bond activation and substrate oxidation by Ru-edta complexes
D. Chatterjee and R. van Eldik
J. Mol. Cat. A, 355, 61-68 (2012)
826. Kinetics and mechanism of the reactions of Au(III) complexes with some biologically relevant molecules
A. Djekovic, B. Petrovic, Z.D. Bugarcic, R. Puchta and R. van Eldik
Dalton Trans., 41, 3633-3641 (2012)
827. Axial ligand and spin state influence on the formation and reactivity of hydroperoxo iron(III) porphyrin complexes
A. Franke, C. Fertinger and R. van Eldik
Chem. Eur. J., in press (2012)
828. Advances in Inorganic Chemistry, Vol. 64: Inorganic/Bioinorganic Reaction Mechanisms
R. van Eldik and I. Ivanovic-Burmazovic (Eds)
Elsevier Academic Press, San Diego, 325 pp (2012)
829. Advances in the mechanistic understanding of selected reactions of transition metal polyaminecarboxylate complexes
A. Brausam and R. van Eldik
Adv. Inorg. Chem., 64, 141-181 (2012)
830. Polyaminecarboxylateruthenium(III) complexes on the mosaic of bioinorganic reactions. Kinetic and mechanistic impact
D. Chatterjee and R. van Eldik
Adv. Inorg. Chem., 64, 183-217 (2012)
831. Seven-coordinate iron(II) complexes of sulfur-based N3S2-macrocyclic ligands. Synthesis, properties and crystal structures
S.Y. Shaban, M.M. Ibrahim, F.W. Heinemann and R. van Eldik
J. Coord. Chem., 65, 934-944 (2012)
832. Reactivity of a cytostatic active N,N-donor containing dinuclear Pt(II) complex with biological relevant nucleophiles
S. Hochreuther and R. van Eldik
Inorg. Chem., 51, 3025-3038 (2012)
833. Apparent or real water exchange reactions on [Zn(H2O)4L]2+.2H2O (L = sp-nitrogen donor ligands)? A quantum chemical investigation
B.M. Azoubi, M. Walther, R. Puchta and R. van Eldik
Dalton Trans., in press (2012)
834. Gutmann donor and acceptor numbers for ionic liquids
M. Schmeisser, P. Illner, R. Puchta, A. Zahl and R. van Eldik
Chem. Eur. J., in press (2012)